The invention relates to powder coating compositions suitable for low temperature powder coating crosslinking typically at curing temperature is between 75 and 140 C. which can be used for powder coating temperature-sensitive substrates like MDF, wood, plastic or temperature sensitive metal alloys.

The present invention relates to a process for the manufacture of an epoxy-functional polyester. The process according to the invention comprises the steps of a) providing a polyester having functional groups selected from hydroxyl groups and carboxylic acid groups, or mixtures thereof, b) reacting the functional groups of the polyester with an epihaloalkane to obtain an epoxy-functional polyester dissolved in a liquid phase, c) optionally adding an organic solvent to the liquid phase obtained in step b); d) precipitating the epoxy-functional polyester from the liquid phase obtained in step b) or in step c); and e) isolating the precipitated epoxy-functional polyester from the liquid phase by a solid-liquid separation technique. The thus obtained resin is in particular useful for use in powder coatings. The invention further relates to a solid epoxy-functional polyester obtainable by such process and to a coating composition, in particular a powder coating composition, comprising such solid epoxy-functional polyester.

The present invention provides a hybrid polyester-fluorocarbon powder coating composition which is a dry blend of a polyester powder coating composition A and a fluorocarbon powder coating composition B, wherein: polyester powder coating composition A comprises a first polyester polymer and a curing agent for the first polyester polymer; and fluorocarbon powder coating composition B comprises a fluorocarbon polymer, a curing agent for the fluorocarbon polymer, and a second polyester polymer and a curing agent for the second polyester polymer; wherein the weight ratio of polyester powder coating composition A and fluorocarbon powder coating composition B is in the range of from 25:75 to 75:25, wherein the first polyester polymer is a carboxyl functional polymer having an acid value in the range from 18 to 70 mg KOH/g polymer and wherein the second polyester polymer is a hydroxyl functional polyester polymer having a hydroxyl value in the range of from 70 to 350 mg KOH/g polymer. The invention further provides to a method for coating a substrate with such hybrid polyester-fluorocarbon powder coating composition.

A process for producing unsaturated polyester microparticles comprising: melt-mixing an unsaturated polyester and an oil in an extruder; washing the microparticles with an organic solvent to reduce the amount of oil; and removing the organic solvent to form the microparticles.

Disclosed are powder coating compositions that include a polymeric aromatic product of an aromatic isocyanate manufacturing process.

Thermosetting powdered coating compositions comprising (a) a high Acid Value carboxylic acid functional polyester resin having an Acid Value of at least 100 mg KOH/g and a functionality of at least 4.5, (b) a low Acid Value carboxylic acid functional polyester resin having an Acid Value of 20 to 50 mg KOH/g and a functionality of about 2.5 or less, and (c) a cross-linking agent. The high Acid Value polyester resin is the reaction product of a polycarboxylic acid or its anhydride reacted with a polyester polyol obtained from reacting 0 mol % to 100 mol % of isophthalic acid and/or 0 to 100 mol % terephthalic acid, or a mixture thereof, with a polyol mixture comprising at least one diol and at least one polyol having at least three hydroxyl groups. The thermosetting powdered coating compositions provide coatings with low gloss levels that can be adjusted from a gloss level of less than 1 to 40 or less, when measured at an angle of 60, by varying the ratios of the high Acid Value and low Acid Value polyester resins in the composition.

The present invention relates to a one-component processing method and system for preparing polyurea materials. This method and system involves a polymerization process using cyclic oligomeric polyurea precursors. These cyclic oligomeric precursors have dynamic urea bonds such as hindered urea bonds (HUBs). These cyclic oligomeric precursors exhibit dynamic properties to reversibly dissociate .sub.in situ yielding isocyanate and amine components which polymerize to yield the polyureas, such as linear, branched or cross-linked polyureas. This method and system has advantages over conventional methods that utilize two-component systems. Such two-component systems require the segregation of the isocyanate and amine components to prevent premature or too rapid polymerization. The resulting polyureas are useful for a variety of applications including coatings.

The invention relates to a polymer comprising certain specific units. The invention further relates to processes for making the polymer of the invention. The invention further relates to a binder and compositions comprising the polymer, preferably to compositions suitable for paints and coatings. The invention relates in particular to water-borne, solvent-borne and powder coating compositions and preferably to curable water-borne, curable solvent-borne and curable powder coating compositions. The invention further relates to cured compositions. The invention further relates to objects, in particular coatings prepared from the compositions of the invention. The invention further relates to processes for making the compositions of the invention. The invention further relates to articles having coated thereon the compositions of the invention. The invention further relates to articles having coated and cured thereon the compositions of the invention. The invention further relates to various uses of the polymer of the invention, the binder of the invention, the composition of the invention, the cured composition of the invention and various uses of articles having coated and optionally cured thereon the compositions of the invention.

The invention relates to a polymer comprising certain specific units. The invention further relates to processes for making the polymer of the invention. The invention further relates to a binder and compositions comprising the polymer, preferably to compositions suitable for paints and coatings. The invention relates in particular to water-borne, solvent-borne and powder coating compositions and preferably to curable water-borne, curable solvent-borne and curable powder coating compositions. The invention further relates to cured compositions. The invention further relates to objects, in particular coatings prepared from the compositions of the invention. The invention further relates to processes for making the compositions of the invention. The invention further relates to articles having coated thereon the compositions of the invention. The invention further relates to articles having coated and cured thereon the compositions of the invention. The invention further relates to various uses of the polymer of the invention, the binder of the invention, the composition of the invention, the cured composition of the invention and various uses of articles having coated and optionally cured thereon the compositions of the invention.

The invention relates to powder coating compositions suitable for low temperature powder coating crosslinking typically at curing temperature is between 75 and 140? C. which can be used for powder coating temperature-sensitive substrates like MDF, wood, plastic or temperature sensitive metal alloys.