In certain non-limiting, aspects, the present invention relates to storage stable premixes of a polyol suitable for polyurethane or polyisocyanurate foam preparation having, at least, 1,1,1,4,4,4-hexafluoro-2-butene (1336mzzm) as the blowing agent and optional one or more additional additives and/or auxillary blowing agents in amounts suitable for polyurethane or polyisocyanurate foam preparation.

Blends, polyol premix compositions, methods of forming such compositions, foamable compositions using the premix compositions, methods of preparing foams containing the premix compositions, and foams made using the premix compositions are described. The polyol premix composition includes a polyester polyol; halogenated olefin blowing agent; and a distribution-enhancing component. In the polyol premix composition, the blowing agent, the polyester polyol, and the distribution-enhancing component form a substantially uniform composition.

Embodiments of the present disclosure are directed towards semi-flexible foam formulations that can be utilized to form semi-flexible foams. As an example, a semiflexible foam formulation can include a first polyether polyol having an average nominal hydroxyl functionality from 2 to 4 and a number average equivalent weight from 120 to 1500, a second polyether polyol having a having an average nominal hydroxyl functionality from 4 to 8 and a number average equivalent weight from 120 to 800, and a third polyether polyol having an average nominal hydroxyl functionality from 2 to 4 a number average equivalent weight from 200 to 500 and toluene diisocyanate.

External thermal insulation composite systems described herein include a concrete or masonry wall and a multilayer thermal insulation board disposed on the concrete or masonry wall. The multilayer thermal insulation board includes at least one closed cell foam layer comprising polyurethane and polyisocyanurate having an open cell volume of less than 20% by volume according to ASTM D 6226 and at least one open cell foam layer comprising polyurethane and polyisocyanurate having an open cell volume of greater than 80% by volume according to ASTM D 6226.

Disclosed are a process of producing a polyurethane foam product, a polyurethane foam product pre-mix, polyurethane foam product formulation, and a polyurethane foam product. The process of producing the polyurethane foam product includes contacting a halohydrin component with a polyurethane foam product pre-mix. The polyurethane foam product pre-mix includes the halohydrin component. The polyurethane foam product formulation includes a polyol component, an isocyanate component, and a halohydrin component. The polyurethane foam product is formed by the pre-mix having the halohydrin component.

Disclosed is a method for producing an open cell low-density semi-rigid polyurethane foam suitable for general use as a thermal insulating material and/or acoustical applications. The method comprises producing a flame-retardant open-celled semi-rigid polyurethane foam having an overall density of 5 to 30 kg/m.sup.2 by reacting (a) a polyisocyanate and (b) a polyol having a molecular weight of 100 to 10,000, in the presence of (c) 2,2-bis(chloromethyl)-trimethylene bis(bis(2-chloroethyl)phosphate, (d) blowing agent, and (e) optional additional components.

External thermal insulation composite systems described herein include a concrete or masonry wall and a multilayer thermal insulation board on the concrete or masonry wall. The multilayer thermal insulation board includes a high density polyurethane layer having a first density from 100 kg/m.sup.3 to 2000 kg/mm.sup.3 according to ASTM D 1622 and a rigid polyurethane foam having a second density of less than 100 kg/m.sup.3 according to ASTM D 1622.

Embodiments of the present disclosure are directed towards polyether polyol compositions that can be utilized to form semi-rigid foams. As an example, a polyether polyol composition can include a first polyether polyol having an average nominal hydroxyl functionality from 2 to 4 and a number average equivalent weight from 120 to 1500, a second polyether polyol having a having an average nominal hydroxyl functionality from 4 to 8 and a number average equivalent weight from 120 to 800, and a third polyether polyol having an average nominal hydroxyl functionality from 2 to 4 a number average equivalent weight from 200 to 500.

A renewable chemical composition is disclosed for use in a variety of industrial applications. The renewable chemical composition may be reacted with an isocyanate to produce a polyurethane material. The renewable chemical composition has aromatic groups. The suitability of this material for use in a variety of applications can be adjusted by modifying the acid number, the Hydroxyl number, the viscosity, the glass transition temperature, the % solids, the softening point, and other properties. The chemical reactivity and properties can be modified based on processing conditions and temperature as well as the source of renewable raw material. The lignin used in these formulations may be from pulp and paper processing such as semi-mechanical processing, soda processing, kraft processing, or biomass processing, or a by-product of ethanol production. The novel biobased polyurethane formulations range in firmness from flexible to semi-rigid to rigid and are useful in large volume polyurethane applications.

The present invention relates to a process for preparing a polyurethane foam by reacting a polyisocyanate with a polyol in the presence of a blow agent and a particular family of amine. The present invention also relates to a polyurethane foam thereof.