The present invention relates to a method for producing foam and foam produced thereby. The method for producing foam includes a step for producing foam by kneading and injection molding a first extrusion product and a second extrusion product, wherein the first extrusion product is obtained by extruding a first composition including an aromatic vinyl-based resin, and the second extrusion product is obtained by extruding a second composition including a polyamide resin and a foaming agent.

Foam compositions are provided. The compositions are prepared from multi-functional acetoacetate esters and multi-functional amines or acrylates. The foam compositions can include one or more additives. The foam compositions can be used for home and commercial insulation, air sealing, sound proofing, structural improvement, and exterior roofing, among other applications. The foam compositions provide advantages of being isocyanate free and offer reduced exposure to isocyanate.

Foam compositions are provided. The compositions are prepared from multi-functional acetoacetate esters and multi-functional amines or acrylates. The foam compositions can include one or more additives. The foam compositions can be used for home and commercial insulation, air sealing, sound proofing, structural improvement, and exterior roofing, among other applications. The foam compositions provide advantages of being isocyanate free and offer reduced exposure to isocyanate.

The invention pertains to a process for manufacturing a glycerol-tricarboxylic acid polyester foam which comprises the steps of combining glycerol and a tri-carboxylic acid to provide a liquid reaction mixture and contacting the reaction mixture with a substrate under polymerization conditions, wherein the substrate has a top layer comprising one or more of metal, metal oxide, and metal halide. The invention also pertains to a glycerol-tricarboxylic polyester foam, in particular a glycerol-citric acid polyester foam, which has a closed cell foam structure wherein at least 90 vol. % of the foam, preferably at least 95% of the foam, is built up from cells having a diameter below 2 mm. The foamed polyester of the present invention is green, biodegradable, and non-toxic, and can be cleanly combusted. It finds application in, int. al., packaging materials, insulation materials, and materials with a short life cycle.

The invention pertains to a process for manufacturing a glycerol-tricarboxylic acid polyester foam which comprises the steps of combining glycerol and a tri-carboxylic acid to provide a liquid reaction mixture and contacting the reaction mixture with a substrate under polymerization conditions, wherein the substrate has a top layer comprising one or more of metal, metal oxide, and metal halide. The invention also pertains to a glycerol-tricarboxylic polyester foam, in particular a glycerol-citric acid polyester foam, which has a closed cell foam structure wherein at least 90 vol. % of the foam, preferably at least 95% of the foam, is built up from cells having a diameter below 2 mm. The foamed polyester of the present invention is green, biodegradable, and non-toxic, and can be cleanly combusted. It finds application in, int. al., packaging materials, insulation materials, and materials with a short life cycle.

A polypropylene composition suitable for foaming having improved processability but maintained strain hardening and the process to produce the polypropylene composition comprising combining a linear polypropylene having a melt strength within a range from 10 to 40 cN (190 C.) with an organic peroxide to obtain a branched polypropylene having a melt strength within a range from 20 to 80 cN (190 C.), wherein the melt strength of the branched polypropylene is greater than the melt strength of the linear polypropylene; and combining the branched polypropylene having a melt flow rate within a range of 0.1 to 20 g/10 min and an Mw/Mn of at least 5 with within a range from 5 to 40 wt % of a low molecular weight polyolefin having a melt flow rate of at least 50 g/10 min and an Mw/Mn of less than 5 to obtain the polypropylene composition.

A polypropylene composition suitable for foaming having improved processability but maintained strain hardening and the process to produce the polypropylene composition comprising combining a linear polypropylene having a melt strength within a range from 10 to 40 cN (190 C.) with an organic peroxide to obtain a branched polypropylene having a melt strength within a range from 20 to 80 cN (190 C.), wherein the melt strength of the branched polypropylene is greater than the melt strength of the linear polypropylene; and combining the branched polypropylene having a melt flow rate within a range of 0.1 to 20 g/10 min and an Mw/Mn of at least 5 with within a range from 5 to 40 wt % of a low molecular weight polyolefin having a melt flow rate of at least 50 g/10 min and an Mw/Mn of less than 5 to obtain the polypropylene composition.

Antioxidant polymer foams and uses thereof are described herein. These foams are synthesized using a Carboni-Lindsey reaction of 1,2,4,5-tetrazine with a polymer having alkenyl functional groups. The foams feature dihydropyridazine functional groups which can be oxidized to consume surrounding reactive oxidizing chemicals and are consequently antioxidant.

Antioxidant polymer foams and uses thereof are described herein. These foams are synthesized using a Carboni-Lindsey reaction of 1,2,4,5-tetrazine with a polymer having alkenyl functional groups. The foams feature dihydropyridazine functional groups which can be oxidized to consume surrounding reactive oxidizing chemicals and are consequently antioxidant.

A formulation of polymeric mixtures for the production of cross-linked expanded PVC foams, of the type comprising PVC, isocyanates, anhydrides and one or more nucleating agents, wherein the nucleating agents are composed of nucleating materials having a porosity of 1-100 nm, preferably 2-50 nm. With respect to known formulations for the production of cross-linked PVC foams, a formulation according to the invention offers the advantage of obtaining the desired degrees of stabilization, nucleation and expansion, even without the use of diazocompounds.