C08J3/20

Multifunctional particle additive for enhancement of toughness and degradation in biodegradable polymers
11542392 · 2023-01-03 · ·

Disclosed is a biodegradable resin composite material including a biodegradable polymer resin and multifunctional particles, wherein: (a) the multifunctional particles include 10-70 wt. % of a hydrophobic active ingredient, 21-72 wt. % of a polysaccharide, 3.80-20 wt. % of a crosslinking agent, 1.00-6 wt. % of a catalyst, 0.10-5 wt. % of a silica flow aid, optionally 0.10-5 wt. % of a desiccant, optionally 0.20-20 wt. % emulsifier, optionally 1-10 wt. % of a degradation enhancer, and optionally 1-10 wt. % of particle dispersion aids; (b) the multifunctional particles are anhydrous; and (c) the hydrophobic active ingredient is encapsulated in a crosslinked polysaccharide matrix. Alternative multifunctional particles useful in the invention are also disclosed.

METHOD FOR THE MANUFACTURE OF POLY(ALIPHATIC ESTER-CARBONATE) COMPOSITIONS AND ARTICLES THEREOF

A process of preparing a compounded hydrostable poly(aliphatic ester-carbonate) comprises providing a hydrostable poly(aliphatic ester-carbonate), compounding in an extruder the hydrostable poly(aliphatic ester-carbonate) and 0.05 wt % to 0.60 wt % of a multifunctional epoxide compounding stabilizer, based on the total weight of the compounded hydrostable poly(aliphatic ester-carbonate), under vacuum of 17000 to 85000 Pascals, and a torque of 30% to 75%, to provide the compounded hydrostable poly(aliphatic ester-carbonate). After compounding, at least one of the following apply: the inter-sample variability in molecular weight is less than 5%, wherein inter-sample variability is determined by comparing five 100 mil chips of the compounded hydrostable poly(aliphatic ester-carbonate); the % weight average molecular weight (MW) difference is less than 5% after hydroaging at 85° C. and 85% humidity; or the compounded poly(aliphatic ester-carbonate) has less than 75 ppm of unreacted —COOH end groups measured by .sup.31P NMR.

Hydrolysis-resistant compositions comprising polyethylene terephthalate (PET)
20220411605 · 2022-12-29 · ·

The invention relates to hydrolysis-resistant compositions comprising polyethylene terephthalate (PET), production processes, and use of the said compositions.

In-vehicle lithium ion battery member

An in-vehicle lithium ion battery member produced by molding a resin composition containing (a) a polyphenylene ether resin, the resin composition having a critical strain in a chemical resistance evaluation of 0.5% or more and a Charpy impact strength at 23° C. of 20 kJ/m.sup.2 or more.

NON-HALOGENATED FLAME RETARDANT AND REINFORCED POLY(ALKYLENE TEREPHTHALATE) POLY(PHENYLENE ETHER) COMPOSITIONS METHODS OF MANUFACTURE AND USES THEREOF
20220403158 · 2022-12-22 ·

A reinforced flame retardant composition comprising: 30-80 wt % of a polymer component comprising 25-65 wt % of a poly(alkylene terephthalate); 5-25 wt % of a poly(phenylene ether); optionally, 5-35 wt % of a polyamide; 5-30 wt % of a reinforcing mineral filler, preferably talc, 5-35 wt % of glass fibers; 4-25 wt % of a flame retardant component comprising: a metal di(C.sub.1-6alkyl)phosphinate and an auxiliary flame retardant; 0.01-2 wt % of a compatibilizing agent; 5-15 wt % of an impact modifier; wherein a molded sample of the composition has a UL94 rating of V0 at thicknesses of 1.5 mm and lower; and a comparative tracking index of 250-399 volts, preferably 400-599 volts, more preferably 600 volts or greater as determined in accordance with UL 746A, a mean time of arc resistance of at least 120 seconds as determined according to ASTM D495, or a combination thereof.

IMMOBILIZATION OF INSOLUBLE PARTICLES IN POLYMER

A method of immobilization of an insoluble dopant. In some embodiments, the insoluble dopant comprises a coordination polymer. In some embodiments, the insoluble dopant comprises a vapochromic coordination polymer. The method may comprise dissolving a polymer carrier in a solvent. The polymer carrier may comprise a thermoplastic such as, but not limited to, polylactic acid, polyethylene glycol or polycarbonate. The insoluble dopant (e.g. a coordination polymer such as a vapochromic coordination polymer) may then be mixed into the dissolved polymer. Phase separation of the mixture of the dopant and dissolved polymer may be induced to form a hydrogel. The hydrogel may be employed as is (e.g. as a raw material for hydrogel 3D printing, as a sensing material, etc.) or may undergo further processing (e.g. solidification, grinding, extrusion, etc.) before being employed, for example, as a raw material for 3D printing, as a sensing material, etc.

Perovskite-polymer composites and methods

Perovskite-polymer composites including perovskite nanocrystals dispersed in a polymer matrix, wherein the perovskite nanocrystals have an average size of from about nm to about 20 nm. Methods for producing a perovskite-polymer composites that may include contacting a solid material comprising a polymer matrix with a solution comprising a perovskite precursor; allowing the solution to penetrate the solid material to yield a swollen solid material comprising the perovskite precursor dispersed within the polymer matrix; optionally contacting the swollen solid material with an antisolvent; and annealing the swollen solid material to crystallize the perovskite precursor and to yield the perovskite-polymer composite comprising perovskite nanocrystals dispersed in the polymer matrix.

BIODEGRADABLE POLYMER NANOCOMPOSITE AND METHOD FOR PRODUCTION THEREOF
20220396685 · 2022-12-15 ·

Disclosed is a method for producing biodegradable polymer nanocomposite, the method comprising dispersing a plurality of graphene nanoplatelets into a matrix of biodegradable polymer and extruding the matrix of biodegradable polymer containing the plurality of graphene nanoplatelets to obtain the biodegradable polymer nanocomposite.

GRAPHENE OXIDE-DOPED POLYVINYLIDENE FLUORIDE PARTICLES WITH ENHANCED BETA-PHASE CRYSTALLINITY

High spherical particles for use in piezoelectric applications may be produced mixing a mixture comprising a graphene oxide-polyvinylidene fluoride (GO-PVDF) composite, a carrier fluid that is immiscible with the PVDF, and optionally an emulsion stabilizer at a temperature equal to or greater than a melting point or softening temperature of the PVDF to disperse the GO-PVDF composite in the carrier fluid, wherein the GO-PVDF composite has a transmission FTIR minimum transmittance ratio of β-phase PVDF to α-phase PVDF of about 1 or less; cooling the mixture to below the melting point or softening temperature of the PVDF to form GO-PVDF particles; and separating the GO-PVDF particles from the carrier fluid, wherein the GO-PVDF particles comprise the graphene oxide dispersed in the PVDF, and wherein the GO-PVDF particles have a transmission FTIR minimum transmittance ratio of β-phase PVDF to α-phase PVDF of about 1 or less.

Method for manufacturing room-temperature-curable organopolysiloxane composition, room-temperature-curable organopolysiloxane composition, and article

Through the present invention, by undergoing a step in which a straight-chain diorganopolysiloxane having silanol groups at both terminal ends of the molecular chain thereof, a hydrolyzable silane and/or a partial hydrolysis condensate thereof having a hydrolyzable group capable of detaching a lactic acid ester, and an amino-group-containing hydrolyzable organosilane and/or a partial hydrolysis condensate thereof are pre-mixed/reacted in advance and silanol groups at both terminal ends of the molecular chain of a main agent (base polymer) are blocked by specific hydrolyzable silyl groups, it is possible to manufacture a lactic-acid-ester-type room-temperature-curable organopolysiloxane composition excellent in all characteristics including curability, adhesive properties, workability, and the like that were not attainable by the conventional lactic-acid-ester-type room-temperature curable (RTV) silicone rubber composition.