The present invention relates to a production method of a poly(ester)carbonate, including subjecting a diol and a carbonate ester to a transesterification reaction in the presence of a catalyst, wherein the catalyst comprises aluminum or a compound thereof, and a phosphorus compound.

Provided is a polycarbonate of Chemical Formula 1: ##STR00001## wherein in Chemical Formula 1: Ar is C.sub.6-60 arylene unsubstituted or substituted with C.sub.1-10 alkyl; and n and m are each independently an integer from 1 to 50, provided that n+m is 2 or more, and a preparation method thereof.

To provide an epoxy resin composition that exhibits excellent low-dielectric properties and that is excellent in copper foil peel strength and interlayer cohesion strength in a printed-wiring board application, as well as an active ester resin that provides the epoxy resin composition. An active ester resin having a polyaryloxy unit containing a dicyclopentenyl group and represented by the following formula (1), and a polyarylcarbonyl unit. Here, R.sup.1 represents a hydrocarbon group having 1 to 8 carbon atoms, R.sup.2 represents a hydrogen atom, or formula (1a) or formula (1b), and at least one R.sup.2 is formula (1a) or formula (1b); and n represents a number of repetitions of 1 to 5.

##STR00001##

To provide an epoxy resin composition that exhibits excellent low-dielectric properties and that is excellent in copper foil peel strength and interlayer cohesion strength in a printed-wiring board application, as well as an active ester resin that provides the epoxy resin composition. An active ester resin having a polyaryloxy unit containing a dicyclopentenyl group and represented by the following formula (1), and a polyarylcarbonyl unit. Here, R.sup.1 represents a hydrocarbon group having 1 to 8 carbon atoms, R.sup.2 represents a hydrogen atom, or formula (1a) or formula (1b), and at least one R.sup.2 is formula (1a) or formula (1b); and n represents a number of repetitions of 1 to 5.

##STR00001##

The present invention relates to a process for preparing a polyester carbonate on the basis of cycloaliphatic diacids and at least one 1,4:3,6-dianhydrohexitol and at least one additional aliphatic dihydroxy compound, to the polyester carbonate prepared according to the process and to a molding compound and a molding body containing the polyester carbonate. The process according to the invention is a direct synthesis, in which all structural elements forming the subsequent polyester carbonate are present as monomers already in the first process step. It is characterized in that a specific ratio of 1,4:3,6-dianhydrohexitol and the at least one additional aliphatic dihydroxy compound is advantageous.

Processes for making a fluid conduits and fluid conduits made thereby are disclosed. The fluid conduits include a mono-layer formed of at least 80 wt %, based on total weight of the mono-layer, of a thermoplastic elastomer in an amount of at least 80 wt % with respect to the total weight of the mono-layer. The thermoplastic elastomer is preferably a block copolymer elastomer formed of hard segments (e.g., polyesters, polyamides and/or polyurethanes) and soft segments (e.g., aliphatic polyethers, aliphatic polyesters and/or aliphatic polycarbonates) and exhibits a melt flow rate measured at 230° C. under a load of 10 kg (MFR 230° C./10 kg), according to ISO1133 (2011) of at most 40 g/10 min and having a heat resistance of at least 250 hours at 175° C. at which the elongation at break remains at least 100% as measured according to ISO 527 with a test speed of 50 mm/min.

Processes for making a fluid conduits and fluid conduits made thereby are disclosed. The fluid conduits include a mono-layer formed of at least 80 wt %, based on total weight of the mono-layer, of a thermoplastic elastomer in an amount of at least 80 wt % with respect to the total weight of the mono-layer. The thermoplastic elastomer is preferably a block copolymer elastomer formed of hard segments (e.g., polyesters, polyamides and/or polyurethanes) and soft segments (e.g., aliphatic polyethers, aliphatic polyesters and/or aliphatic polycarbonates) and exhibits a melt flow rate measured at 230° C. under a load of 10 kg (MFR 230° C./10 kg), according to ISO1133 (2011) of at most 40 g/10 min and having a heat resistance of at least 250 hours at 175° C. at which the elongation at break remains at least 100% as measured according to ISO 527 with a test speed of 50 mm/min.

A bio-based polycarbonate ester resin is environment friendly by not containing a bisphenol, and exhibits excellent heat resistance, transparency, strength, hardness, dimensional stability and chemical resistance. Thus, the bio-based polycarbonate ester resin is suitable for use in an eyeglass frame. In addition, various colors may be painted and coated on during post-processing, a separate additive is not required during a molding process, and processing is undergone at a temperature lower than that for conventional plastic materials for an eyeglass frame, and thus manufacturing costs may be reduced.

A bio-based polycarbonate ester resin is environment friendly by not containing a bisphenol, and exhibits excellent heat resistance, transparency, strength, hardness, dimensional stability and chemical resistance. Thus, the bio-based polycarbonate ester resin is suitable for use in an eyeglass frame. In addition, various colors may be painted and coated on during post-processing, a separate additive is not required during a molding process, and processing is undergone at a temperature lower than that for conventional plastic materials for an eyeglass frame, and thus manufacturing costs may be reduced.

Novel surgical sutures and novel medical devices made from novel semi-crystalline, glycolide-rich A-B-A triblock copolymers of glycolide and lactide, wherein said B-segment is a fully amorphous random copolymer of glycolide and lactide, for long term medical applications are disclosed. The novel polymer compositions are useful for long term absorbable surgical sutures, meshes and other medical devices, especially for patients with compromised healing. The novel sutures have improved properties and improved breaking strength retention, while still substantially absorbing within about a 120-day period post-implantation.