Patent classifications
C08F2810/20
Process for modifying LDPE
Process for obtaining polyethylene with an MFI (190° C./2.16 kg) of at least 4 g/10 minutes and a melt strength (190° C.) of at least 8.0 cN, said process involving extrusion of low density polyethylene (LDPE) with an MFI of at least 5 g/10 minutes and a vinyl content of less than 0.25 terminal vinyl groups per 1000 C-atoms (measured with NMR in deuterated tetrachloroethane solution)—in the presence of 500-5,000 ppm, based on the weight of low density polyethylene, of an organic peroxide.
Gelation reagent for forming gel electrolyte and methods relating thereto
The present technology relates to gel electrolytes for using in lithium-ion electrochemical cells and methods of forming the same. For example, the method may include adding one or more gelation reagents to an electrochemical cell including one or more liquid electrolyte precursors. The one or more gelation reagents include one or more initiators and one or more crosslinking agents. Each of the one or more initiators may be one of a thermal initiator and an actinic/electron beam initiator. Each of the one or more crosslinking agents may be one of a tridentate alkane and a tetradentate alkane having one or more substitutes including a terminal group represented by: ##STR00001##
REACTIVE OLIGOMERS, ADDITIVE MANUFACTURING METHODS, AND ARTICLES THEREOF
A reactive oligomer has a backbone derived from at least one of polyamideimide, polyimide, polyetherimide, polyaryletherketone, polyethersulfone, polyphenylene sulfide, polyamide, polyester, polyarylate, polyesteramide, polycarbonate, polybenzoxazole or polybenzimidazole and functionalized with at least one unreacted functional group capable of thermal chain extension and crosslinking after formation of the reactive oligomer, wherein the reactive oligomer has an M.sub.n of about 250 to about 10,000 g/mol, calculated using the Carothers equation. Compositions comprising the reactive oligomer have at least one other component that includes a second reactive oligomer, an oligomer lacking unreacted functional groups capable of thermal chain extension and crosslinking, a thermoplastic polymer, a thermoplastic polymer having the same backbone repeat units as the reactive oligomer, a filler, or an additive. A method of manufacture of an article comprises heating a composition comprising the reactive oligomer at a sufficient temperature and time to shape and crosslink the reactive oligomer, including additive manufacturing.
Flame-retardant Antimicrobial Agent, Preparation Method therefor and Use thereof, and Flame-retardant Antimicrobial Thermoplastic Resin Composition
A flame-retardant antimicrobial agent is a polymer microsphere with the surface grafted thereof with a guanidine salt. The polymer microsphere has a cross-linked structure composed of a structural unit A derived from maleic anhydride, a structural unit B derived from a monomer M, and a structural unit C derived from a cross-linking agent. The monomer M is selected from a C.sub.4-C.sub.9 aliphatic olefin or a mixture thereof, and the guanidine salt comprises at least one guanidine salt having the property of flame resistance. The flame-retardant antimicrobial agent has both a good antimicrobial effect and a good flame-retardant effect. A flame-retardant antimicrobial thermoplastic resin composition containing the flame-retardant antimicrobial agent also has a good flame-retardant and antimicrobial performance and a good overall performance.
METHOD FOR PRODUCING MODIFIED CONJUGATED DIENE-BASED POLYMER, POLYMER COMPOSITION, CROSS-LINKED PRODUCT, AND TIRE
A method for producing a modified conjugated diene-based polymer includes polymerizing a monomer including a conjugated diene compound in the presence of an alkali metal compound or an alkali earth metal compound to obtain a polymer having an active terminal; (a modification) reacting the polymer having an active terminal with a compound [M] having a plurality of hydrocarbyloxysilyl groups to obtain a modified polymer; and a mixing the modified polymer with at least one compound [C] selected from a compound [N] having one hydrocarbyloxysilyl group and an alcohol having 6 to 20 carbon atoms.
ETHYLENE/ALPHA-OLEFIN INTERPOLYMER BASED COMPOSITIONS WITH IMPROVED BALANCE OF CURE AND PROCESSABILITY
A composition comprising the following components a)-c): a) an alpha composition comprising a multimodal ethylene/alpha-olefin interpolymer, and wherein the alpha composition comprises the following properties: i) an Mz/Mn≥8.0, ii) a density from 0.855 to 0.890 g/cc, iii) a V100 (100° C.)≤2,000 Pa.Math.s, iv) a V1.0 (100° C.)≥15,000 Pa.Math.s, v) a Mn≥16,000 g/mol; b) a peroxide; and c) a silane coupling agent.
Water-absorbing resin
Provided is a water-absorbent resin which is capable of giving an absorbent material improved gel-shape stability and which has excellent water-absorption capacity. A water-absorbent resin of the present invention is a polymer of a water-soluble ethylenically unsaturated monomer, and has the following properties (1) and (2): (1) A disintegration amount at 20-fold swelling is 30% by mass or less; and (2) a solubility in physiological saline is 25% by mass or less. (Determination Method for Disintegration Amount at 20-Fold Swelling) 5 g of the water-absorbent resin is added to 100 g of physiological saline to allow the water-absorbent resin to absorb the physiological saline, thereby obtaining a gel. The obtained gel is divided approximately equally into five portions, and these portions are introduced respectively into cylindrical molds having a length of 3.6 cm and a radius of 2.8 cm and molded. The masses of the five molded cylindrical gels are measured. The heaviest and the lightest of the five gels are removed, and the remaining three gels are used as samples. A mass Wa (g) of each sample is measured. Each weighed sample is placed on the uppermost sieve of a combination of JIS standard sieves having a mesh size of 5.6 mm and a receptacle in this order and shaken for 10 minutes using a Ro-Tap shaker (rotation speed, 290 rpm; number of taps, 165 rpm). A mass Wb (g) of the gel which has passed through the sieves is measured. The disintegration amount of each sample is calculated using the following equation: Disintegration amount of sample (%)=Wb (g)/Wa (g)×100. An average of the disintegration amounts for three samples to be measured is regarded as the disintegration amount at 20-fold swelling of the water-absorbent resin.
HYDROCARBON SWELLING PARTICLES FOR WELLBORE CEMENTING
Hydrocarbon swelling particles for wellbore cementing include a crosslinked polymer comprising vinyl aromatic monomer and/or (meth)acrylic monomer.
ARTICLE AND METHOD OF MAKING ARTICLE
An article includes a polymer. The polymer includes a product of a crosslinking reaction including at least one cross-linker selected from the group consisting of: a) di-acrylates, tri-acrylates, and tetra-acrylates; b) modified tri-acrylates and tetra-acrylates; c) silanes and siloxanes; and d) triazinane-triones.
Bimodal polyethylene resins and pipes produced therefrom
Disclosed herein are ethylene-based polymers generally characterized by a density of at least 0.94 g/cm.sup.3, a high load melt index from 4 to 20 g/10 min, a zero-shear viscosity at 190° C. from 20,000 to 400,000 kPa-sec, and a relaxation time at 190° C. from 225 to 3000 sec. These ethylene polymers can be produced by peroxide-treating a broad molecular weight distribution Ziegler-catalyzed resin, and can be used in large diameter, thick wall pipes and other end-use applications.