The present disclosure relates to gel compositions of, or containing, a non-isocyanate polyurethane (NIPU) elastomer formed from the reaction of a polycarbonate, where carbonate groups may be cyclic or non-cyclic, and a polyamine, where amines are either primary or secondary, in an optional topically acceptable carrier fluid. The gelled compositions may further contain a personal or healthcare active. The actives may be incorporated into the gel via either a pre or post load method.

The present disclosure relates to gel compositions of, or containing, a non-isocyanate polyurethane (NIPU) elastomer formed from the reaction of a polycarbonate, where carbonate groups may be cyclic or non-cyclic, and a polyamine, where amines are either primary or secondary, in an optional topically acceptable carrier fluid. The gelled compositions may further contain a personal or healthcare active. The actives may be incorporated into the gel via either a pre or post load method.

The present invention relates to an acrylated and/or methacrylated urethane oligomer obtained by reaction of a specific polyamine a) with a cyclic carbonate compound b) carrying m cyclic carbonate groups, giving an intermediate product c) carrying m formed urethane groups which carry residual reactive amine —NH— groups, and subsequently an addition reaction of each of the said residual reactive amine groups of the said product c) with an acrylate group of a compound d) carrying, in addition to the said acrylate group, p additional acrylate and/or methacrylate groups, with each residual reactive amine —NH— group of the said product c) being thus converted into a carbon-nitrogen bond carrying the said acrylate and/or methacrylate groups, and thus production of the said urethane oligomer, with each carbon-nitrogen bond formed carrying p acrylate and/or methacrylate groups and the said urethane oligomer carrying m urethane groups and m hydroxyl groups in the alpha or beta position with respect to the said urethane and having a functionality in acrylates and/or methacrylates ranging from m*p(n−1) to m*p(2n−2).

The invention also relates to a process for the preparation of the said oligomer in two stages, to the intermediate product c) and to the use of the said urethane oligomer in crosslinkable compositions, in particular in coating compositions, adhesive compositions, compositions for systems for the layer-by-layer manufacture of 3D objects, compositions for 3D printing systems, moulding compositions, leaktightness agent compositions, chemical sealing compositions, concrete compositions or composite compositions.

A method of preparing a composition for a one-package (1 K) waterborne non isocyanate polyurethane epoxy hybrid coating includes providing a cyclic carbonate; combining the cyclic carbonate with an internal emulsifier and a diamine to thereby obtain a non-isocyanate polyurethane (NIPU) prepolymer; subjecting the NIPU prepolymer to chain extension by combining the NIPU prepolymer with an epoxy resin, to thereby obtain a chain extended NIPU polymer; subjecting the chain extended NIPU polymer to neutralization by combining the chain extended NIPU polymer with a neutralizing agent, to thereby obtain a neutralized NIPU polymer; and dispersing the neutralized NIPU polymer in water to thereby provide a waterborne NIPU liquid dispersion.

A method of preparing a composition for a one-package (1 K) waterborne non isocyanate polyurethane epoxy hybrid coating includes providing a cyclic carbonate; combining the cyclic carbonate with an internal emulsifier and a diamine to thereby obtain a non-isocyanate polyurethane (NIPU) prepolymer; subjecting the NIPU prepolymer to chain extension by combining the NIPU prepolymer with an epoxy resin, to thereby obtain a chain extended NIPU polymer; subjecting the chain extended NIPU polymer to neutralization by combining the chain extended NIPU polymer with a neutralizing agent, to thereby obtain a neutralized NIPU polymer; and dispersing the neutralized NIPU polymer in water to thereby provide a waterborne NIPU liquid dispersion.

The present invention provides an oil-in-water emulsion composition thickened with a hydrophobically modified polyether urethane, the composition having improved high-temperature stability and giving a pudding-like unique feeling. The invention provides an elastic jelly-like composition characterized in that a hydrophobically modified polyether urethane has been incorporated into an oil-in-water emulsion including oil droplets with an average particle diameter of 150 nm or smaller. The elastic jelly-like composition is transparent or translucent, gives a pudding-like elastic feeling, has excellent viscosity stability at high temperatures, and is suitable for use as a cosmetic-preparation base. The hydrophobically modified polyether urethane is especially preferably a PEG-240/decyltetradeceth-20/HDI copolymer.

The present invention provides an oil-in-water emulsion composition thickened with a hydrophobically modified polyether urethane, the composition having improved high-temperature stability and giving a pudding-like unique feeling. The invention provides an elastic jelly-like composition characterized in that a hydrophobically modified polyether urethane has been incorporated into an oil-in-water emulsion including oil droplets with an average particle diameter of 150 nm or smaller. The elastic jelly-like composition is transparent or translucent, gives a pudding-like elastic feeling, has excellent viscosity stability at high temperatures, and is suitable for use as a cosmetic-preparation base. The hydrophobically modified polyether urethane is especially preferably a PEG-240/decyltetradeceth-20/HDI copolymer.

A first process to produce polycarbamate comprising providing urea in liquid form; and adding the liquid urea to a polyol is provided. A second process for producing polycarbamate comprising adding solid urea to a polyol in liquid form to form a reaction mixture is provided. Also provided is a reaction product produced by the first process or second process.

A first process to produce polycarbamate comprising providing urea in liquid form; and adding the liquid urea to a polyol is provided. A second process for producing polycarbamate comprising adding solid urea to a polyol in liquid form to form a reaction mixture is provided. Also provided is a reaction product produced by the first process or second process.

Acid-catalyzed curable coating compositions containing 1,1-di-activated vinyl compounds are described, including multi-layer coatings. Also provided are processes for coating substrates with coating compositions comprising 1,1-di-activated vinyl N compounds. Also provided are coated articles comprising coatings formed from coating compositions comprising 1,1-di-activated vinyl compounds.