The invention relates to foam materials that are resistant to high temperatures, to the production of same from aromatic polyisocyanates and polyepoxides, and to the use of said foam materials.

A novel Aromatic Thermosetting Copolyester (ATSP) fully dense sheets can be processed by recycling the foam structure with unique combination of properties including mechanical strength and high temperature performance (compared to PEEK) to help improve part functionality, gain long-term reliability and cost savings. ATSP machinable plates can be used in valves, fittings, bearing, bushing, seals, aerospace parts and pump components.

Disclosed herein are compositions comprising an epoxy-functionalized sacrificial polymer, wherein the sacrificial polymer decomposes into one or more gaseous decomposition products at a temperature of 180 C. or less for a period of time of 24 hrs or less. Also disclosed are compositions comprising a copolymer derived from an epoxy resin; an epoxy-functionalized sacrificial polymer; and optionally a crosslinker. The epoxy-functionalized sacrificial polymer can be derived from a polycarbonate. Methods of preparing the copolymers described herein are also disclosed. Porous films derived from the copolymers described herein, wherein a majority of the sacrificial polymer in the composition has been degraded to form pores in the porous film are also disclosed.

Disclosed herein are compositions comprising an epoxy-functionalized sacrificial polymer, wherein the sacrificial polymer decomposes into one or more gaseous decomposition products at a temperature of 180 C. or less for a period of time of 24 hrs or less. Also disclosed are compositions comprising a copolymer derived from an epoxy resin; an epoxy-functionalized sacrificial polymer; and optionally a crosslinker. The epoxy-functionalized sacrificial polymer can be derived from a polycarbonate. Methods of preparing the copolymers described herein are also disclosed. Porous films derived from the copolymers described herein, wherein a majority of the sacrificial polymer in the composition has been degraded to form pores in the porous film are also disclosed.

Embodiments are directed to a pourable foam comprising a first resin component comprising a polymeric methylene diphenyl diisocyanate, a second resin component comprising a polyol, and a barium sulfate powder component. The barium sulfate powder component is combined with the second resin component prior to combining the first and second resin components. The barium sulfate component may comprise between 1% and 50% of the pourable foam. The pourable foam may be used to repair or create aircraft components.

Embodiments are directed to a pourable foam comprising a first resin component comprising a polymeric methylene diphenyl diisocyanate, a second resin component comprising a polyol, and a barium sulfate powder component. The barium sulfate powder component is combined with the second resin component prior to combining the first and second resin components. The barium sulfate component may comprise between 1% and 50% of the pourable foam. The pourable foam may be used to repair or create aircraft components.

This invention relates to thermoset, thermal insulating panel, pour-in-place and pour-in-place foams having desirable and unexpectedly low thermal conductivity, and to compositions, method and systems which use and/or are used to make such foams comprising: (a) providing thermosetting foam forming component and a blowing agent for forming predominantly closed cells in the foam, wherein the blowing agent comprises: (i) cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzzm(Z)) and cyclopentane, with the HFO-1336mzzm(Z) and cyclopentane in the blowing agent together comprising at least about 50% by weight of the total of all components in the blowing agent and (ii) the weight ratio of HFO-1336mzzm(Z) to cyclopentane in the blowing agent is from about 45:55 to less than 68:32 and (b) forming foam from said provided foamable composition.

This invention relates to thermoset, thermal insulating panel, pour-in-place and pour-in-place foams having desirable and unexpectedly low thermal conductivity, and to compositions, method and systems which use and/or are used to make such foams comprising: (a) providing thermosetting foam forming component and a blowing agent for forming predominantly closed cells in the foam, wherein the blowing agent comprises: (i) cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzzm(Z)) and cyclopentane, with the HFO-1336mzzm(Z) and cyclopentane in the blowing agent together comprising at least about 50% by weight of the total of all components in the blowing agent and (ii) the weight ratio of HFO-1336mzzm(Z) to cyclopentane in the blowing agent is from about 45:55 to less than 68:32 and (b) forming foam from said provided foamable composition.

The present invention relates to a curable isocyanate-free formulation for preparing a polyurethane self-blowing foam comprising at least one multifunctional cyclic carbonate having at least two cyclic carbonate groups at the end of the chain (compound A), at least one multifunctional amine (compound B), water or/and a water source and optionally at least one catalyst (compound D), to a process for preparing said foams and to the thus obtained foams, to a process for recycling the obtained foams and to the thus recycled foams.

The present invention relates to a curable isocyanate-free formulation for preparing a polyurethane self-blowing foam comprising at least one multifunctional cyclic carbonate having at least two cyclic carbonate groups at the end of the chain (compound A), at least one multifunctional amine (compound B), water or/and a water source and optionally at least one catalyst (compound D), to a process for preparing said foams and to the thus obtained foams, to a process for recycling the obtained foams and to the thus recycled foams.