The present invention is to provide a bound stopper, which has high mechanical strength, is excellent in durability against fatigue breaking, settling or the like when a heavy load is repeatedly received, and is easy to be produced, in which the bound stopper comprises a polyurethane foam obtained from a polyurethane foam composition containing an isocyanate component and a blowing agent, and the isocyanate component contains a urethane prepolymer having an isocyanate group, the urethane prepolymer being obtained from a polyol component, a polyrotaxane containing a cyclic molecule having an active hydrogen group as a constituent, and an isocyanate.

This document relates to methods for preventing or inhibiting the formation of micro-cracks and fractures in the cement of an oil well using cement compositions that contain cross-linked polyrotaxane additives. The cement compositions containing the cross-linked polyrotaxane additives exhibit increased stiffness without suffering a decrease in compressive strength, as compared to the same cement without the cross-linked polyrotaxane additive.

Provided is a photochromic optical article obtained by bonding a pair of optical article plates to each other with an adhesive layer that contains (A) a photochromic compound and (B) a urethane resin, wherein (B) the urethane resin is obtained by polymerizing: (B1) a polyiso(thio)cyanate compound having two or more iso(thio)cyanate groups in a molecule; (B2) a poly(thi)ol compound having, in a molecule, two or more active hydrogen-containing groups selected from a hydroxyl group and a thiol group; and (B3) a mono(thi)ol compound having, in a molecule, one active hydrogen-containing group selected from a hydroxyl group and a thiol group. Also provided is a method for manufacturing the photochromic optical article.

The present invention relates to a method of preparing a polyrotaxane, said method comprising: performing a radical copolymerization of at least (a) a first polymerizable monomer having a stopper group, and of at least (b) a second polymerizable monomer, wherein said second monomer is complexed by a ring-shaped molecule; wherein during said copolymerization a copolymer threading said ring-shaped molecule is formed, wherein during said copolymerization said first monomer having a stopper group is incorporated into the chain of said copolymer at least partially between the ends thereof, and wherein said stopper groups prevent said ring-shaped molecule from disassembling from the copolymer; and wherein the amount of said first monomer having a stopper group is of from 0.1 mol % to 20 mol % based on 100 mol % of the total amount of polymerizable monomers. The present invention also relates to polyrotaxanes which can be prepared by using such a method. The present invention further relates to cross-linked polyrotaxanes, products which contain polyrotaxanes or cross-linked polyrotaxanes or which can be prepared from polyrotaxanes or cross-linked polyrotaxanes, and the use of polyrotaxanes or cross-linked polyrotaxanes.

Various embodiments of the present invention are directed to polyrotaxanes comprising a poloxamer core and at least one cyclodextrin and methods for treating Niemann-Pick type C (NPC) and imaging (e.g., MRI) using the polyrotaxanes of the various embodiments of the present invention.

A self-healing composite material includes at least one cross-linked polyrotaxane and at least one organically modified inorganic hybrid material which comprises functional groups (B) or at least one type of surface-modified inorganic particles which have functional groups (B) on their surface. The polyrotaxane is a cross-linked polyrotaxane and at least two of the threaded ring-shaped molecules are cross-linked by linking of the functional groups (A) and (B).

Provided is a molded article comprising a resin, wherein the molded article has a Hermann's degree of orientation f of 0.006 or more which is determined by the following formula (1) and the following formula (2) based on an azimuth angle distribution curve obtained by wide-angle X-ray diffraction measurement and a haze of less than 10%, the resin comprises a structural unit derived from a monomer comprising a carbon-carbon double bond at the end and a structural unit derived from a polyrotaxane compound, and the polyrotaxane compound comprises cyclic molecules comprising a functional group capable of addition polymerization with the carbon-carbon double bond, a linear molecule clathrated in a skewer shape by the cyclic molecules, and blocking groups disposed at the ends of the linear molecule to prevent elimination of the cyclic molecules.

A three-dimensional-forming photo-curable composition includes a (meth)acrylic compound having a (meth)acryloyl group; a photo-radical generator; and a polyrotaxane having a plurality of cyclic molecules having at least one of a (meth)acryloyl group and a hydroxyl group.

Provided are supramolecular polypseudorotaxane hydrogel compositions and 3-D structures capable of reversible 3-D structural deformation which include (a) a solvent; (b) an at least partially linear polymer, where the polymer further comprises groups capable of covalent crosslinking between the polymers; (ii) at least one first macrocyclic ring which forms a pseudorotaxane with a polymer in the polymer network; and (iii) at least one second macrocyclic ring that does not form the pseudorotaxane. The hydrogel composition has a viscosity which allows for 3-D printing of the hydrogel to form a 3-D structure, and a storage (elastic) modulus after crosslinking that allows for the 3-D structure to undergo reversible 3-D structural deformation upon change of solvent conditions. Also provided are methods of manufacturing the compositions and 3-D structures.

A rubber composition for a tire, which does not require the addition of a compound when synthesizing rubber component and the modification of a rubber component, and a winter tire using the rubber composition are provided. The rubber composition for a tire contains fine particles of rotaxane having a straight chain molecule, acyclic molecule clathrating the straight chain molecule and blocking groups arranged at both terminals of the straight chain molecule such that the cyclic molecule does not desorb from the straight chain molecule, covered with silica; a rubber component comprising styrene-butadiene rubber; and at least one of carbon black and silica, wherein the total content of the fine particles, the carbon black and the silica (excluding silica covering rotaxane) is 70 to 150 parts by mass per 100 parts by mass of the rubber component.