A composition for forming a dynamic crosslinked polymer network may comprise (a) a dynamic crosslinker having formula R—R″R′N—S—S—NR′R″—R, wherein each R is a polymerizable group comprising a carbon-carbon (C—C) double bond capable of undergoing free radical polymerization and each R′ and each R″ are independently selected alkyl groups; (b) a polymer comprising a C═C double bond capable of undergoing free radical polymerization, a monomer comprising a C═C double bond capable of undergoing free radical polymerization, or combinations thereof; and (c) a free radical initiator, wherein the dynamic crosslinker does not comprise a urethane group.

Disclosed herein are ethylene-based polymers generally characterized by a density of at least 0.94 g/cm.sup.3, a high load melt index from 4 to 20 g/10 min, a zero-shear viscosity at 190° C. from 20,000 to 400,000 kPa-sec, and a relaxation time at 190° C. from 225 to 3000 sec. These ethylene polymers can be produced by peroxide-treating a broad molecular weight distribution Ziegler-catalyzed resin, and can be used in large diameter, thick wall pipes and other end-use applications.

New polypropylene composition, which combines low sealing initiation temperature (SIT), high hot-tack and good optical properties, like low haze, the use of such polypropylene composition and articles made therefrom.

A process forming a high MFR polypropylene includes providing a reactor powder polypropylene, the reactor powder polypropylene having a melt flow rate of less than 100 dg/min. The process also includes mixing the reactor powder polypropylene with a free-radical initiator to form a powder/initiator mixture and subjecting the powder/initiator mixture to post-reactor forming. The present disclosure further provides for a vis-broken polypropylene and a polymer article.

Ethylene-based polymers are generally characterized by a high load melt index of less than 12 g/10 min, a weight-average molecular weight from 200,000 to 550,000 g/mol, a number-average molecular weight from 18,000 to 48,000 g/mol, a CY-a parameter of less than 0.12, a tan δ at 0.1 sec.sup.−1 from 0.5 to 0.9 degrees, a tan δ at 100 sec.sup.−1 from 0.5 to 0.75 degrees, and a viscosity at 0.001 sec.sup.−1 from 1.3×10.sup.6 to 1×10.sup.7 Pa-sec. These ethylene polymers can be produced by peroxide-treating a bimodal molecular weight distribution dual metallocene-catalyzed resin, and can be used to produce blow molded bottles and other blow molded products.

Ethylene-based polymers are generally characterized by a high load melt index of less than 12 g/10 min, a weight-average molecular weight from 200,000 to 550,000 g/mol, a number-average molecular weight from 18,000 to 48,000 g/mol, a CY-a parameter of less than 0.12, a tan δ at 0.1 sec.sup.−1 from 0.5 to 0.9 degrees, a tan δ at 100 sec.sup.−1 from 0.5 to 0.75 degrees, and a viscosity at 0.001 sec.sup.−1 from 1.3×10.sup.6 to 1×10.sup.7 Pa-sec. These ethylene polymers can be produced by peroxide-treating a bimodal molecular weight distribution dual metallocene-catalyzed resin, and can be used to produce blow molded bottles and other blow molded products.

Methods for processing LDPE recyclates including, but not limited to, polyethylene and polypropylene and compositions therefrom are provided. LDPE recyclate can be visbroken to improve processing characteristics and/or devolatilized to remove waste byproducts to produce processed LDPE recyclates. Processed LDPE recyclates are compounded with pre-consumer polyolefins to produce blend compositions having acceptable or even improved processing characteristics. Such pre-consumer polyolefins can also be visbroken to further tailor processing characteristics of such polymer blends. A combination of extruders and/or extruder zones can be used at the same or different locations for visbreaking and/or compounding of both LDPE recyclate and/or pre-consumer polyolefins.

Methods for processing HDPE and/or MDPE recyclates including, but not limited to, polyethylene and polypropylene and compositions therefrom are provided. HDPE and/or MDPE recyclate feedstocks can be visbroken to improve processing characteristics and/or devolatilized to remove waste byproducts to produce processed HDPE recyclate and/or processed MDPE recyclates. Processed HDPE recyclate and/or processed MDPE recyclates are compounded with pre-consumer polyolefins to produce blend compositions having acceptable or even improved processing characteristics. Such pre-consumer polyolefins can also be visbroken to further tailor processing characteristics of such polymer blends. A combination of extruders and/or extruder zones can be used at the same or different locations for visbreaking and/or compounding of both HDPE and/or MDPE recyclate and/or pre-consumer polyolefins.

Ethylene-based polymers are generally characterized by a high load melt index of less than 12 g/10 min, a weight-average molecular weight from 200,000 to 550,000 g/mol, a number-average molecular weight from 18,000 to 48,000 g/mol, a CY-a parameter of less than 0.12, a tan δ at 0.1 sec.sup.-1 from 0.5 to 0.9 degrees, a tan δ at 100 sec.sup.-1 from 0.5 to 0.75 degrees, and a viscosity at 0.001 sec.sup.-1 from 1.3 x 10.sup.6 to 1 x 10.sup.7 Pa-sec. These ethylene polymers can be produced by peroxide-treating a bimodal molecular weight distribution dual metallocene-catalyzed resin, and can be used to produce blow molded bottles and other blow molded products.

Ethylene-based polymers are generally characterized by a high load melt index of less than 12 g/10 min, a weight-average molecular weight from 200,000 to 550,000 g/mol, a number-average molecular weight from 18,000 to 48,000 g/mol, a CY-a parameter of less than 0.12, a tan δ at 0.1 sec.sup.-1 from 0.5 to 0.9 degrees, a tan δ at 100 sec.sup.-1 from 0.5 to 0.75 degrees, and a viscosity at 0.001 sec.sup.-1 from 1.3 x 10.sup.6 to 1 x 10.sup.7 Pa-sec. These ethylene polymers can be produced by peroxide-treating a bimodal molecular weight distribution dual metallocene-catalyzed resin, and can be used to produce blow molded bottles and other blow molded products.