A process for preparing a low-molecular weight fluoropolyether containing an acid fluoride by decomposing a triflate or trifluoroacetate of a fluoropolyether having a hydroxyl group in the presence of a Lewis acid.

An ink composition and an adhesion promoter are provided. The adhesion promoter is suitable for production while remaining the stronger adhesion. The adhesion promoter is formed by the reaction of at least one alpha hydroxy acid and at least one alpha hydroxy acid ester with the metal alkoxide. More specifically, by combining the renewable and green alpha hydroxy acid and safer plasticizing alpha hydroxy acid ester as reagent to react with the metal alkoxide, the eco-friendly and non-toxic adhesion promoter with superior adhesion for use in ink composition can be obtained. The ink composition includes the adhesion promoter, a pigment, a polymeric binder, and a solvent for the polymeric binder. The ink composition is odorless and colorless, and shows good wet crinkle resistance. Especially, the ink composition is suitable for printing on the food package.

An ink composition and an adhesion promoter are provided. The adhesion promoter is suitable for production while remaining the stronger adhesion. The adhesion promoter is formed by the reaction of at least one alpha hydroxy acid, at least one alpha hydroxy acid ester, and a polymer having hydroxyl group, amino group, carboxyl group, or a combination thereof with a metal alkoxide. By combining the renewable and green alpha hydroxy acid and safer plasticizing alpha hydroxy acid ester, and the polymer as reagents to react with the metal alkoxide, the eco-friendly and non-toxic adhesion promoter with superior adhesion for use in ink composition can be obtained. The ink composition includes the adhesion promoter, a pigment, a polymeric binder, and a solvent for the polymeric binder. The ink composition is odorless and colorless, and shows good wet crinkle resistance. Especially, the ink composition is suitable for printing on the food package.

Provided herein is a thermoplastic elastomer hydrogel and methods of making such. The hydrogel comprises a glass formed from poly(styrene)-b-poly(ethylene oxide) in which the coronal chain end has been functionalized with photodimerizable groups (AB-photo) and a liquid medium at a concentration between about 32:1 and about 2:1 liquid medium/AB-photo by weight. The hydrogel has a fatigue resistance to at least 500,000 compression cycles.

A random copolymer compound of (A) a polyphenylene ether resin having phenolic hydroxy groups at both ends, (B) an aliphatic polymer having alcoholic hydroxy groups at both ends, and (C) an acid dichloride compound that is a binder is disclosed, wherein the number of mol a of the (A) polyphenylene ether resin, the number of mol b of the (B) aliphatic polymer, and the number of mol c of the (C) acid dichloride compound that is a binder satisfies the relationship (a+b)>c.

A material comprising an epoxy/elastomer adduct, a polymeric particle, from about 0.05 to about 20 weight percent of an epoxy/diacid adduct, and optionally, an amine reaction product.

A composition for forming an electroactive coating is described, including an acid as a polymerization catalyst, at least one functional component, and at least one compound of formula (1) as a monomer: ##STR00001##
wherein X is selected from S, O, Se, Te, PR.sup.2 and NR.sup.2, Y is hydrogen (H) or a precursor of a good leaving group Y.sup. whose conjugate acid (HY) has a pK.sub.a of less than 30, Z is hydrogen (H), silyl, or a good leaving group whose conjugate acid (HY) has a pK.sub.a of less than 30, b is 0, 1 or 2, each R.sup.1 is a substituent, and the at least one compound of formula (1) includes at least one compound of formula (1) with Z=H and YH.

A method for forming a conjugated heteroaromatic polymer is described, wherein at least one compound of formula (1) is polymerized using an acid as a catalyst,

##STR00001##

wherein X is selected from S, O, Se, Te, PR.sup.2 and NR.sup.2, Y is hydrogen (H) or a precursor of a good leaving group Y.sup. whose conjugate acid (HY) has a pK.sub.a of less than 30, Z is hydrogen (H), silyl, or a good leaving group whose conjugate acid (HY) has a pK.sub.a of less than 30, b is 0, 1 or 2, each R.sup.1 is a substituent, and the at least one compound of formula (1) being polymerized includes at least one compound of formula (1) with ZH and YH.

The invention provides compositions and methods relating to self-assembly of structures of various size and shape complexity. The composition include synthetic single-stranded polymers having a backbone and pre-determined linear arrangement of monomers.

A method of creating biocompatible polymeric structures includes the steps of: providing a biocompatible polymer including a strained cycloalkyne end group; forming a polymeric structure from the biocompatible polymer such that the strained cycloalkyne end group remains on the biocompatible polymer; providing an azide tethered molecule; and, after forming the polymeric structure, reacting the azide tethered molecule with the cycloalkyne in an azide alkyne cycloaddition reaction to further functionalize the polymeric structure.