The present invention relates to a synthesis method for sulfate ester (amine) type linker polymer, which comprises a monomer containing hydroxyl or amino group and sulfuryl fluoride monomer proceeding a polycondensation reaction under a basic condition by one-pot process. As compared to the traditional polyester synthesis method, the present invention is economical; the reaction conditions are mild and easy to control, the reaction process is simple and easy to operate; the post-treatment process is simple with little environmental pollution, which is beneficial to industrial production. In addition, the bisphenol type polysulfate ester compounds synthesized by the present invention have excellent mechanical performances, dielectric performances, tolerance performances, and abrasion resistance performances.

The present invention relates to a synthesis method for sulfate ester (amine) type linker polymer, which comprises a monomer containing hydroxyl or amino group and sulfuryl fluoride monomer proceeding a polycondensation reaction under a basic condition by one-pot process. As compared to the traditional polyester synthesis method, the present invention is economical; the reaction conditions are mild and easy to control, the reaction process is simple and easy to operate; the post-treatment process is simple with little environmental pollution, which is beneficial to industrial production. In addition, the bisphenol type polysulfate ester compounds synthesized by the present invention have excellent mechanical performances, dielectric performances, tolerance performances, and abrasion resistance performances.