C08G64/16

POLYCARBONATE RESIN COMPOSITION OR COPOLYMER, AND OPTICAL FILM
20220135795 · 2022-05-05 · ·

A polycarbonate resin composition or a copolymer, comprising, as main repeating units, a carbonate unit (a-1) having a fluorene ring in a side chain, a carbonate unit (a-2) represented by the following formula (a-2):

##STR00001##

(wherein W represents an alkylene group having 1 to 20 carbon atoms or a cycloalkylene group having 6 to 20 carbon atoms, R represents a branched or linear-chain alkyl group having 1 to 20 carbon atoms or a cycloalkyl group having 6 to 20 carbon atoms optionally having a substituent, and u represents an integer of 0 to 3), and a carbonate unit (a-3) derived from 2,2-bis(4-hydroxyphenyl)propane, wherein 1) a molar ratio of the carbonate unit (a-1) to the carbonate unit (a-2) is from 50/50 to 80/20, and 2) a molar ratio of the total of the carbonate unit (a-1) and the carbonate unit (a-2) to the carbonate unit (a-3) is from 1:99 to 70:30. This polycarbonate resin composition or copolymer has excellent heat resistance, transparency, and bending resistance and has low retardation.

POLYCARBONATE RESIN COMPOSITION OR COPOLYMER, AND OPTICAL FILM
20220135795 · 2022-05-05 · ·

A polycarbonate resin composition or a copolymer, comprising, as main repeating units, a carbonate unit (a-1) having a fluorene ring in a side chain, a carbonate unit (a-2) represented by the following formula (a-2):

##STR00001##

(wherein W represents an alkylene group having 1 to 20 carbon atoms or a cycloalkylene group having 6 to 20 carbon atoms, R represents a branched or linear-chain alkyl group having 1 to 20 carbon atoms or a cycloalkyl group having 6 to 20 carbon atoms optionally having a substituent, and u represents an integer of 0 to 3), and a carbonate unit (a-3) derived from 2,2-bis(4-hydroxyphenyl)propane, wherein 1) a molar ratio of the carbonate unit (a-1) to the carbonate unit (a-2) is from 50/50 to 80/20, and 2) a molar ratio of the total of the carbonate unit (a-1) and the carbonate unit (a-2) to the carbonate unit (a-3) is from 1:99 to 70:30. This polycarbonate resin composition or copolymer has excellent heat resistance, transparency, and bending resistance and has low retardation.

Carrier for bio-related molecule immobilization

The present invention relates to a carrier for bio-related molecule immobilization, which comprises a resin substrate, an amino group-containing compound layer that is formed on the resin substrate, and a polyvalent carboxylic acid layer that is formed on the amino group-containing compound layer. The carboxyl groups in the polyvalent carboxylic acid layer are actively esterified; and the (COO peak intensity)/(C—C peak intensity) ratio of the C1s spectrum is from 0.064 to 0.12 (inclusive) if the carrier surface before the active esterification is measured by X-ray photoelectron spectroscopy. The present invention also relates to a carrier for bio-related molecule immobilization, which comprises a water repellent resin substrate, an aminoalkyl silane layer that is formed on the resin substrate and a polyvalent carboxylic acid layer that is formed on the aminoalkyl silane layer, and which is characterized in that: the carboxyl groups in the polyvalent carboxylic acid layer are actively esterified; and the resin substrate is exposed after the formation of the aminoalkyl silane layer.

POST POLYMERIZATION MODIFICATION IN FLOW

Techniques regarding post polymerization modifications to polycarbonate polymers via a flow reactor are provided. For example, one or more embodiments described herein can comprise a cyclic carbonate monomer that can be employed to facilitate polymerization of one or more polycarbonate platforms susceptible to post polymerization modification. For instance, one or more embodiments can regard a cyclic carbonate molecular backbone covalently bonded to an aryl halide functional group via in accordance with a chemical structure selected from the group consisting of:

##STR00001##

In the chemical structures, “R.sub.1” can be selected from the group consisting of a hydrogen atom and a functional group comprising a first alkyl group; “L” can represent a linkage group, comprising: a second alkyl group and an end group having at least one member selected from the group consisting of an oxygen atom and a nitrogen atom; and “A” can represent the aryl halide functional group.

Compound, resin, polycarbonate resin, and optical molded article

Provided is a compound represented by General Formula (1) ##STR00001## in General Formula (1), Ar.sub.1 and Ar.sub.2 independently represent a group selected from the following Formulae, ##STR00002##

COMPOUND, RESIN, POLYCARBONATE RESIN, AND OPTICAL MOLDED ARTICLE

Provided is a compound represented by General Formula (1)

##STR00001##

in General Formula (1), Ar.sub.1 and Ar.sub.2 independently represent a group selected from the following Formulae,

##STR00002##

##STR00003##

##STR00004##

##STR00005##

##STR00006##

##STR00007##

##STR00008##

##STR00009##

##STR00010##

##STR00011##

##STR00012##

##STR00013##

##STR00014##

##STR00015##

MONOMER COMPOSITION FOR SYNTHESIZING RECYCLED PLASTIC, PREPARATION METHOD THEREOF, RECYCLED PLASTIC, AND MOLDED PRODUCT USING THE SAME

The present disclosure relates to a monomer composition for synthesizing recycled plastic that contains a high-purity aromatic diol compound recovered through recycling by chemical decomposition of a polycarbonate-based resin, a method for preparing the same, and a recycled plastic and molded product using the same. Also, the present disclosure relates to a monomer composition for synthesizing recycled plastic that contains a by-product with a high added value recovered through recycling by chemical decomposition of a polycarbonate-based resin, a method for preparing the same, and a recycled plastic and molded product using the same.

MONOMER COMPOSITION FOR SYNTHESIZING RECYCLED PLASTIC, PREPARATION METHOD THEREOF, RECYCLED PLASTIC, AND MOLDED PRODUCT USING THE SAME

The present disclosure relates to a monomer composition for synthesizing recycled plastic that contains a high-purity aromatic diol compound recovered through recycling by chemical decomposition of a polycarbonate-based resin, a method for preparing the same, and a recycled plastic and molded product using the same. Also, the present disclosure relates to a monomer composition for synthesizing recycled plastic that contains a by-product with a high added value recovered through recycling by chemical decomposition of a polycarbonate-based resin, a method for preparing the same, and a recycled plastic and molded product using the same.

RESIN PRODUCED BY POLYCONDENSATION, AND RESIN COMPOSITION

A polyester carbonate resin is provided, which includes a structural unit derived from a compound represented by general formula (1), a structural unit derived from a compound represented by general formula (2), a structural unit derived from a dicarboxylic acid or a derivative thereof, and a structural unit derived from a carbonic acid diester. The polyester carbonate can be used, e.g., in optical systems.

##STR00001##

POLYCARBONATE RESIN

Provided is a polycarbonate resin having a structural unit (I) represented by formula (1) below:

##STR00001##

wherein L.sup.1 and L.sup.2 each independently represent a divalent linking group selected from an alkylene group, a cycloalkylene group, an arylene group, an oxyalkylene group, an oxyarylene group, and a group formed by combining two or more of these, where one or more hydrogen atoms of the linking group are optionally further replaced with substituents, and two of the substituents are optionally bonded to each other to form a ring structure.