C08J9/16

Poly(3-hydroxyalkanoate) foam particles and poly(3-hydroxyalkanoate) foam molded article
11459436 · 2022-10-04 · ·

Provided are poly(3-hydroxyalkanoate) foam particles, which can give a foam molded article having good surface aspects and a low shrinkage ratio of a molding, and the foam molded article. The poly(3-hydroxyalkanoate) foam particles have at least two melting peaks on a DSC curve obtained by differential scanning calorimetry and in which a melting calorie (X) on a high temperature side is 0.1 to 20 J/g, a gel fraction (Y) is 20 to 75% by weight, and the melting calorie (X) and the gel fraction (Y) satisfy Formula: X+Y≥30.

POLYMER COMPOSITION AND EXPANDED POLYPROPYLENE BEADS MADE FROM THE POLYMER COMPOSITION

The present invention relates to a polymer composition comprising (85-100 wt %) of a propylene copolymer based on the total amount of the polymer composition, wherein the comonomer in the propylene copolymer is selected from moiety derived from ethylene, an α-olefin having (4) to (20) carbon atoms or a combination thereof, wherein the amount of the comonomer is in the range of (0.50 to 4.5) wt % based on the propylene copolymer, wherein the fraction of melted propylene copolymer in the temperature range from (116 to 151° C.) is in the range from (65 to 90) wt % based on the total weight of the propylene copolymer. The present invention also relates to expanded polypropylene (EPP) beads comprising said polymer composition. The invention further relates to the use of such EPP beads. The invention further relates to a process for preparing such EPP beads. The present invention also relates to an article made from said EPP beads. The invention further relates to the use of such article. The invention further relates to a process for preparing such article.

POLYMER COMPOSITION AND EXPANDED POLYPROPYLENE BEADS MADE FROM THE POLYMER COMPOSITION

The present invention relates to a polymer composition comprising (85-100 wt %) of a propylene copolymer based on the total amount of the polymer composition, wherein the comonomer in the propylene copolymer is selected from moiety derived from ethylene, an α-olefin having (4) to (20) carbon atoms or a combination thereof, wherein the amount of the comonomer is in the range of (0.50 to 4.5) wt % based on the propylene copolymer, wherein the fraction of melted propylene copolymer in the temperature range from (116 to 151° C.) is in the range from (65 to 90) wt % based on the total weight of the propylene copolymer. The present invention also relates to expanded polypropylene (EPP) beads comprising said polymer composition. The invention further relates to the use of such EPP beads. The invention further relates to a process for preparing such EPP beads. The present invention also relates to an article made from said EPP beads. The invention further relates to the use of such article. The invention further relates to a process for preparing such article.

Voided latex particles

A process for forming voided latex particles is improved by combining swelling and polymerization of an outer shell into a single step. The process includes contacting multi-stage emulsion polymer particles comprising a core, at least one intermediate shell, with a swelling agent, and polymerizing an outer shell after said contacting with swelling agent wherein the core and the at least one intermediate shell are contacted with swelling agent in the presence of less than 0.5% monomer based on the weight of the multi-stage emulsion polymer particles, and substantially all of the swelling occurs during polymerization of the outer shell.

Voided latex particles

A process for forming voided latex particles is improved by combining swelling and polymerization of an outer shell into a single step. The process includes contacting multi-stage emulsion polymer particles comprising a core, at least one intermediate shell, with a swelling agent, and polymerizing an outer shell after said contacting with swelling agent wherein the core and the at least one intermediate shell are contacted with swelling agent in the presence of less than 0.5% monomer based on the weight of the multi-stage emulsion polymer particles, and substantially all of the swelling occurs during polymerization of the outer shell.

PROCESS FOR PRODUCING POROUS PARTICLES OF A POLYHYDROXYALKANOATE (PHA), POROUS PARTICLES OBTAINABLE FROM SAID PROCESS AND COSMETIC COMPOSITIONS COMPRISING THE SAME

A process for producing porous particles of a polyhydroxyalkanoate (PHA) includes the following steps: providing a spray drying atomization chamber heated to an operating temperature comprised between 50° C. and 300° C.; providing an aqueous suspension having the PHA and an expanding agent which decomposes at the operating temperature of the atomization chamber, with the formation of at least one gaseous compound; and injecting the aqueous suspension into the atomization chamber provided at the operating temperature, so as to cause instantaneous evaporation of the aqueous suspension and decomposition of the expanding agent, with formation of the porous PHA particles. The particles obtained from said process can be used to obtain cosmetic compositions that are soft to the touch, with high oil absorbing capacities and high flow index, able to generate a uniform, filling effect for wrinkles and skin furrows, making the skin more glossy and compact.

PROCESS FOR PRODUCING POROUS PARTICLES OF A POLYHYDROXYALKANOATE (PHA), POROUS PARTICLES OBTAINABLE FROM SAID PROCESS AND COSMETIC COMPOSITIONS COMPRISING THE SAME

A process for producing porous particles of a polyhydroxyalkanoate (PHA) includes the following steps: providing a spray drying atomization chamber heated to an operating temperature comprised between 50° C. and 300° C.; providing an aqueous suspension having the PHA and an expanding agent which decomposes at the operating temperature of the atomization chamber, with the formation of at least one gaseous compound; and injecting the aqueous suspension into the atomization chamber provided at the operating temperature, so as to cause instantaneous evaporation of the aqueous suspension and decomposition of the expanding agent, with formation of the porous PHA particles. The particles obtained from said process can be used to obtain cosmetic compositions that are soft to the touch, with high oil absorbing capacities and high flow index, able to generate a uniform, filling effect for wrinkles and skin furrows, making the skin more glossy and compact.

Block copolymer foam

The invention relates to a noncrosslinked block copolymer foam, comprising at least one rigid block and at least one flexible block, in which the copolymer includes at least one carboxylic acid chain end blocked with a polycarbodiimide. The invention also relates to a process for manufacturing this foam and to articles manufactured therefrom.

Process for producing foam beads using a modified ethylene-based polymer

The present disclosure provides a process. The process includes (i) forming a composition containing a peroxide-modified ethylene-based polymer selected from the group consisting of a peroxide-modified ethylene/a-olefin multi-block copolymer, a peroxide-modified low density polyethylene, and combinations thereof; (ii) contacting the composition with a blowing agent to form a foam composition; and (iii) forming foam beads comprising the foam composition. The present disclosure also provides a foam bead produced by said process.

MOLD DEVICE FOR RESIN MOLDED ARTICLE, MOLDING APPARATUS, MOLDING SYSTEM, AND METHOD FOR MANUFACTURING MOLDED ARTICLE
20220219358 · 2022-07-14 ·

The present invention is a manufacturing method for obtaining a molded article having foam layer inside for providing a foaming agent, a device, a mold, a molding machine, a means for increasing the foaming ratio and a means for increasing coating appropriateness used for manufacturing resin having foaming properties. When the resin having compatibility (miscibility) with the resin to be blended is used as a carrier resin used for manufacturing a masterbatch of the foaming agent, the molded article having an excellent outer appearance can be obtained. When the sodium bicarbonate which is an inorganic foaming agent is used for the foaming agent, a sodium carbonate, which is a foam residue remaining in the molded article after the foaming agent is decomposed to generate the foaming gas, reduces the adherability of the coating film. Thus, when the acid cleaning is preliminarily performed to remove the sodium carbonate, the coating appropriateness is satisfied. When performing the GCP, the thickness of the skin layer located at the surface varies depending on the surface temperature of the mold. In general, the means using the heated steam is generally used for increasing the temperature of the mold. In the present invention, the means for heating the magnetic fluid (liquid) by high frequency induction heating is used. Thus, the temperature of the mold can be safely increased at low cost with heating efficiency. When a mold-back or a core-back is performed for obtaining the molded article having high foaming ratio, the resin is separated from the fixed side. The present invention provides the means for solving the above described problem of the separation by using the gas.