A synthetic resin laminated sheet, in which whitening, cracking, and foaming do not occur when thermoforming is carried out, in particular when deep-draw molding is carried out, and defects do not occur during lamination of a hard coating layer; and a molded article obtained by molding the laminated sheet. A synthetic resin laminated sheet has a coating layer, which includes an acrylic resin, laminated on one surface of a substrate layer including a polycarbonate resin in which a monohydric phenol represented by general formula (1) is used as a chain terminator and is obtained by reacting the monohydric phenol with a dihydric phenol and a carbonate binding agent and has a viscosity average molecular weight of 18000-35000. (In the formula, R1 represents a C8-36 alkyl group or a C8-36 alkenyl group. R2-R5 each represent hydrogen, halogen, or an optionally substituted C1-20 alkyl group or C6-12 aryl group).

##STR00001##

Provided is a polycarbonate-based resin composition, including a polycarbonate-based resin composition (A) including: 90 mass % to 10 mass % of a polycarbonate-polyorganosiloxane copolymer (A-1); and 10 mass % to 90 mass % of a recycled material (A-2) containing a polycarbonate-based resin, in which a content of a polyorganosiloxane block moiety in the polycarbonate-based resin composition is from 0.7 mass % to 40 mass %.

Provided is a polycarbonate-based resin composition, including a polycarbonate-based resin composition (A) including: 90 mass % to 10 mass % of a polycarbonate-polyorganosiloxane copolymer (A-1); and 10 mass % to 90 mass % of a recycled material (A-2) containing a polycarbonate-based resin, in which a content of a polyorganosiloxane block moiety in the polycarbonate-based resin composition is from 0.7 mass % to 40 mass %.

In an embodiment, a method for producing an aryl alkyl carbonate can comprise: reacting methanol with a diaryl carbonate in the presence of a catalyst to form a mixture comprising an aryl alkyl carbonate and a hydroxy compound, wherein the methanol is in an acetone monomer mixture comprising acetone and at least one of diaryl carbonate and dihydroxy compound; separating the aryl alkyl carbonate from the mixture.

Provided is a polycarbonate resin having excellent solubility in low-boiling-point non-halogenated solvents and having a high glass transition temperature. The polycarbonate resin includes constituent units (A) represented by general formula (1) and constituent units (B) represented by general formula (2), the molar ratio of the constituent units (A) to the constituent units (B), A/B, being 45/55 to 95/5.

##STR00001##

A process for purifying a diaryl carbonate, comprises introducing an aqueous stream to a diaryl carbonate stream that comprises a metal contaminant, wherein the aqueous stream reacts with the metal contaminant to form a precipitate; wherein introducing the aqueous stream to the diaryl carbonate stream results in introducing 100 to 10,000 ppm water based on the total composition of the diaryl carbonate stream and the aqueous stream; removing the precipitate via one or both of a separation column and a filter to result in a purified diaryl carbonate.

A process for purifying a diaryl carbonate, comprises introducing an aqueous stream to a diaryl carbonate stream that comprises a metal contaminant, wherein the aqueous stream reacts with the metal contaminant to form a precipitate; wherein introducing the aqueous stream to the diaryl carbonate stream results in introducing 100 to 10,000 ppm water based on the total composition of the diaryl carbonate stream and the aqueous stream; removing the precipitate via one or both of a separation column and a filter to result in a purified diaryl carbonate.

In one embodiment, a light emitting device includes a lighting element located in a housing, wherein the housing is formed from a plastic composition including, for example, a polycarbonate formed from reacting, in the presence of a transesterification catalyst, a diaryl carbonate ester and a bisphenol A, wherein the bisphenol A has a sulfur concentration of 1 ppm to 15 ppm, based upon a weight of the bisphenol A; and a conversion material wherein the conversion material includes an inorganic material that converts radiation of a certain wavelength and re-emits of a different wavelength; wherein after the conversion material has been exposed to an excitation source, the conversion material has a luminescence lifetime of less than 10.sup.−4 seconds when the excitation source is removed.

Provided is a polycarbonate-based resin composition, including: 50 mass % or more to 99 mass % or less of a polycarbonate-based resin (S) containing 0.1 mass % or more to 100 mass % or less of a polycarbonate-polyorganosiloxane copolymer (A), which contains a polycarbonate block (A-1) formed of a specific repeating unit and a polyorganosiloxane block (A-2) containing a specific repeating unit, and 0 mass % or more to 99.9 mass % or less of an aromatic polycarbonate-based resin (B) except the polycarbonate-polyorganosiloxane copolymer (A); 1 mass % or more to 50 mass % or less of a polyester-based resin (C); and 0.001 part by mass or more to 1 part by mass or less of an amide compound (D) with respect to 100 parts by mass of a total amount of the polycarbonate-based resin (S) and the polyester-based resin (C).

Provided is a polycarbonate-based resin composition, including: 50 mass % or more to 99 mass % or less of a polycarbonate-based resin (S) containing 0.1 mass % or more to 100 mass % or less of a polycarbonate-polyorganosiloxane copolymer (A), which contains a polycarbonate block (A-1) formed of a specific repeating unit and a polyorganosiloxane block (A-2) containing a specific repeating unit, and 0 mass % or more to 99.9 mass % or less of an aromatic polycarbonate-based resin (B) except the polycarbonate-polyorganosiloxane copolymer (A); 1 mass % or more to 50 mass % or less of a polyester-based resin (C); and 0.001 part by mass or more to 1 part by mass or less of an amide compound (D) with respect to 100 parts by mass of a total amount of the polycarbonate-based resin (S) and the polyester-based resin (C).