Patent classifications
C08J7/08
Heat-Induced Grafting Of Nonwovens For High Capacity Ion Exchange Separation
The invention provides methods for preparing a polymer-grafted and functionalized nonwoven membrane adapted for use in separation processes. The invention further provides so-formed membranes as well as improved separation methods utilizing the membranes. The polymer-grafted and functionalized nonwoven membranes are particularly formed utilizing thermal grafting. In particular, an acrylate or methacrylate polymer can be grafted onto a nonwoven web comprising a plurality of polymeric fibers to form a plurality of polymer segments covalently attached to the polymeric fibers. Thermal grafting particularly can comprise using a thermal initiator and exposing the nonwoven web to heat to initiate polymerization of the acrylate or methacrylate monomer. The grafted polymeric fibers can be functionalized to attach at least one functional group adapted for binding to a target molecule to the polymer segments of the grafted polymeric fibers.
Propylene-based resin microporous film, separator for battery, battery, and method for producing propylene-based resin microporous film
The present invention provides a propylene-based resin microporous film which has excellent lithium ion permeability, can constitute a high-performance lithium ion battery, and can prevent a short circuit between a positive electrode and a negative electrode due to dendrites. The propylene-based resin microporous film of the present invention is a propylene-based resin microporous film containing micropores, wherein the degree of gas permeability is 100 to 400 s/100 mL, the standard deviation of the degree of gas permeability is 7 s/100 mL or less, the thermal shrinkage ratio during heating at 105 C. for 2 hours is 6% or less, and the standard deviation of the thermal shrinkage ratio is 1% or less.
Method for making carbon nanotube composite structure
A method for making a carbon nanotube composite structure includes providing a polymer substrate having a first surface and a second surface opposite to the first surface. A first carbon nanotube layer including a plurality of carbon nanotubes is placed on the first surface to form a preformed structure, wherein the carbon nanotube layer and the polymer substrate are stacked with each other. The preformed structure is scanned with a laser according to a predetermined pattern. The treated preformed structure includes a first part and a second part. The first part is scanned by the laser, and the second part is not scanned by the laser. The first part includes a plurality of first carbon nanotubes, and the second part includes a plurality of second carbon nanotubes. The plurality of second carbon nanotubes is removed.
PRODUCTION METHOD OF POLYTETRAFLUOROETHYLENE PARTICLE
A method for producing a polytetrafluoroethylene particle, which includes subjecting tetrafluoroethylene to suspension polymerization in an aqueous medium to prepare a suspension-polymerized particle of polytetrafluoroethylene, washing and then crushing the suspension-polymerized particle or crushing the suspension-polymerized particle with washing to prepare a crushed particle, dehydrating the crushed particle to prepare a crushed particle having a water content of 40% by mass or less, and subjecting the dehydrated crushed particle to heat treatment to produce a polytetrafluoroethylene particle.
Heat-resistant synthetic resin microporous film and method for producing the same
Provided are a heat-resistant synthetic resin microporous film that has both good heat resistance and good mechanical strength and exhibits a suppressed decrease in mechanical strength over time, and a method for producing the heat-resistant synthetic resin microporous film. The heat-resistant synthetic resin microporous film of the present invention includes a synthetic resin microporous film, and a coating layer formed on at least part of the surface of the synthetic resin microporous film and containing a polymer of a polymerizable compound having two or more radically polymerizable functional groups per molecule. The maximum thermal shrinkage rate of the heat-resistant synthetic resin microporous film when heated from 25 C. to 180 C. at a temperature rising rate of 5 C./min is 15% or less. The piercing strength thereof is 0.6 N or more. The rate of retention of the piercing strength after heating at 70 C. for 168 hours is 85% or more.
Melt-processable perfluoropolymers having improved thermal and mechanical properties after heating treatment
The invention mainly pertains to a method for heat treating a composition [composition (C)] which contains at least one melt-processible perfluoropolymer [polymer (F)] formed of tetrafluoroethylene (TFE) copolymer with one or more perfluorinated comonomers [comonomer (F)] containing at least one unsaturation of ethylene type in amounts from 0.5% to 13% by weight, preferably from 0.6% to 11% by weight, and more preferably from 0.8% to 9% by weight; said polymer (F) possessing reactive end groups comprising at least one of the group consisting of hydrogen atoms, oxygen atoms and ethylenically unsaturated double bonds in an amount of at least 4.5 mmol/kg, the process comprising at least the step of heat-treating the composition (C) at a temperature of at least 260 C.
Thermoplastic/Thermoset Grafted Composites
Disclosed are thermoset/thermoplastic composites that include a thermoset component directly or indirectly bonded to a thermoplastic component via a crosslinked binding layer between the two. The crosslinked binding layer is bonded to the thermoplastic component via epoxy linkages and is either directly or indirectly bonded to the thermoset component via epoxy linkages. The composite can be a laminate and can provide a route for addition of a thermoplastic implant to a thermoset structure.
MEANS FOR PREPARING A POLYMER FILM, AND A POLYMER FILM PREPARED THEREOF
The present invention relates to a method for preparing a polymer film, comprising the following steps: preparing a polymer film with a polymer solution prepared from PVDF and/or TPU; preparing a mixed solvent selected from a group consisting of dimethylformamide, dimethylacetamide, ethanol, water, or any combination thereof, wherein said mixed solvent is characterized by the solubility of said mixed solvent to the polymer selected for said polymer solution and/or the contact angle of said mixed solvent on said polymer film; wetting said polymer film with said mixed solvent; and subjecting the wet polymer film to thermal treatment under pressure.
Piezoelectric body film, piezoelectric body film production method, and piezoelectric body device
To provide a piezoelectric body film that can suppress decrease in the piezoelectric constant d31, a method of producing a piezoelectric body film, and a piezoelectric body device. A piezoelectric body film comprising a fluororesin as a piezoelectric material, the fluororesin containing, as a main constituent unit, a repeating unit derived from vinylidene fluoride, a piezoelectric constant d31 of the piezoelectric body film being 20 pC/N or greater, and an extrapolated onset temperature at start of shrinkage determined by TMA measurement being not lower than 90? C. and not higher than 115? C. The difference between piezoelectric constants d31 measured before and after heating the piezoelectric body film at 100? C. for 24 hours relative to the piezoelectric constant d31 before the heating for 24 hours is 20% or less.
Terminally-crosslinked methyl morpholinium-functionalized block copolymers, and anion exchange membranes using the same
The present disclosure herein relates to a terminally-crosslinked methyl morpholinium-functionalized block copolymer, and an anion exchange membrane using the same, and more particularly, to a terminally-crosslinked block copolymer which has a novel structure, and in which, in a poly(arylene ether sulfone) multiblock copolymer (MM-PES) having methyl morpholinium as a conducting group, an azide compound may be used as a crosslinking agent so that crosslinking only occurs at ends of the polymer chains (xMM-PES), thereby minimizing conductivity loss, significantly increasing mechanical and chemical stability, attaining additional conductivity resulting from the three-dimensional structure of morpholinium, and reducing water uptake while enhancing water retention capacity, uses thereof as an alkaline fuel cell anion exchange membrane (AEM), and a method for conveniently preparing the same through simple heat-treatment.