Patent classifications
C08G75/20
Hydroxybenzophenone-based stabilizers and polymers end-capped with the same
The invention relates to hydroxybenzophenone-based compounds of formula (I) that are used to improve UV, thermal, and thermo-oxidative stability of high performance aromatic polymers in a blend or as end-cappers of the same polymers.
Hydroxybenzophenone-based stabilizers and polymers end-capped with the same
The invention relates to hydroxybenzophenone-based compounds of formula (I) that are used to improve UV, thermal, and thermo-oxidative stability of high performance aromatic polymers in a blend or as end-cappers of the same polymers.
ZWITTERION-FUNCTIONALIZED MULTICOMPONENT COPOLYMERS AND ASSOCIATED POLYMER BLENDS AND MEMBRANES
Multicomponent copolymers including two or more types of repeat units is presented. In one example, the multicomponent copolymer includes at least one repeat unit AC having a structure (I), at least one repeat unit DC having a structure (II), and at least one repeat unit BC having a structure (III) or (V). The multicomponent copolymer may be cross-linked via a cross-linking agent. A polymer blend including the multicomponent copolymer or a cross-linked copolymer and a second polymer is also provided. The multicomponent copolymer may be a random or a block copolymer. The structural units of the multicomponent copolymers provide improved, tunable properties, such as improved biocompatibility and hydrophilicity, protein fouling, and mechanical properties, to the copolymers and/or the membranes fabricated from the copolymers.
ZWITTERION-FUNCTIONALIZED MULTICOMPONENT COPOLYMERS AND ASSOCIATED POLYMER BLENDS AND MEMBRANES
Multicomponent copolymers including two or more types of repeat units is presented. In one example, the multicomponent copolymer includes at least one repeat unit AC having a structure (I), at least one repeat unit DC having a structure (II), and at least one repeat unit BC having a structure (III) or (V). The multicomponent copolymer may be cross-linked via a cross-linking agent. A polymer blend including the multicomponent copolymer or a cross-linked copolymer and a second polymer is also provided. The multicomponent copolymer may be a random or a block copolymer. The structural units of the multicomponent copolymers provide improved, tunable properties, such as improved biocompatibility and hydrophilicity, protein fouling, and mechanical properties, to the copolymers and/or the membranes fabricated from the copolymers.
Method for preparing nanoporous polysulfone-based polymers
The present invention relates to a method for preparing nanoporous polysulfone-based polymers, including: a copolymer of a polysulfone polymer and a polar polymer is immersed into a compound swelling agent, and maintained for at least 1 minute above room temperature; the compound swelling agent is a solvent pair composed of the mixture of solvent A and solvent B; the solvent A has high affinity with the polysulfone polymer; and the solvent B has high affinity with the polar polymer; the treated copolymer is taken out from the compound swelling agent and then dried to remove the solvent to obtain the nanoporous polysulfone-based polymers.
Method for preparing nanoporous polysulfone-based polymers
The present invention relates to a method for preparing nanoporous polysulfone-based polymers, including: a copolymer of a polysulfone polymer and a polar polymer is immersed into a compound swelling agent, and maintained for at least 1 minute above room temperature; the compound swelling agent is a solvent pair composed of the mixture of solvent A and solvent B; the solvent A has high affinity with the polysulfone polymer; and the solvent B has high affinity with the polar polymer; the treated copolymer is taken out from the compound swelling agent and then dried to remove the solvent to obtain the nanoporous polysulfone-based polymers.
Polycarbonate resin composition having excellent heat resistance and fluidity, and molded product including same
Disclosed is a polycarbonate resin composition including (1) a polyester compound having a structure of chemical formula 1 as defined herein or a phenyl-arylene ether sulfone compound having a structure of chemical formula 2 as defined herein; (2) a polycarbonate block copolymer; and (3) a thermoplastic aromatic polycarbonate resin or a polysiloxane-polycarbonate resin; and a molded product including the same. The polycarbonate resin composition exhibits remarkably excellent heat resistance compared to existing high heat resistance polycarbonate resins, and has an excellent balance of physical properties such as fluidity.
Biostable segmented elastomers and thermoplastics and methods of making and using thereof
Polymers having mechanical properties approaching or exceeding commercial elastomers and engineering thermoplastics, but improved biostability, are described herein. In one embodiment, the polymers have a hard segment containing one or more disulfoxide or disulfone moieties and a soft segment connected to the hard segment to form an elastomeric polymer. The polymer is resistant to oxidation and/or hydrolytic degradation, particularly in vivo, which allows for the use of these materials in implants/devices which are implanted for an extended period of time. The ratio or percentage by weight of soft segment to hard segment can be varied based on the physical and mechanical properties of the desired device.
Biostable segmented elastomers and thermoplastics and methods of making and using thereof
Polymers having mechanical properties approaching or exceeding commercial elastomers and engineering thermoplastics, but improved biostability, are described herein. In one embodiment, the polymers have a hard segment containing one or more disulfoxide or disulfone moieties and a soft segment connected to the hard segment to form an elastomeric polymer. The polymer is resistant to oxidation and/or hydrolytic degradation, particularly in vivo, which allows for the use of these materials in implants/devices which are implanted for an extended period of time. The ratio or percentage by weight of soft segment to hard segment can be varied based on the physical and mechanical properties of the desired device.
ALIPHATIC POLYSULFONES WITH IMPROVED MECHANICAL INTEGRITY
A polysulfone has sulfone units that are separated by alkylene units in a polymer chain or a copolymer chain where the alkylene units have at least four carbons between sulfone units. The alkylene units can include an ethenylene unit separated from the sulfone units by at least one methylene units. The polysulfones can be crosslinked for enhanced thermal stability. Membranes can be formed from the polysulfones.