A sponge for oil-water separation, which is prepared by reacting a polyol blend with a polyisocyanate and graphene, in the presence of a catalyst, a foaming agent and a foam stabilizer. The polyol blend includes: a first polyol component having a hydroxyl number of 33 to 60 mg KOH/g and an oxyethylene content of 50 to 80 mol %; a second polyol component having a hydroxyl number of 80 to 300 mg KOH/g and having an oxyethylene content of 50 to 80 mol %; a graft polyol component having a hydroxyl number of 20 to 40 mg KOH/g; a tetrafunctional polyol component having a hydroxyl number of 350 to 650 mg KOH/g; and glycerol.

High resiliency polyurethane foam is made from a polyether polyol having an equivalent weight of at least 1000. At least a portion of the polyether polyol is one or more random copolymer(s) formed by polymerizing a mixture of 70 to 95% by weight propylene oxide and 5 to 30% by weight ethylene oxide onto an initiator compound. The random copolymer(s) has a nominal hydroxyl functionality of at least 5, a hydroxyl equivalent weight of at least 1500 g/equivalent and no more than 0.01 milliequivalents per gram of terminal unsaturation. The randomly polymerized propylene oxide and ethylene oxide constitute at least 80% of the total weight of the random copolymer. At least 70% of the hydroxyl groups of the random copolymer are secondary hydroxyls.

In an HFO-1234ze or HFCO-1233zd formulated polyol, a shelf life improvement may be realized by including in the composition an excess of a carboxylic acid.

The disclosure relates to methods of making foams comprising aromatic polyester polyether polyol materials derived from the transesterification of polyethylene terephthalate with either glycerin or trimethylolpropane, wherein each of these triols, independently, has a degree of ethoxylation of from 1 to 9. Uses of the foams are further disclosed. The disclosure further relates to selection of blowing agents suitable to generate a selected end use case. Yet further, the disclosure relates to selection of end uses, properties, and environmental profiles of the foams generated according to the methods herein, and selecting formulation variables suitable to obtain the foams.

The present disclosure describes a flexible polyurethane foam having suspended within its matrix particles of silicon dioxide, SiO.sub.2. The particles of silicon dioxide are interspersed within the polyurethane matrix and protrude from the surface of the foam. These particles form an abrasive surface and the produced foam finds use as a cleaning material. The foam includes the use of a pre-polymer polyol formed by the reaction of triol polyol having a molecular weight of from 700 to 8000 with a polyisocyanate and a tin catalyst. The produced foam is much more durable than commercially available melamine foams and is an effective cleaning foam.

A polyisocyanurate foam insulation product includes polyisocyanurate foam produced from reacting an isocyanate and a polyol blend having a functionality of at least 2.2. The isocyanate and the polyol blend are reacted so that the polyisocyanurate foam has an isocyanate index equivalent with or greater than 300. The polyisocyanurate foam includes a fire retardant and includes between 0.02 and 0.45 weight percent of a zinc salt compound. The foam insulation board exhibits a flame spread of no greater than 25 and a smoke index of no greater than 50 when exposed to flame conditions in accordance with an ASTM E-84 test.

A polyurethane foam of the present disclosure is obtained from a polyurethane raw material containing a polyol component and a polyisocyanate component, and a gas for foaming. The polyurethane raw material contains a hydrophobic silica as a foam retention agent for retaining a foam and a light calcium carbonate, and a blending amount of the light calcium carbonate is 10 parts by weight or more based on 100 parts by weight of the polyol component.

A polyisocyanurate foam insulation product includes polyisocyanurate foam produced from reacting an isocyanate and a polyol blend having a functionality of at least 2.2. The isocyanate and the polyol blend are reacted so that the polyisocyanurate foam has an isocyanate index equivalent with or greater than 300. The polyisocyanurate foam includes a fire retardant and includes between 0.02 and 0.45 weight percent of a zinc salt compound. The foam insulation board exhibits a flame spread of no greater than 25 and a smoke index of no greater than 50 when exposed to flame conditions in accordance with an ASTM E-84 test.

A biodegradable foam which includes a polyester-based polyurethane foam and a mixture comprised of a soil-dwelling carbon-digesting bacteria embedded in a carrier compound. The mixture of the soil-dwelling carbon-digesting bacteria is homogenously dispersed throughout the polyester-based polyurethane foam. This biodegradable foam exhibits biodegradation rates higher than a polyester-based polyurethane foam absent the soil-dwelling carbon-digesting bacteria.

Composition for producing polyurethane foam, in particular rigid polyurethane foam, comprising at least an isocyanate component, a polyol component, optionally a catalyst that catalyses the formation of a urethane or isocyanate linkage, blowing agents, wherein the composition comprises polyester-polysiloxane block copolymers.