Patent classifications
C08F2500/38
Processes for Producing High Propylene Content PEDM using Tetrahydroindacenyl Catalyst Systems
The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 1 to 35 mol % of ethylene, from 98.9 to 65 mol % C.sub.3-C.sub.40 olefin, and, optionally, from 0.1 to 10 mol % diene. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.
Processes for Producing High Propylene Content PEDM Having Low Glass Transition Temperatures Using Tetrahydroindacenyl Catalyst Systems
The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is −28° C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.
Processes for Producing High Propylene Content PEDM Having Low Glass Transition Temperatures Using Tetrahydroindacenyl Catalyst Systems
The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is −28° C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.
Metallocene compound, catalyst component for olefin polymerization and catalyst for olefin polymerization containing the same, and method for producing olefin polymer using catalyst for olefin polymerization
The metallocene compound represented by the following general formula (1): ##STR00001##
(the numerals and signs in the general formula (1) are as described in the description).
Metallocene compound, catalyst component for olefin polymerization and catalyst for olefin polymerization containing the same, and method for producing olefin polymer using catalyst for olefin polymerization
The metallocene compound represented by the following general formula (1): ##STR00001##
(the numerals and signs in the general formula (1) are as described in the description).
ETHYLENE-alpha-OLEFIN COPOLYMER, METHOD OF PRODUCING ETHYLENE-alpha-OLEFIN COPOLYMER, ETHYLENE-BASED RESIN COMPOSITION, AND FILM
An ethylene-α-olefin copolymer capable of implementing formation of a film having excellent slipperiness and suppressed fish eyes, a method of producing the ethylene-α-olefin copolymer, an ethylene-based resin composition containing the ethylene-α-olefin copolymer, and a film containing the ethylene-α-olefin copolymer or the ethylene-based resin composition. An ethylene-α-olefin copolymer according to the present invention has: a monomer unit (1) based on ethylene; and a monomer unit (2) based on an α-olefin having 3 to 20 carbon atoms, wherein a branching parameter is 0.70 to 0.90, and a light scattering area ratio is 1.60 to 3.60.
ETHYLENE-alpha-OLEFIN COPOLYMER, METHOD OF PRODUCING ETHYLENE-alpha-OLEFIN COPOLYMER, ETHYLENE-BASED RESIN COMPOSITION, AND FILM
An ethylene-α-olefin copolymer capable of implementing formation of a film having excellent slipperiness and suppressed fish eyes, a method of producing the ethylene-α-olefin copolymer, an ethylene-based resin composition containing the ethylene-α-olefin copolymer, and a film containing the ethylene-α-olefin copolymer or the ethylene-based resin composition. An ethylene-α-olefin copolymer according to the present invention has: a monomer unit (1) based on ethylene; and a monomer unit (2) based on an α-olefin having 3 to 20 carbon atoms, wherein a branching parameter is 0.70 to 0.90, and a light scattering area ratio is 1.60 to 3.60.
Indacene Based Metallocene Catalysts Useful in the Production of Propylene Polymers
This invention relates homogeneous (typically solution) polymerization of propylene and optional olefin comonomer using metallocene catalyst compounds having a 1,5,6,7-tetrahydro-s-indacenyl moiety bridged to another indacenyl moiety or bridged to a substituted or unsubstituted indenyl moiety.
Indacene Based Metallocene Catalysts Useful in the Production of Propylene Polymers
This invention relates homogeneous (typically solution) polymerization of propylene and optional olefin comonomer using metallocene catalyst compounds having a 1,5,6,7-tetrahydro-s-indacenyl moiety bridged to another indacenyl moiety or bridged to a substituted or unsubstituted indenyl moiety.
Catalysts for Olefin Polymerization
The present disclosure provides catalyst compounds represented by Formula (I):
##STR00001##
where Q is OR.sup.13, SR.sup.13, NR.sup.13R.sup.14, PR.sup.13R.sup.14, or a heterocyclic ring; each R.sup.1-14 is independently hydrogen, C.sub.1-C.sub.40 hydrocarbyl, substituted C.sub.1-C.sub.40 hydrocarbyl, a heteroatom, or a heteroatom-containing group, or multiple R.sup.1-14 are joined together to form a C.sub.4-C.sub.62 cyclic, heterocyclic, or polycyclic ring structure, or combination(s) thereof; each X.sup.1 and X.sup.2 is independently C.sub.1-C.sub.20 hydrocarbyl, substituted C.sub.1-C.sub.20 hydrocarbyl, a heteroatom, or a heteroatom-containing group, or X.sup.1 and X.sup.2 join together to form a C.sub.4-C.sub.62 cyclic, heterocyclic, or polycyclic ring structure; and Y is a hydrocarbyl. The present disclosure also provides catalyst systems including an activator, a support, and a catalyst of the present disclosure. The present disclosure also provides polymerization processes including introducing olefin monomers to a catalyst system. Additionally, the present disclosure provides a polyolefin formed by a catalyst system or method of the present disclosure.