C08J3/24

Process for enhancing the melt strength of propylene-based polymer compositions

Disclosed is a process for preparation of a propylene-based polymer composition involving the steps of: (a) mixing a propylene-based polymer and a peroxydicarbonate in a mixing device, wherein the mixing takes place at a temperature of ≤30° C., wherein the peroxydicarbonate is introduced into the mixing process in a dry form; (b) keeping the mixed composition at a temperature of ≤30° C.; (c) feeding the mixed composition into a melt extruder; (d) homogenizing the mixed composition at a temperature where the propylene-based polymer is in solid state during an average residence time of ≥6.0 and ≤30.0 seconds; (e) further homogenizing the mixed composition at a temperature at which the propylene-based polymer is in the molten state; and (f) extruding the homogenized material from a die outlet of the melt extruder followed by cooling and solidification; wherein the steps (a) through (f) are conducted in that order.

Super absorbent resin having improved solidification resistance, and method for preparing same

Disclosed are a superabsorbent polymer having improved anti-caking properties and a method of preparing the same, and the superabsorbent polymer having improved anti-caking properties includes a superabsorbent polymer, microparticles, and water, and to improve anti-caking properties of the superabsorbent polymer, the temperature of the superabsorbent polymer or water upon addition of water or the aging time upon stirring is adjusted, thereby preventing caking of the particles.

Method for preparing super absorbent polymer

A method for preparing a super absorbent polymer and a superabsorbent polymer prepared from the same are disclosed herein. In some embodiments, a method includes mixing super absorbent polymer particles, water and an additive form a hydrated super absorbent polymer, wherein the super absorbent polymer particles comprise a base polymer powder including a cross-linked polymer polymerized from a water-soluble ethylenically unsaturated monomer having an acidic group of which at least a part is neutralized, and a surface cross-linked layer formed on the base polymer powder, wherein the surface cross-linked layer is formed by further cross-linking the cross-linked polymer, and wherein the additive including a polyoxyalkylene aliphatic hydrocarbon ether carboxylic acid. The method can appropriately control the water content of the super absorbent polymer by water-addition or the like to suppress crushing or the like during transfer, and also can suppress deterioration of physical properties.

Curative

An illustrative embodiment of a manufactured surface component may be comprised of a textile material on a first face and an elastomer material on a second face, wherein said elastomer material is bonded to said textile material, wherein said manufactured surface component is substantially planarly configured, wherein an area of said first face and said second face is from about 0.04 square inches to about 4.0 square inches, wherein a thickness of said manufactured surface component is from about 0.3 mm to about 2.5 mm, and wherein said manufactured surface component is substantially free of any petrochemical-derived plastics, petrochemicals, and toxins.

Curative

An illustrative embodiment of a manufactured surface component may be comprised of a textile material on a first face and an elastomer material on a second face, wherein said elastomer material is bonded to said textile material, wherein said manufactured surface component is substantially planarly configured, wherein an area of said first face and said second face is from about 0.04 square inches to about 4.0 square inches, wherein a thickness of said manufactured surface component is from about 0.3 mm to about 2.5 mm, and wherein said manufactured surface component is substantially free of any petrochemical-derived plastics, petrochemicals, and toxins.

Tunable, rapid uptake, aminopolymer aerogel sorbent for direct air capture of CO.SUB.2

A porous polymer aerogel, wherein the aerogel has greater than 5 wt % of amine containing vinyl monomers integrated into a polymer backbone. A method of fabrication of a porous polymer aerogel amine material, includes preparing a solution comprising at least a solvent, amine monomers having protected amino groups, one or more crosslinkers, one or more radical initiators, and a nitroxide mediator, removing oxygen from the solution, heating the solution to promote polymerization and to produce a polymerized material, performing solvent exchange with the polymerized material, causing a deprotection reaction in the polymerized material to remove groups protecting the amino groups, soaking and rinsing the material to remove excess reagents and any byproducts of the deprotection reaction, and drying the material to produce the amine sorbent. A system to separate CO2 from other gases, comprising a polymer porous aerogel sorbent having greater than 5 wt % of amine containing vinyl monomers integrated into a polymer backbone.

Tunable, rapid uptake, aminopolymer aerogel sorbent for direct air capture of CO.SUB.2

A porous polymer aerogel, wherein the aerogel has greater than 5 wt % of amine containing vinyl monomers integrated into a polymer backbone. A method of fabrication of a porous polymer aerogel amine material, includes preparing a solution comprising at least a solvent, amine monomers having protected amino groups, one or more crosslinkers, one or more radical initiators, and a nitroxide mediator, removing oxygen from the solution, heating the solution to promote polymerization and to produce a polymerized material, performing solvent exchange with the polymerized material, causing a deprotection reaction in the polymerized material to remove groups protecting the amino groups, soaking and rinsing the material to remove excess reagents and any byproducts of the deprotection reaction, and drying the material to produce the amine sorbent. A system to separate CO2 from other gases, comprising a polymer porous aerogel sorbent having greater than 5 wt % of amine containing vinyl monomers integrated into a polymer backbone.

FUNCTIONALIZED POLY(ARYL ETHER SULFONES) COPOLYMERS AND POLYMER ADDUCTS OBTAINED THEREFROM
20220348720 · 2022-11-03 ·

The present invention relates to copolymers comprising moieties able to undergo a crosslinking reaction under certain stimuli, thereby forming polymer adducts having improved or additional properties, such as resistance to solvents, increased thermal performance and increased adhesion to surfaces.

ARTICLE COMPRISING MODIFIED TUBULAR LOW DENSITY POLYETHYLENE

Process for obtaining polyethylene with an MFI (190° C./2.16 kg) of at least 4 g/10 minutes and a melt strength (190° C.) of at least 8.0 cN, said process involving extrusion of low density polyethylene (LDPE) with an MFI of at least 5 g/10 minutes and a vinyl content of less than 0.25 terminal vinyl groups per 1000 C-atoms (measured with NMR in deuterated tetrachloroethane solution)—in the presence of 500-5,000 ppm, based on the weight of low density polyethylene, of an organic peroxide.

ARTICLE COMPRISING MODIFIED TUBULAR LOW DENSITY POLYETHYLENE

Process for obtaining polyethylene with an MFI (190° C./2.16 kg) of at least 4 g/10 minutes and a melt strength (190° C.) of at least 8.0 cN, said process involving extrusion of low density polyethylene (LDPE) with an MFI of at least 5 g/10 minutes and a vinyl content of less than 0.25 terminal vinyl groups per 1000 C-atoms (measured with NMR in deuterated tetrachloroethane solution)—in the presence of 500-5,000 ppm, based on the weight of low density polyethylene, of an organic peroxide.