A monolayer membrane containing gelling polymer particles having at least one of a basic functional group and an acidic functional group, and having a thickness of less than 5 μm. A composite having a porous carrier and gelling polymer particles having at least any one of a basic functional group and an acidic functional group and filling up the surface pores of the porous carrier. The invention can provide a novel material capable of efficiently separating an acid gas from a mixed gas.

The present invention provides a lithium secondary battery including a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode, and a gel polymer electrolyte formed by polymerizing an oligomer, wherein one or more electrodes selected from the positive electrode and the negative electrode includes an electrode current collector, an electrode active material layer formed on the electrode current collector, and a coating layer formed on the electrode active material layer and including a first binder, and the first binder is bonded to the gel polymer electrolyte.

An amorphous composite solid electrolyte is provided that includes one or more three-dimensional branched macromolecules with a core portion and at least three arm portions connected to the core portion. Each arm portion includes a random copolymer or a block polymer comprising a first monomer and a second monomer with a molar ratio of the first monomer to the second monomer in the range from greater than 0 to less than or equal to 1. An ion conductive electrolytic solution including at least one lithium salt solution in an amount of approximately 1 mol/l to 10 mol/l is entrained within the branched macromolecule, with a weight ratio of the branched macromolecule to the ion conducive electrolytic solution equal to or lower than 1:9, such that the branched macromolecule has a swelling degree of at least 5:1 (liquid:polymer in weight) of the ion conductive electrolytic solution.

A novel solid block copolymer electrolyte material is described. The material has first structural polymer blocks that make up a structural domain that has a modulus greater than 110.sup.7 Pa at 25 C. There are also second ionically-conductive polymer blocks and a salt that make up an ionically-conductive domain adjacent to the structural domain. Along with the second ionically-conductive polymers, there is also a crosslinked network of third polymers, which interpenetrates the ionically-conductive domain. The third polymers are miscible with the second polymers. It has been shown that the addition of such an interpenetrating, crosslinked polymer network to the ionically-conductive domain improves the mechanical properties of the block copolymer electrolyte with no sacrifice in ionic conductivity.

A novel solid block copolymer electrolyte material is described. The material has first structural polymer blocks that make up a structural domain that has a modulus greater than 110.sup.7 Pa at 25 C. There are also second ionically-conductive polymer blocks and a salt that make up an ionically-conductive domain adjacent to the structural domain. Along with the second ionically-conductive polymers, there is also a crosslinked network of third polymers, which interpenetrates the ionically-conductive domain. The third polymers are miscible with the second polymers. It has been shown that the addition of such an interpenetrating, crosslinked polymer network to the ionically-conductive domain improves the mechanical properties of the block copolymer electrolyte with no sacrifice in ionic conductivity.

A solvent-free polymer electrolyte having a polymer matrix which is conductive for lithium ions and a lithium salt, wherein the polymer matrix has at least one pseudo-polyrotaxane which includes at least one linear polymer and at least one ring-shaped molecule, and wherein the lithium salt is arranged in the polymer matrix and is at least partially chemically bonded to the polymer matrix, wherein the polymer matrix includes at least one pseudo-polyrotaxane with at least one completely or partially chemically modified cyclodextrin or at least one completely or partially chemically modified crown ether, in which the present hydroxyl groups of the cyclodextrin, or the scaffold of the crown ether, are/is partly or completely modified by functional groups, wherein the functional groups comprise alkyl, aryl, alkenyl, alkynyl groups (C.sub.n, with n5), or other short-chain polymer groups having up to 20 repeating units.

A polymer electrolyte is disclosed, the polymer electrolyte includes a poly ethylene oxide (PEO)-acrylate chain comprising a plurality of ethylene oxide molecules. The PEO-acrylate chain is linked to a polyhedral oligomeric silsesquioxane (POSS) chain comprising a plurality of POSS molecules, thereby forming a block copolymer. The polymer electrolyte also includes salt molecules, the concentration of which may change the ionic conductivity of the polymer electrolyte.

A copolymer for constituting a polymer electrolyte for a solid-electrolyte lithium or sodium cell. A polymer electrolyte that is usable in combination with high-voltage cathode active materials and makes it possible to provide solid-electrolyte lithium or sodium cells and/or batteries having a high energy density that is sufficient even for use in electricity-based vehicles, the copolymer encompasses at least two ion-conductive polymers, the copolymer encompassing at least one polymer polymerized by ring-opening polymerization of at least one lactone and/or of at least one lactide and/or of at least one cyclic carbonate and/or of at least one cyclic carbamate and/or of at least one lactam and/or of at least one epoxide, and/or at least one polymer polymerized by radical polymerization of acrylonitrile and/or of at least one acrylonitrile derivative; and encompasses at least one polyacrylate having at least one repeating unit.

The present disclosure is directed to polymeric beads, methods of making the beads, and methods of using the beads as high-capacity anion exchange materials. In particular, the disclosure provides polymeric beads comprising a cross-linked polyamine and having a crush strength of about 250 g/bead or more. Preferably, the beads are substantially spherical. Also disclosed are polymeric beads comprising a cross-linked polyamine that has a substantial number of both strong base sites and weak base sites. Methods of using the polymeric beads in various industrial applications, such as groundwater remediation, radio waste management, municipal wastewater management, demineralization, toxin removal, mining, food refinery, research, agriculture, and the like, are also disclosed herein.

The present disclosure is directed to polymeric beads, methods of making the beads, and methods of using the beads as high-capacity anion exchange materials. In particular, the disclosure provides polymeric beads comprising a cross-linked polyamine and having a crush strength of about 250 g/bead or more. Preferably, the beads are substantially spherical. Also disclosed are polymeric beads comprising a cross-linked polyamine that has a substantial number of both strong base sites and weak base sites. Methods of using the polymeric beads in various industrial applications, such as groundwater remediation, radio waste management, municipal wastewater management, demineralization, toxin removal, mining, food refinery, research, agriculture, and the like, are also disclosed herein.