Patent classifications
C08J3/005
METHOD FOR PRODUCING THERMOPLASTIC ELASTOMER COMPOSITION
Provided is a method for producing a thermoplastic elastomer composition that can form a molded article having both good appearance and high stiffness. The method for producing a thermoplastic elastomer composition comprises the following first step and second step, wherein the produced thermoplastic elastomer composition contains 5 mass % or less of a mineral oil (C): first step: a step of melt-kneading polypropylene (A-1) and an ethylene-based copolymer rubber (B) in the presence of an organic peroxide, the polypropylene (A-1) being polypropylene of which 20° C. xylene insoluble fraction has an intrinsic viscosity [η.sub.cxis] of 0.1 dl/g or more and less than 1.5 dl/g; and second step: a step of further adding polypropylene (A-2) of which 20° C. xylene insoluble fraction has an intrinsic viscosity [η.sub.cxis] of 1.5 dl/g or more and 7 dl/g or less, and melt-kneading the resulting mixture.
LIQUID CHLORIDE SALT-BASED POLYMER SUSPENSION FLUIDS WITH POLYETHYLENE GLYCOL DISPERSANTS AND APPLICATION TO DRAG REDUCTION
Aqueous suspensions are presented that are stable against settling without additional mixing in which the suspensions comprise a water soluble polymer that is anionic or non-ionic comprising a blend of water with at least about 32 wt % chloride salt with a counter ion A.sup.+a with 2≤a, from about 1 wt % to about 10 wt % particulate polyethylene glycol having an average molecular weight from about 1600 g/mol to about 50,000 g/mol, and from about 10 wt % to about 50 wt % of the water soluble polymer that is not a polyether. The suspensions have chlorides in a sufficient amount to inhibit hydration of the suspended water soluble polymer and the particulate polyethylene glycol. The aqueous suspension can be formed by adding a powder of polyethylene glycol to a high salt solution and then adding the high molecular weight polymer. The aqueous suspensions can be useful as friction reducing agents in flowing liquids, such as for hydraulic fracture.
Method for producing a polycondensate melt from a first partial melt stream and a second partial melt stream, with increasing or reducing an intrinsic viscosity of the second partial melt
A method for producing a polycondensate melt from a primary material and a secondary material from materials of substantially the same type is provided. A first partial melt stream of the primary material and a second partial melt stream of the secondary material are provided, and a measured value of the intrinsic viscosity of both partial melt streams is determined, and a difference value is calculated from the measured values. Based on the difference value, the intrinsic viscosity of the second partial melt stream is increased, reduced or maintained unchangedly by using a first melt treatment device. Subsequently, the two partial melt streams are combined into a common melt stream.
Cross-linkable polyolefin composition comprising a first and a second olefin polymer
The present invention relates to a cross-linkable polyolefin composition comprising a first olefin polymer (A) comprising a first comonomer comprising epoxy groups, and a second olefin polymer (B) comprising a second comonomer comprising carboxylic acid groups and/or precursor thereof.
Bimodal high-density polyethylene resins and compositions with improved properties and methods of making and using the same
Bimodal high-density polyethylene polymer compositions with increased high melt strength and good processability. The compositions comprise a base resin having a density of about 945 kg/m.sup.3 to about 955 kg/m.sup.3, and an ethylene polymer (A) having a density of at least about 968 kg/m.sup.3, in an amount ranging from 45% to 55% by weight and an ethylene polymer (B) having a density lower than the density of polymer (A). The composition has a complex viscosity at a shear rate of 0.01 rad/s ranging from about 200 to 450 kPa.Math.s and a complex viscosity at a shear rate of 100 rad/s ranging from about 1900 to 2500 Pa.Math.s. Articles made from these compositions, such as pipes and fittings achieve long-term oxidative resistance and have a low wall thickness variability while maintaining high production output.
Artificial timber
An artificial timber comprises the following components in parts by weight: 35-50 parts of cellulose, 20-35 parts of hemicellulose and 15-35 parts of lignin, wherein the artificial timber has a density of 0.01-0.05 g/cm.sup.3. The preparing method comprises: (1) dissolving 15-35 parts by weight of lignin, 35-50 parts by weight of cellulose and 20-35 parts by weight of hemicellulose with an ionic liquid; (2) cleaning and replacing it with water to obtain a lignocellulose hydrogel; and (3) drying the lignocellulose hydrogel to obtain an artificial timber. The artificial timber prepared by the present invention is large in specific area, low in density, low in material energy consumption, moderate in condition and easy for operation. The artificial timber obtained by the present invention is regular in shape and is shaped like a sandy beige cylinder without obvious damage and deformation, which indicates that such artificial timber with high specific area has well molding capacity.
Thermoplastic resin composition, method of producing thermoplastic resin composition, molded article of cellulose-reinforced resin, and method of producing molded article of cellulose-reinforced resin
A method of producing a thermoplastic resin composition containing a thermoplastic synthetic resin and a cellulose, in which at least one type of the thermoplastic synthetic resin is a resin having a group containing a partial structure of an acid anhydride in the polymer molecule; a molded article of a cellulose-reinforced resin; and a method of producing a molded article of a cellulose-reinforced resin.
Cellulose based composition
The present invention concerns a cellulose based composition for manufacturing a film or foil, which composition comprises at least one selected from the group consisting of cellulose acetate butyrate, cellulose acetate propionate and ethyl cellulose, together with tall oil fatty acid ester, as well as a manufacturing method thereof. The invention also concerns packaging film comprising the composition and use of the composition.
Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom
Pellet-stable olefinic copolymer bimodal rubber is made using parallel reactors, with one reactor synthesizing higher molecular weight (MW) rubber with dual catalysts, with an improved molecular weight split ratio and an improved composition distribution of the moderate and ultra-high MW components, while another reactor synthesizes random isotactic polypropylene copolymer (RCP). The effluents are reactor-blended and result in pellet-stable bimodal rubber (P-SBR), which may be pelletized. When making thermoplastic vulcanizates (TPVs) with P-SBR, the need to granulate rubber bales and subsequently use talc, clay, or other anti-agglomeration agents to prevent granulated rubber crumbs from agglomerating are eliminated. TPVs made with P-SBR have vulcanized rubber particles that are smaller and more uniform in size, resulting in TPVs with higher particle counts and more thermoplastic “ligaments” between the particles, with such ligaments being made stronger by the added RCP. Such thus-produced TPVs have a lower hysteresis and flexural modulus, and better elastic properties.
Ethylene-based polymer, method of producing ethylene-based polymer, and film
Provided are an ethylene-based polymer capable of obtaining a film in which thickness unevenness is reduced, a method of producing the ethylene-based polymer, and a film containing the ethylene-based polymer. In the ethylene-based polymer according to the present invention, the following Expressions (1) and (2) are satisfied:
0.362≤ηL.sup.1,256%/ηL.sup.10%≤0.466 (1)
0.0282≤I5.sup.2,506%/I1.sup.2,506%≤0.0328 (2).