Patent classifications
C08G64/02
POLYESTER ELASTOMER RESIN COMPOSITION
The present invention is a polyester elastomer resin composition that has excellent extrusion moldability and surface smoothness even in a thin shape, while maintaining mechanical characteristics, and that is halogen-free and has excellent flame retardancy as well as heat aging resistance and hydrolysis resistance. The polyester elastomer resin composition comprises a polyester elastomer (A) and a phosphorus flame retardant (B); the polyester elastomer (A) comprises a hard segment composed of a polyester and at least one soft segment selected from aliphatic polyethers, aliphatic polyesters, and aliphatic polycarbonates, and has a Shore D surface hardness of 55 or less; the phosphorus flame retardant (B) has an average particle size D50 of 20 μm or less and a phosphorus concentration of 15 mass % or more; and the polyester elastomer resin composition comprises 5 to 50 parts by mass of the phosphorus flame retardant (B) and optionally a predetermined amount of an acid end capping agent (C) based on 100 parts by mass of the polyester elastomer (A), and has an acid value of 10 eq/ton or less.
POLYESTER ELASTOMER RESIN COMPOSITION
The present invention is a polyester elastomer resin composition that has excellent extrusion moldability and surface smoothness even in a thin shape, while maintaining mechanical characteristics, and that is halogen-free and has excellent flame retardancy as well as heat aging resistance and hydrolysis resistance. The polyester elastomer resin composition comprises a polyester elastomer (A) and a phosphorus flame retardant (B); the polyester elastomer (A) comprises a hard segment composed of a polyester and at least one soft segment selected from aliphatic polyethers, aliphatic polyesters, and aliphatic polycarbonates, and has a Shore D surface hardness of 55 or less; the phosphorus flame retardant (B) has an average particle size D50 of 20 μm or less and a phosphorus concentration of 15 mass % or more; and the polyester elastomer resin composition comprises 5 to 50 parts by mass of the phosphorus flame retardant (B) and optionally a predetermined amount of an acid end capping agent (C) based on 100 parts by mass of the polyester elastomer (A), and has an acid value of 10 eq/ton or less.
GLYCEROL-BASED POLYCARBONATES
The invention provides polymer compositions, compounds, processes, and methods of use of the polymers for drug delivery, biodegradable consumer plastics, or solvents for Li-based batteries or supercapacitors. The invention is based, at least in part, on the discovery that poly(glyceric acid carbonate)s and alkyl functionalized poly(1,2 glycerol carbonates) and poly(glyceric acid carbonate)s and pharmaceutical agent/composition functionalized poly(1,2 glycerol carbonates) and poly(glyceric acid carbonate)s represent a new type of glycerol based polymer that 1) degrade into glycerol and carbon dioxide; 2) the poly(1,2 glycerol carbonates) degrade more readily than conventional poly(1,3 glycerol carbonates; and 3) poly(1,2 glycerol carbonates) can be processed to give melts, viscous fluids, liquids, films, sheets, gels, meshes, foams, fibers, or particles.
POLYCARBONATE RESIN, POLYCARBONATE RESIN COMPOSITION, OPTICAL MOLDED ARTICLE COMPRISING SAME, AND CYCLIC CARBONATE
A polycarbonate resin comprising a structural unit represented by the following formula (1), wherein weight-average molecular weight Mw measured by size-exclusion chromatography using polymethyl methacrylate as a standard sample is 50,000 or larger and 500,000 or smaller:
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Polyhydroxy ketal ester adducts, methods of manufacture and uses thereof
Disclosed herein is a polyhydroxy ketal adduct obtained by the esterification of a hydrocarbon polyol by at least 1.5 equivalents of a ketocarboxy to produce an intermediate ketocarboxylic ester. The intermediate polyketocarboxylic ester is then ketalized to produce the polyhydroxyketal adduct, which can be used to provide a polymeric composition.
Recyclable polymers from environmentally benign building blocks
Disclosed herein are embodiments of a method for making recyclable polymers and a method for decomposing the polymers back to the monomers which can then be reused. The polymer are stable to aqueous and/or acid conditions and may have a formula II ##STR00001## The method to decompose the polymer back to the monomers may comprise heating the polymer in a protic organic solvent.
ASTAXANTHIN BASED POLYMER AND USES THEREOF
Provided are polymers having a repeating unit including at least one astaxanthin moiety. Also provided are processes for preparing the polymers and various uses thereof.
SUBSTRATE WITH CONDUCTIVE FILM
A substrate with conductive film includes a base material; and a film of a conductive metal oxide arranged on an upper part of the base material. The film includes, by a top plan view, a first region and a second region, the second region is configured of a same material as the first region, and an electric resistance of the second region is higher than an electric resistance of the first region. The second region includes a part configured by a plurality of cellular sections surrounded by a plurality of fine cracks. In the part, each fine crack has a width of 1 nm to 50 nm, and each cellular section has a largest measure of less than 10 μm.
Thermoplastic resin and optical member
The purpose of the present invention is to provide a thermoplastic resin that has a high refractive index and enables low birefringence and balanced heat resistance and moldability. This thermosetting resin includes repeating units represented by formula (1). (In the formula, the rings Z are the same or different and represent an aromatic hydrocarbon ring, R.sup.1 and R.sup.2 independently represent a C1-C12 hydrocarbon group optionally including a hydrogen atom, a halogen atom, and an aromatic group, Ar.sup.1 and Ar.sup.2 represent a C6-C10 aromatic group optionally having a substituent, L.sup.1 and L.sup.2 independently represent a divalent linking group, j and k independently represent an integer of 0 or more, m and n independently represent 0 or 1, and W is at least one selected from the groups represented by formulae (2) and (3).) (In the formula, X represents a divalent linking group.)
Methods for making functionalized fluorinated monomers, fluorinated monomers, and compositions for making the same
A method of making a functionalized fluorinated monomer for use in making oligomers and polymers that can be used to improve surface properties of polymer-derived systems, such as coatings. The method of making a functionalized fluorinated monomer includes reacting at least one fluorinated nucleophilic reactant, such as a fluorinated alcohol, with at least one compound containing at least one epoxide group. Other methods include reaction of a fluorinated alcohol with a cyclic carboxylic anhydride. In another embodiment, a method includes reacting a fluorinated mesylate, tosylate or triflate with an amine, alkoxide or phenoxide. In other embodiments, the method includes reacting a fluorinated alcohol with an alkyl halide, or reacting a fluorinated alkyl halide with an amine. The functionalized fluorinated monomers may be used as intermediates and reacted to modify the functional groups thereon. Further, the functionalized fluorinated monomers may be reacted to form polymers or oligomers, or with polymers or oligomers having functional groups to modify the polymer or oligomer through the functional group thereon.