The present technology provides a reactive hot-melt adhesive including a urethane prepolymer formed from a polyol and a polyisocyanate; and a thermoplastic poly (meth)acrylic resin; the polyol including a bifunctional polyol including polypropylene glycol and polyethylene glycol, a trifunctional polyol, and a polyester polyol having a glass transition temperature of from 20 to 60° C.

A lactic acid based hot-melt adhesive with an amorphous lactic acid oligomer tackifier. A hot-melt adhesive (HMA) includes: a lactic acid and caprolactone copolymer resin, a crystalline lactic acid oligomer wax, and said amorphous lactic acid oligomer tackifier, characterized in that the amorphous lactic acid oligomer tackifier includes an amorphous polymerisation product of a) lactic acid monomer and b) a multifunctional polymerization initiator containing three or more hydroxy and/or amino groups. The use of the amorphous lactic acid oligomer tackifier in a lactic acid-based hot-melt adhesive, to a method for adhering substrates together using a hot-melt adhesive including said amorphous lactic acid oligomer tackifier, and to a specific amorphous lactic acid oligomer tackifier and a method of its preparation.

A method of applying a material comprising a fusible polymer comprises the step of: applying a filament of the at least partly molten material comprising a fusible polymer from a discharge opening of a discharge element to a first substrate. The fusible polymer has the following properties: a melting point (DSC, differential scanning calorimetry; 2nd heating at heating rate 5° C./min) within a range from ≥35° C. to ≤150° C.; a glass transition temperature (DMA, dynamic-mechanical analysis to DIN EN ISO 6721-1:2011) within a range from ≥−70° C. to ≤110° C.;
wherein the filament, during the application process, has an application temperature of ≥100° C. above the melting point of the fusible polymer for ≤20 minutes. There are furthermore blocked NCO groups present in the material comprising the fusible polymer.

The invention relates to an adhesive film which comprises a layer of an adhesive that comprises one or more polymers and at least one peroxide, characterized in that the adhesive comprises at last 50% by weight of thermoplastic polymers that do not have C═C multiple bonds, in that at least one peroxide has the general structural formula R—O—O—R′, wherein R and R′ each represent organyl groups or together represent a cyclic organyl group, and in that the peroxide in solution has a 1-minute half-life temperature of less than 200° C. In a preferred embodiment, the thermoplastic polymer is a polyurethane and the peroxide is a dicumyl peroxide.

Aqueous polyurethane dispersions and coatings and heat-activatable adhesives made from the dispersions are disclosed. The dispersions include a polyurethane reaction product of a polyester polyol and a polyisocyanate. The polyester polyol comprises recurring units of at least one C.sub.2-C.sub.6 aliphatic diol, at least one aliphatic or cycloaliphatic C.sub.4-C.sub.10 dicarboxylic acid, and an aromatic diacid source, which can be recycled PET. The dispersion is formulated using 1 to 3 moles of an acid-functional diol per mole of polyester polyol. Dispersions for the adhesives are produced at NCO/OH molar ratios within the range of 0.90 to 0.98. The adhesives successfully bond a wide range of plastic and metal materials, often demonstrating substrate failure, even with steel. This contrasts with commercial adhesives such as EVA that exhibit only adhesive failure with the same substrates.

Disclosed is a method of producing a fabric product, the method comprising preparing an upper; preparing a lining fabric; layering a thermoplastic hot-melt film between the upper and the lining fabric for bonding the upper and the lining fabric; bonding a lining fabric to the upper, wherein the thermoplastic hot-melt film consists of the composition selected from the group consisting of thermoplastic polyurethane, ethylene vinyl acetate, polyamide and polyester compositions, wherein the thermoplastic hot-melt film further contains nanosilica, wherein a content of the nanosilica is 0.1 to 5.0 Parts per Hundred Resin (phr) and a size of the nanosilica is less than 100 nm.

A laminate 10 includes: a foamed polyurethane layer 11 obtained from a foamable polyurethane resin composition containing an active hydrogen group-containing tin ricinoleate and a phosphorus-containing solid flame retardant; and a coating layer 15 adhered to the foamed polyurethane layer 11 by a polyurethane hot melt adhesive 13 containing a polyurethane prepolymer (I) obtained by using a polyol component (A) and a polyisocyanate component (B) as raw materials, and a catalyst (II).

The invention relates to an adhesive film which comprises a layer of an adhesive that comprises one or more polymers and at least one peroxide, characterized in that the adhesive comprises at last 50% by weight of thermoplastic polymers that do not have C═C multiple bonds, in that at least one peroxide has the general structural formula R—O—O—R′, wherein R and R′ each represent organyl groups or together represent a cyclic organyl group, and in that the peroxide in solution has a 1-minute half-life temperature of less than 200° C. In a preferred embodiment, the thermoplastic polymer is a polyurethane and the peroxide is a dicumyl peroxide.

One-component, moisture-curable polyurethane adhesives exhibit excellent handling strength before being fully cured, and excellent creep properties after curing. The adhesives include an isocyanate-terminated prepolymer made from polyols that include a crystalline polyester and hydroquinone bis (2-hydroxyethyl) ether, and a polyoxazolidine compound.

Phthalonitrile adhesive formulations are provided. Such an adhesive formulation may comprise an etherimide-phthalonitrile oligomer having formula ##STR00001## wherein R.sub.1 is an unsubstituted or substituted aryl group or an unsubstituted or substituted cycloalkyl group; R.sub.2 is an unsubstituted or substituted aryl group and n has a value of from 1 to 30. Also provided are methods of making and using the adhesive formulations.