The present disclosure relates to a protective glove, which has different polymer layers arranged in a multi-layered polymer composite material. According to the present disclosure, the protective glove contains polyvinyl alcohol and a protective layer on top of this containing a fluorinated elastomer. The present disclosure also relates to a method for manufacturing a protective glove of this kind. The combination of various polymers and their arrangement in the polymer composite material achieve a powerful protective action against a multitude of chemical compound classes while simultaneously producing advantageous mechanical properties.

An elastomeric article having a rubber component comprising polyisoprene and an aldehyde aniline condensate, the elastomeric article having less than 1 ppm diisopropyl xanthogen polysulfide residue.

A chloroprene copolymer latex containing a chloroprene copolymer having a structural unit derived from chloroprene and a structural unit derived from 2,3-dichloro-1,3-butadiene, in which a toluene insoluble content in the chloroprene copolymer is 50 to 95% by mass, and a modulus at 500% elongation of a film, which is obtained on a base material by dipping the base material in the chloroprene copolymer latex and then performing vulcanization at 100° C. for 30 minutes, according to JIS K 6251 is 4.0 MPa or less.

This application relates to synthetic elastomeric articles, and gloves in particular, comprising the cured product of a synthetic latex composition, the synthetic latex composition comprising a synthetic carboxylated polymer and a cross-linking composition, the cross-linking composition comprising an aqueous solution of a negatively charged multivalent metal complex ion having a pH of at least 9.0. Also described are compositions for forming the articles, and methods for making the articles, based on the use of the described cross-linking composition. The articles so produced have an average thickness of 0.2 mm or less and a modulus at 500% of less than 6.5 MPa.

This application relates to synthetic elastomeric articles, and gloves in particular, comprising the cured product of a synthetic latex composition, the synthetic latex composition comprising a synthetic carboxylated polymer and a cross-linking composition, the cross-linking composition comprising an aqueous solution of a negatively charged multivalent metal complex ion having a pH of at least 9.0. Also described are compositions for forming the articles, and methods for making the articles, based on the use of the described cross-linking composition. The articles so produced have an average thickness of 0.2 mm or less and a modulus at 500% of less than 6.5 MPa.

This application relates to synthetic elastomeric articles, such as gloves, comprising the cured product of a synthetic latex composition, the synthetic latex composition comprising a synthetic carboxylated polymer and a cross-linking composition, the cross-linking composition comprising an aqueous solution of a negatively charged multivalent metal complex ion having a pH of at least 9.0. Also described are compositions for forming the articles, and methods for making the articles, based on the use of the described cross-linking composition. The articles, compositions and methods contain an aqueous solution of a multimetal oxide of the multivalent metal, a hydroxide of the multivalent metal, or a salt of the multivalent metal, such as sodium aluminate, in an amount of less than 0.3 phr. The articles produced have a thickness of between 0.01-3 mm and an unaged tensile strength of at least 15 MPa.

This application relates to synthetic elastomeric articles, such as gloves, comprising the cured product of a synthetic latex composition, the synthetic latex composition comprising a synthetic carboxylated polymer and a cross-linking composition, the cross-linking composition comprising an aqueous solution of a negatively charged multivalent metal complex ion having a pH of at least 9.0. Also described are compositions for forming the articles, and methods for making the articles, based on the use of the described cross-linking composition. The articles, compositions and methods contain an aqueous solution of a multimetal oxide of the multivalent metal, a hydroxide of the multivalent metal, or a salt of the multivalent metal, such as sodium aluminate, in an amount of less than 0.3 phr. The articles produced have a thickness of between 0.01-3 mm and an unaged tensile strength of at least 15 MPa.

One embodiment of the present invention relates to a chloroprene copolymer latex, a method for producing a chloroprene copolymer latex, a chloroprene copolymer latex composition, and a molded article or dipped product of a chloroprene copolymer rubber. The chloroprene copolymer latex is a latex of a chloroprene copolymer including monomer units derived from 2-chloro-1,3-butadiene (chloroprene) and monomer units derived from 2-methyl-1,3-butadiene, wherein the tetrahydrofuran insoluble content in the chloroprene copolymer is 20% by mass or less, and the proportion of the monomer units derived from 2-methyl-1,3-butadiene is 10 to 27 mol % in the chloroprene copolymer.

One embodiment of the present invention relates to a chloroprene copolymer latex, a method for producing a chloroprene copolymer latex, a chloroprene copolymer latex composition, and a molded article or dipped product of a chloroprene copolymer rubber. The chloroprene copolymer latex is a latex of a chloroprene copolymer including monomer units derived from 2-chloro-1,3-butadiene (chloroprene) and monomer units derived from 2-methyl-1,3-butadiene, wherein the tetrahydrofuran insoluble content in the chloroprene copolymer is 20% by mass or less, and the proportion of the monomer units derived from 2-methyl-1,3-butadiene is 10 to 27 mol % in the chloroprene copolymer.

A latex composition for dip molding includes a carboxylic acid-modified nitrile-based copolymer latex having pKa of 9.5 to 10.2 and satisfying General Formulas 1 and 2.

0.85≤P≤1.0, P=CV.sub.D/CV.sub.0  [General Formula 1]

5≤M≤20, M=m.sub.1×m.sub.2  [General Formula 2] wherein CV.sub.0 represents a capillary viscosity which is measured in a swollen in a methyl ethyl ketone solvent, CV.sub.D represents a capillary viscosity in a deswollen state, m.sub.1 represents an insolubility of a dried film in the methyl ethyl ketone solvent, and m.sub.2 represents a swelling index of the dried film in the methyl ethyl ketone solvent, wherein a carboxylic acid-modified nitrile-based copolymer of carboxylic acid-modified nitrile-based copolymer latex includes: a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit. A molded article having a layer derived from the latex composition is also provided.