A process can be used for preparing silicone (meth)acrylates, according to which at least one acetoxysilicone is reacted with at least one hydroxyfunctional (meth)acrylic acid ester. The corresponding silicone (meth)acrylates are useful, and can be used in curable compositions.

A reaction composition contains (a) an allyl polyether having the following formula: CH.sub.2=CHCH.sub.2O-A.sub.a-B where, (i) subscript a is 2 to 170; (ii) A is selected from: —CH.sub.2CH.sub.2O—; —CH.sub.2CH(CH.sub.3)O—; —CH(CH.sub.3)CH.sub.2O—, CH.sub.2CH(CH.sub.2CH.sub.3)O—; —CH(CH.sub.2CH.sub.3)CH.sub.2O, —CH.sub.2CF(CF.sub.3)O—, —CF(CF.sub.3)CF.sub.2O— and —CF.sub.2CF(CF.sub.3)O—; and (iii) B is selected from —H, —CH.sub.3, —CH.sub.2CH.sub.3, —CH.sub.2CH.sub.2CH.sub.3, —CH.sub.2CH.sub.2CH.sub.2CH.sub.3, —C(O)CH.sub.3, and —CF.sub.2CF.sub.2CF.sub.3; (b) A silyl hydride functional siloxanc comprising the following siloxane units [R.sub.2HSiO.sub.1/2].sub.m[R.sub.2SiO.sub.2/2].sub.d[R.sub.2SiO.sub.3/2].sub.t[SiO4/2].sub.q wherein d+t+q is one or more and wherein: (i) R is selected from hydrocarbyl groups liaing from one to 8 carbon atoms; (ii) subscript m is 2 or more; (iii) subscript d is zero to 20; (iv) subscript t is zero to 2; (v) subscript q is zero to 2; and (c) a platinum-based hydrosilylation catalyst; where there are at least 4 molar equivalents of silyl hydride functionalities relative to allyl functionalities in the reaction composition.

A bio-electrode composition contains (A) a silicone bonded to an ionic polymer and having a structure containing a T unit shown by the following general formula (T1): (R.sup.0SiO.sub.3/2) (T1), the structure excluding a cage-like structure. In the formula, R.sup.0 represents a linking group to the ionic polymer. The ionic polymer is a polymer containing a repeating unit having a structure selected from the group consisting of salts of ammonium, lithium, sodium, potassium, and silver formed with any of fluorosulfonic acid, fluorosulfonimide, and N-carbonyl-fluorosulfonamide. Thus, the present invention provides a bio-electrode composition capable of forming a living body contact layer for a bio-electrode which is excellent in electric conductivity, biocompatibility, stretchability, and adhesion, soft, light-weight, and manufacturable at low cost, and which prevents significant reduction in the electric conductivity even when wetted with water or dried.

A composition contains 45-65 weight-percent (wt %) of a linear polyorganosiloxane with terminal vinyl functionality, 39 wt % to less than 50 wt % alkenyl-free polyorganosiloxane resin comprising R.sub.3SiO.sub.1/2 and SiO.sub.4/2 siloxane units at an average molar ratio of greater than zero to 10; where R is independently in each occurrence selected from a group consisting of alkyl groups containing from one to 10 carbon atoms; 0.5-15 wt % mercapto-functional linear polyorganosiloxane crosslinker; 0.01-0.1 wt % radical stabilizer; 0.01-3 wt % thiol-ene photopolymerization initiator; 0-10 wt % fumed silica; and 0-5 wt % polydimethylsiloxane; wherein weight-percent values are relative to composition weight, the composition has a molar ratio of SiH/vinyl functional groups that is greater than 0.3 and at the same time less than 0.8 and wherein the composition is free of alkenyl functional polyorganosiloxane resin, free of alkoxysilyl containing components, and free of polysiloxane comprising R.sup.SHSiO.sub.3/2 siloxane units, where R.sup.SH is a mercapto-group containing hydrocarbyl.

The present invention pertains to a branched polymeric liquid poly siloxane material comprising non-organofunctional Q-type siloxane moieties and mono-organofunctional T-type siloxane moieties, as well as optionally tri-organofunctional M-type siloxane moieties and/or di-organofunctional D-type siloxane moieties characterized in that the polysiloxane material has a specified degree of polymerization, comprises a significant amount of four-membered Q2-type and/or Q3-type siloxane ring species relative to the total Q-type siloxane species, and is optionally functionalized at specific moieties. The present invention further pertains to methods for producing the polymeric liquid polysiloxane material as well as associated uses of the material.

A new class of liquid polysiloxane materials obtainable from cost-effective commodity precursors allow tailoring a plurality of (multi)—functional properties. The materials are classified in terms of their chemical identity, which comprises Q-type nonorganofunctional, T-type monoorganofunctional and optional D-type diorganofunctional moieties. The T-type organofunctional species within a polymeric MBB can be present in various preferred combinations defined by spatial, stereochemical and compositional factors. The corresponding method of production for the liquid polymeric polysiloxanes involves a scalable, non-hydrolytic acetic anhydride method either in a simple one-step format to create statistically distributed “core-only” hyperbranched poly-alkoxysiloxanes or as a two— or multistep process to create “core-shell” materials.

Provided is a silicone adsorption film that excels in both adsorption to a smooth surface and the suppression of remnants of glue on the smooth surface after detachment. The silicone adsorption film comprises a base material layer and a silicone adsorption layer laminated on the base material layer. The silicone adsorption layer is a cured product of a crosslinkable composition containing (a) a crosslinkable organopolysiloxane, (b) a crosslinking agent, (c) a non-reactive MQ resin and (d) a reactive MQ resin. The silicone adsorption film excels in both adsorption to a smooth surface and the suppression of remnants of glue on the smooth surface after detachment.

Foam control compositions along with formulations thereof and their use in various applications, including a method for making a foam control composition comprising a cross-linked polyorganosiloxane material including a dispersed silica filler, including the steps of: A) preparing a hydrosilylation reaction mixture by combining the following components: (i) silica filler, (ii) a polyorganosiloxane having at least two reactive substituents capable of addition reaction with component (iii) via hydrosilylation, (iii) a polyorganosiloxane having at least three reactive substituents capable of addition reaction with component (ii) via hydrosilylation, and (iv) a hydrosilylation catalyst; B) conducting a hydrosilylation reaction of components (ii) and (iii) until the reaction mixture at least partially gels to form a hydrosilylation reaction product; C) shearing the hydrosilylation reaction product of step B); and D) combining the hydrosilylation reaction product of step C) with a (v) silicone resin and an (vi) condensation catalyst to form a condensation reaction mixture and conducting a condensation reaction between the (v) silicone resin and the hydrosilylation reaction product of step C) to form a condensation reaction product.

A polysiloxane-substituted quinacridone pigment is produced by a quinacridone pigment with an epoxy-terminated polysiloxane under conditions effective to cause the epoxy group on the polysiloxane to react with, and bond the polysiloxane to, the quinacridone pigment. The quinacridone pigment thus produced has the polysiloxane grouping bonded to one of the quinacridone nitrogen atoms via a hydrocarbon linking group, which bears a hydroxyl group on a carbon atom α or β to the quinacridone nitrogen atom. These quinacridone pigments are useful in electrophoretic displays.

A composition contains a blend of linear and resinous alkenyl functionalized polyorganosiloxanes, a blend of linear and resinous silyl hydride functionalized polyorganosiloxanes, and a hydrosilylation catalyst where the linear silyl hydride functionalized polyorganosiloxanes has a ratio of D/D.sup.H that is greater than 2.0 and less than 14, the molar and the ratio of silyl hydride hydrogens to the sum of terminal alkenyl functionality on the alkenyl functionalized polyorganosiloxane is 1.2-2.2.