The present invention relates to optionally substituted 1,3-dimethoxypropanes and 3-methoxypropylamines, and more particularly to their use as internal donors in Ziegler-Natta catalysts to obtain polymers with desirable properties. The present disclosure further concerns Ziegler-Natta catalyst components comprising said optionally substituted 1,3-dimethoxypropanes and 3-methoxypropylamines, and Ziegler-Natta catalysts for olefin polymerization comprising said Ziegler-Natta catalyst components, as well as a method for preparing the same and their use in providing polyolefins.

The present invention relates to optionally substituted 1,3-dimethoxypropanes and 3-methoxypropylamines, and more particularly to their use as internal donors in Ziegler-Natta catalysts to obtain polymers with desirable properties. The present disclosure further concerns Ziegler-Natta catalyst components comprising said optionally substituted 1,3-dimethoxypropanes and 3-methoxypropylamines, and Ziegler-Natta catalysts for olefin polymerization comprising said Ziegler-Natta catalyst components, as well as a method for preparing the same and their use in providing polyolefins.

Provided is a polyethylene powder having a density of 910 kg/m.sup.3 or more and less than 935 kg/m.sup.3 and an average particle diameter of 50 μm or more and less than 140 μm, wherein the polyethylene powder contains a particle having a particle diameter of 60 μm and a particle having a particle diameter of 100 μm, the compressive strength at 10% displacement of the particle having a particle diameter of 60 μm is 2.0 MPa or more and less than 5.0 MPa, and the compressive strength at 10% displacement of the particle having a particle diameter of 60 μm is 0.5 times or more and less than 1.3 times the compressive strength at 10% displacement of the particle having a particle diameter of 100 μm.

Provided is a polyethylene powder having a density of 910 kg/m.sup.3 or more and less than 935 kg/m.sup.3 and an average particle diameter of 50 μm or more and less than 140 μm, wherein the polyethylene powder contains a particle having a particle diameter of 60 μm and a particle having a particle diameter of 100 μm, the compressive strength at 10% displacement of the particle having a particle diameter of 60 μm is 2.0 MPa or more and less than 5.0 MPa, and the compressive strength at 10% displacement of the particle having a particle diameter of 60 μm is 0.5 times or more and less than 1.3 times the compressive strength at 10% displacement of the particle having a particle diameter of 100 μm.

Disclosed is a catalyst for olefin polymerization, comprising a main catalyst and a cocatalyst; the main catalyst is a bisphenol metal complex represented by formula I, and the cocatalyst comprises an organoaluminum compound; in formula I, R.sub.1, R.sub.1′, R.sub.2, R.sub.2′ are the same or different, and are each independently selected from hydrogen and a substituted or unsubstituted C.sub.1-C.sub.20 hydrocarbyl; R.sub.3-R.sub.7, R.sub.3′-R.sub.7′ are the same or different, and are each independently selected from hydrogen and a substituted or unsubstituted C.sub.1-C.sub.20 hydrocarbyl; R.sub.8 and R.sub.9 are the same or different, and are each independently selected from hydrogen or a substituted or unsubstituted C.sub.1-C.sub.20 hydrocarbyl; M and M′ are the same or different, and are selected from Group IV metals; and X is halogen;

##STR00001##

Disclosed is a catalyst for olefin polymerization, comprising a main catalyst and a cocatalyst; the main catalyst is a bisphenol metal complex represented by formula I, and the cocatalyst comprises an organoaluminum compound; in formula I, R.sub.1, R.sub.1′, R.sub.2, R.sub.2′ are the same or different, and are each independently selected from hydrogen and a substituted or unsubstituted C.sub.1-C.sub.20 hydrocarbyl; R.sub.3-R.sub.7, R.sub.3′-R.sub.7′ are the same or different, and are each independently selected from hydrogen and a substituted or unsubstituted C.sub.1-C.sub.20 hydrocarbyl; R.sub.8 and R.sub.9 are the same or different, and are each independently selected from hydrogen or a substituted or unsubstituted C.sub.1-C.sub.20 hydrocarbyl; M and M′ are the same or different, and are selected from Group IV metals; and X is halogen;

##STR00001##

An object of the present invention is to provide a composition capable of allowing for production of a crosslinked foamed product suitable for applications of footwear parts such as soles and excellent in properties such as lightweight properties, heat shrinkability, compression set and mechanical strength in a well-balanced manner, a foamed product using the composition and a footwear part using the same. An ethylene copolymer composition including an ethylene copolymer (A) satisfying all the following requirements (A-a), (A-b), (A-c) and (A-d), ethylene/α-olefin having 3 to 20 carbon atoms/non-conjugated polyene copolymer rubber (B), and, if necessary, an ethylene/polar monomer copolymer (C); (A-a) a vinyl group content per 1,000 carbon atoms is 0.025 to 0.3, (A-b) MFR.sub.10/MFR.sub.2.16 is 7 to 20, (A-c) a density is 0.850 to 0.910 g/cm.sup.3, and (A-d) a melt flow rate is 0.01 to 200 g/10 min.

An object of the present invention is to provide a composition capable of allowing for production of a crosslinked foamed product suitable for applications of footwear parts such as soles and excellent in properties such as lightweight properties, heat shrinkability, compression set and mechanical strength in a well-balanced manner, a foamed product using the composition and a footwear part using the same. An ethylene copolymer composition including an ethylene copolymer (A) satisfying all the following requirements (A-a), (A-b), (A-c) and (A-d), ethylene/α-olefin having 3 to 20 carbon atoms/non-conjugated polyene copolymer rubber (B), and, if necessary, an ethylene/polar monomer copolymer (C); (A-a) a vinyl group content per 1,000 carbon atoms is 0.025 to 0.3, (A-b) MFR.sub.10/MFR.sub.2.16 is 7 to 20, (A-c) a density is 0.850 to 0.910 g/cm.sup.3, and (A-d) a melt flow rate is 0.01 to 200 g/10 min.

This invention relates to polyolefin. More specifically, this invention relates to polyolefin that has small copolymer content, but exhibits excellent mechanical properties.

This invention relates to polyolefin. More specifically, this invention relates to polyolefin that has small copolymer content, but exhibits excellent mechanical properties.