Patent classifications
C08G64/40
AROMATIC POLYCARBONATE RESIN COMPOSITION AND AROMATIC POLYCARBONATE RESIN MANUFACTURING METHOD
Provided is a method of manufacturing an aromatic polycarbonate resin composition with high fluidity, particularly during low shear, and a good color. An aromatic polycarbonate resin composition including: an aromatic polycarbonate resin that has a structural unit expressed by general formula (1); a aliphatic cyclic carbonate that is expressed by general formula (2) and is included at a ratio of 10 ppm-10,000 ppm; an aromatic cyclic carbonate that is expressed by general formula (3); and at least one compound selected from the group consisting of compounds expressed by general formulas (4)-(6), wherein the total content of the aromatic cyclic carbonate and the compound(s) expressed by general formula(s) (4)-(6) is 0.1 mass %-2.0 mass % by bisphenol A-converted value.
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END-GROUP ISOMERIZATION OF POLY(ALKYLENE CARBONATE) POLYMERS
Described herein are methods of preparing poly(alkylene carbonate) polymers comprising an increased ratio of primary hydroxyl end groups to secondary hydroxyl end groups, and compositions thereof.
END-GROUP ISOMERIZATION OF POLY(ALKYLENE CARBONATE) POLYMERS
Described herein are methods of preparing poly(alkylene carbonate) polymers comprising an increased ratio of primary hydroxyl end groups to secondary hydroxyl end groups, and compositions thereof.
PRODUCING SEMI-CRYSTALLINE PULVERULENT POLYCARBONATE AND USE THEREOF IN ADDITIVE MANUFACTURING
Ways of preparing a partially crystalline polycarbonate powder are provided that include dissolving an amorphous polycarbonate in a polar aprotic solvent to form a first solution of solubilized polycarbonate at a first temperature. The first solution is then cooled to a second temperature, the second temperature being lower than the first temperature, where a portion of the solubilized polycarbonate precipitates from the first solution to form a second solution including the partially crystalline polycarbonate powder. Certain partially crystalline polycarbonate powders resulting from such methods are particularly useful in additive manufacturing processes, including powder bed fusion processes.
PRODUCING SEMI-CRYSTALLINE PULVERULENT POLYCARBONATE AND USE THEREOF IN ADDITIVE MANUFACTURING
Ways of preparing a partially crystalline polycarbonate powder are provided that include dissolving an amorphous polycarbonate in a polar aprotic solvent to form a first solution of solubilized polycarbonate at a first temperature. The first solution is then cooled to a second temperature, the second temperature being lower than the first temperature, where a portion of the solubilized polycarbonate precipitates from the first solution to form a second solution including the partially crystalline polycarbonate powder. Certain partially crystalline polycarbonate powders resulting from such methods are particularly useful in additive manufacturing processes, including powder bed fusion processes.
METHOD FOR SEPARATING ORGANOZINC CATALYST FROM POLYALKYLENE CARBONATE POLYMERIZATION SOLUTION
The present invention relates to a method for separating an organozinc catalyst from a polyalkylene carbonate polymerization solution, and the method of the present invention includes: stirring and aging a polymerization solution including a polyalkylene carbonate resin, an organozinc catalyst, an alkylene oxide and a polymerization solvent; and filtering the polymerization solution after completing the aging.
METHOD FOR SEPARATING ORGANOZINC CATALYST FROM POLYALKYLENE CARBONATE POLYMERIZATION SOLUTION
The present invention relates to a method for separating an organozinc catalyst from a polyalkylene carbonate polymerization solution, and the method of the present invention includes: stirring and aging a polymerization solution including a polyalkylene carbonate resin, an organozinc catalyst, an alkylene oxide and a polymerization solvent; and filtering the polymerization solution after completing the aging.
Method for Preparing Granular Polycarbonate
A method for preparing granular polycarbonate particles is disclosed herein. In some embodiments, a method for preparing granulated polycarbonate particles includes mixing a polymerization reaction solution comprising polycarbonate and an organic solvent, and an anti-solvent solution comprising water and an anti-solvent to prepare a mixed solution, heating the mixed solution to remove the organic solvent, and drying or filtering the mixed solution to obtain granular polycarbonate particles. The granular polycarbonate particles having excellent physical properties without using a stabilizer or a surfactant can be obtain.
Method for Preparing Granular Polycarbonate
A method for preparing granular polycarbonate particles is disclosed herein. In some embodiments, a method for preparing granulated polycarbonate particles includes mixing a polymerization reaction solution comprising polycarbonate and an organic solvent, and an anti-solvent solution comprising water and an anti-solvent to prepare a mixed solution, heating the mixed solution to remove the organic solvent, and drying or filtering the mixed solution to obtain granular polycarbonate particles. The granular polycarbonate particles having excellent physical properties without using a stabilizer or a surfactant can be obtain.
SEPARATING A DOUBLE METAL CYANIDE CATALYST
A method for separating a double metal cyanide catalyst (DMC catalyst) from polyol, comprising: A) initially charging a polyol comprising DMC catalyst, an alcohol, and optionally a filtration aid into a reactor, the mixture being heated, B) filtering the mixture from step A), and C) optionally separating the alcohol from the filtrate of step B), wherein in step A), as the alcohol, 4% by weight to 12% by weight of ethanol, based on 100% by weight of polyol, without a chelating agent is used.