The disclosure relates to methods of capturing carbon by microbial fermentation of a gaseous substrate comprising CO into one or more first products which, in turn, may be incorporated into an article of manufacture or one or more second products. Further, the disclosure relates to improving carbon capture and/or efficiency.

The disclosure relates to methods of capturing carbon by microbial fermentation of a gaseous substrate comprising CO into one or more first products which, in turn, may be incorporated into an article of manufacture or one or more second products. Further, the disclosure relates to improving carbon capture and/or efficiency.

A method for synthesizing an aliphatic polyester block copolymer regulated by carbon monoxide. The method uses an organic cobalt metal complex as a convertible catalyst and includes: first regulating an anionic ring-opening copolymerization reaction between an aliphatic acid anhydride and an epoxy compound; then using carbon monoxide as a conversion agent for conversion to obtain a catalyst having a new catalytic active site; and regulating a vinyl monomer to perform active free radical polymerization to obtain an aliphatic polyester block copolymer having a controllable structure. The described synthesis method uses a convertible catalyst and a conversion agent, combines two controllable polymerization reactions which have different but compatible mechanisms, and obtains a block copolymer by means of a “one-pot” reaction.

A method for synthesizing an aliphatic polyester block copolymer regulated by carbon monoxide. The method uses an organic cobalt metal complex as a convertible catalyst and includes: first regulating an anionic ring-opening copolymerization reaction between an aliphatic acid anhydride and an epoxy compound; then using carbon monoxide as a conversion agent for conversion to obtain a catalyst having a new catalytic active site; and regulating a vinyl monomer to perform active free radical polymerization to obtain an aliphatic polyester block copolymer having a controllable structure. The described synthesis method uses a convertible catalyst and a conversion agent, combines two controllable polymerization reactions which have different but compatible mechanisms, and obtains a block copolymer by means of a “one-pot” reaction.

The present invention relates to a polyester consisting of (A) repeat units derived from an acid component, which consists of (a1) 2,5-furandicarboxylic acid, (a2) an aliphatic C.sub.4-C.sub.36 dicarboxylic acid or a mixture of a plurality of aliphatic C.sub.4-C.sub.36 dicarboxylic acids, and (a3) a sulfonate group-containing dicarboxylic acid, and of (B) repeat units derived from a di-ol/amine component, and optionally of further repeat units (C) and/or branching components (E), and of (D) repeat units derived from at least one di- or oligofunctional compound selected from the group consisting of a di- or oligoisocyanate and a di- or oligoisocyanurate. In addition, the present invention relates to the production of these polyesters and their use.

The present invention relates to a polyester consisting of (A) repeat units derived from an acid component, which consists of (a1) 2,5-furandicarboxylic acid, (a2) an aliphatic C.sub.4-C.sub.36 dicarboxylic acid or a mixture of a plurality of aliphatic C.sub.4-C.sub.36 dicarboxylic acids, and (a3) a sulfonate group-containing dicarboxylic acid, and of (B) repeat units derived from a di-ol/amine component, and optionally of further repeat units (C) and/or branching components (E), and of (D) repeat units derived from at least one di- or oligofunctional compound selected from the group consisting of a di- or oligoisocyanate and a di- or oligoisocyanurate. In addition, the present invention relates to the production of these polyesters and their use.

The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use.

The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.

The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use.

The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.

A method for producing a polyhydroxyalkanoate, the method including: (a) preparing an aqueous polyhydroxyalkanoate suspension having a pH of not more than 5; (b) mixing the aqueous suspension obtained in (a) with a water-insoluble organic solvent having a specific gravity of more than 1.0 g/mL; (c) separating a mixed solution obtained in (b) into a water-insoluble organic solvent phase and an aqueous phase by centrifugal separation, and then removing the aqueous phase; and (d) heating the water-insoluble organic solvent phase obtained in (c), and then cooling the water-insoluble organic solvent phase to obtain a gelatinous polyhydroxyalkanoate.

The present invention relates to methods for the preparation of high molecular weight polyhydroxybutyrate (PHB) by culturing Bacillus megaterium strains in a mixture of agri-food wastes, PHB obtained or obtainable by the methods as well as to its use in the preparation of articles such as, for example, soles and/or heels for shoes.