Provided is a method of producing a polycarbonate-based resin composition, including mixing an aliphatic polycarbonate-based resin (A) containing a specific repeating unit (A-1), and at least one kind of aromatic thermoplastic resin (S) selected from the group consisting of an aromatic polycarbonate-based resin (B) containing a polycarbonate block formed of a specific repeating unit, an aromatic polyester-based resin (C) having a specific structural unit, and a polyarylate resin (D) having a specific structural unit in the presence of a transesterification catalyst at a temperature at which the resin components melt.

A foamable poly carbonate composition comprising 5 to 95 wt % of a poly(siloxane) block copolymer comprising a poly(carbonate-siloxane) comprising 50 to 99 wt % of bisphenol A carbonate units and 1 to 50 wt % of dimethylsiloxane units, each based on the weight of the poly(carbonate-siloxane), a poly(ester-carbonate-siloxane) comprising bisphenol A carbonate units, isophthalate-terephthalate-bisphenol A ester units, and 5 to 200 dimethyl siloxane units, or a combination thereof; 5 to 95 wt % of an auxiliary component comprising a poly(alkylene ester), a poly(ester-carbonate), or a combination thereof, and optionally, a homopolycarbonate; optionally, up to 10 wt % of an additive composition, wherein the composition has a glass transition temperature of 140° C. and below measured using differential scanning calorimetry, and wherein a foamed sample of the composition has an average cell size of 10 nanometers to 20 micrometers.

Provided is a high molecular weight aromatic polycarbonate resin manufacturing method that suppresses the occurrence of heterogeneous structures and can achieve a sufficiently high molecular weight. A high molecular weight aromatic polycarbonate resin manufacturing method including: a step in which a dialcohol compound expressed by general formula (1) and a catalyst are mixed to obtain a catalyst composition; a step in which the obtained catalyst composition is transferred to a prepolymer mixing tank via a transfer pipe, with a transfer period of 10 hours or less; a step in which the transferred catalyst composition and an aromatic polycarbonate prepolymer are mixed in the prepolymer mixing tank to obtain a prepolymer mixture; and a high molecular weight achievement step in which the obtained prepolymer mixture is heat-treated under reduced pressure conditions to obtain a high molecular weight aromatic polycarbonate resin.

Provided is a polycarbonate resin composition containing polycarbonate resin (A) having structural units represented by general formula (1) and polycarbonate resin (B) having a structural unit represented by general formula (2): ##STR00001##
(in general formula (1), R represents a hydrogen atom or C.sub.1-C.sub.4 alkyl group); ##STR00002##
(in general formula (2), R.sup.1 and R.sup.2 each independently represent a hydrogen atom, C.sub.1-C.sub.20 alkyl group, C.sub.1-C.sub.20 alkoxyl group, C.sub.5-C.sub.20 cycloalkyl group, C.sub.5-C.sub.20 cycloalkoxyl group, C.sub.6-C.sub.20 aryl group or C.sub.6-C.sub.20 aryloxy group, and Y represents a C.sub.1-C.sub.4 alkylene group.)

A polycarbonate resin composition containing 0.1 to 10 parts by mass of a polycarbonate copolymer (B) having carbonate bonding between (B1) bisphenol A and a (B2) polyalkylene glycol and 0.005 to 0.5 parts by mass of a phosphorus-containing stabilizer (C) relative to 100 parts by mass of a polycarbonate resin (A).

Provided are a polycarbonate having an appropriate refractive index and an appropriate Abbe number, and comprehensively excelling in heat resistance, total light transmittance, and hue, and a molded article thereof. The polycarbonate includes a constituent unit represented by Formula [I] and a constituent unit having a hydrocarbon group containing a cyclic structure. In Formula [I], R.sup.1 and R.sup.2 each independently denote a hydrocarbon group, and each R.sup.3 independently denotes a hydrogen atom, a heteroatom-containing group, a halogen atom-containing group, a linear alkyl group having from 1 to 6 carbon atoms, a branched alkyl group having from 3 to 6 carbon atoms, or a group including an aryl group and having from 6 to 12 carbon atoms.

##STR00001##

##STR00001##

The purpose of the present invention is to provide a high temperature/humidity resistant polycarbonate resin without using bisphenol A as a raw material. The present invention relates to a polycarbonate resin comprising the repeating units of formulas (1), (2) and (3), wherein the content of the repeating unit of formula (3) is 5 mol % to 50 mol %, and the refractive index is 1.570 to 1.600. {In formula (1), R.sub.1 and R.sub.2 each represent a hydrogen atom or a C.sub.1-10 hydrocarbon group.} {In formula (3), n ranges from 0 to 8, and the R symbols are each selected from C.sub.1-3 alkyl groups}.

##STR00001##

The purpose of the present invention is to provide a high temperature/humidity resistant polycarbonate resin without using bisphenol A as a raw material. The present invention relates to a polycarbonate resin comprising the repeating units of formulas (1), (2) and (3), wherein the content of the repeating unit of formula (3) is 5 mol % to 50 mol %, and the refractive index is 1.570 to 1.600. {In formula (1), R.sub.1 and R.sub.2 each represent a hydrogen atom or a C.sub.1-10 hydrocarbon group.} {In formula (3), n ranges from 0 to 8, and the R symbols are each selected from C.sub.1-3 alkyl groups}.

A high molecular weight aromatic polycarbonate resin manufacturing method that can achieve good quality and sufficiently high molecular weight includes: a step in which a dialcohol compound expressed by general formula (1) and a catalyst are mixed to obtain a catalyst composition; a step in which the obtained catalyst composition is transferred to a prepolymer mixing tank via a transfer pipe; a step in which the transferred catalyst composition and an aromatic polycarbonate prepolymer are mixed in the prepolymer mixing tank, under a pressure that is greater than or equal to the vapor pressure of the dialcohol compound at the temperature of the prepolymer mixing tank and is less than or equal to 5 MPa, to obtain a prepolymer mixture; and a high molecular weight achievement step in which the obtained prepolymer mixture is heat-treated under reduced pressure conditions to obtain a high molecular weight aromatic polycarbonate resin. ##STR00001##

To provide a polycarbonate resin having an excellent hue and high heat stability, and a production method and a film thereof. The polycarbonate resin has a carbonate constituent unit represented by the following formula (A), wherein the resin contains a terminal group represented by the following formula (1) or (2) and 0.1 to 500 ppm of an aromatic monohydroxy compound. ##STR00001## (In the formula (1), R.sub.1 is an alkyl group having 6 to 15 carbon atoms which may be substituted.) ##STR00002## (In the formula (2), R.sub.2 and R.sub.3 are each independently an alkylene group having 1 to 12 carbon atoms which may be substituted. R.sub.4 is a hydrogen atom or alkyl group having 1 to 12 carbon atoms which may be substituted. n is an integer of 1 to 20.)