Patent classifications
C08J9/16
FOAMABLE POLYPROPYLENE COMPOSITION, AND FOAMED POLYPROPYLENE AND PREPARATION METHOD THEREFOR
A foamable polypropylene composition, and foamed polypropylene and a preparation method therefor are provided. The polypropylene composition comprises polypropylene, a polypropylene modifier, a foaming agent, and an optional nucleating agent. A preparation method for the polypropylene modifier comprises: enabling polar monomer grafted polypropylene to be in contact with a component A to react and carrying out extruding pelletizing, wherein a polar monomer in the polar monomer grafted polypropylene can chemically react with the component A; the polar monomer is selected from at least one of dimethylamino methacrylate, epoxy acrylate, trimeric acrylic isocyanurate, and acrylamide; and the component A is selected from at least one of polyisocyanate, polyethylene oxide, and an amido-containing substance. The foamed polypropylene has an obtained foaming ratio of 12 times or more, and also has high tensile and flexural properties.
Comfort eTPU
Molded articles contain a foam composed of a thermoplastic elastotner (TPE-1). The foam has a storage modulus (G modulus) at 25° C. and 1 Hz within the range from 0.01 to 0.5 MPa, a molding density within the range from 20 to 400 kg/m.sup.3, and a comfort factor of greater than 4. A process produces molded articles of this kind, and the molded article can be used for producing floors, mattresses, seating furniture, bicycle saddles, car seats, motorcycle seats, components of a shoe, shoe inserts, packaging, shock absorbers, protectors, fall protection mats, elastic insulating material, or sealing material.
Comfort eTPU
Molded articles contain a foam composed of a thermoplastic elastotner (TPE-1). The foam has a storage modulus (G modulus) at 25° C. and 1 Hz within the range from 0.01 to 0.5 MPa, a molding density within the range from 20 to 400 kg/m.sup.3, and a comfort factor of greater than 4. A process produces molded articles of this kind, and the molded article can be used for producing floors, mattresses, seating furniture, bicycle saddles, car seats, motorcycle seats, components of a shoe, shoe inserts, packaging, shock absorbers, protectors, fall protection mats, elastic insulating material, or sealing material.
Super absorbent polymer
The present invention relates to a super absorbent polymer. The super absorbent polymer exhibits excellent initial absorption capacity, and thus can provide a sanitary material such as a diaper or a sanitary napkin which can quickly absorb body fluids and impart a dry and soft touch feeling.
THERMALLY EXPANDABLE CELLULOSE-BASED MICROSPHERES
The disclosure relates to thermally expandable microspheres comprising a polymeric shell surrounding a blowing agent-containing hollow core, the polymer shell comprising a carboxylate-functionalised cellulose having a glass transition temperature (Tg) of at least about 125° C. The disclosure also relates to a method for preparing such thermally expandable microspheres, comprising mixing an aqueous phase that optionally comprises an emulsifier with an organic phase that comprises an organic solvent, a blowing agent and a carboxylate-functionalised cellulose having a Tg of at about least 125° C., to form a microsphere dispersion.
THERMALLY EXPANDABLE CELLULOSE-BASED MICROSPHERES
The disclosure relates to thermally expandable microspheres comprising a polymeric shell surrounding a blowing agent-containing hollow core, the polymer shell comprising a carboxylate-functionalised cellulose having a glass transition temperature (Tg) of at least about 125° C. The disclosure also relates to a method for preparing such thermally expandable microspheres, comprising mixing an aqueous phase that optionally comprises an emulsifier with an organic phase that comprises an organic solvent, a blowing agent and a carboxylate-functionalised cellulose having a Tg of at about least 125° C., to form a microsphere dispersion.
POLYAMIDE-BASED RESIN EXPANDED BEADS, MOLDED ARTICLE OF POLYAMIDE-BASED RESIN EXPANDED BEADS, AND METHOD FOR PRODUCING POLYAMIDE-BASED RESIN EXPANDED BEADS
Polyamide-based resin expanded beads contain a polyamide-based resin as a base material resin. The beads have a crystal structure, an intrinsic peak of the polyamide-based resin and a high-temperature peak having a peak top temperature on a higher temperature side than a peak top temperature of the intrinsic peak appear in a DSC curve obtained under a predetermined condition; an amount of heat of fusion of the high-temperature peak is within 5 J/g or more and 50 J/g or less; and a coefficient of variation of the amount of heat of fusion of the high-temperature peak is 20% or less. The beads are produced by in-mold molding. A method for producing the beads includes: impregnating a polyamide-based resin; and releasing expandable polyamide-based resin beads from a sealed container, a temperature in the sealed container is raised at a rate of 0.3° C. or higher and 1.5° C. or lower per 10 minutes.
POLYAMIDE-BASED RESIN EXPANDED BEADS, MOLDED ARTICLE OF POLYAMIDE-BASED RESIN EXPANDED BEADS, AND METHOD FOR PRODUCING POLYAMIDE-BASED RESIN EXPANDED BEADS
Polyamide-based resin expanded beads contain a polyamide-based resin as a base material resin. The beads have a crystal structure, an intrinsic peak of the polyamide-based resin and a high-temperature peak having a peak top temperature on a higher temperature side than a peak top temperature of the intrinsic peak appear in a DSC curve obtained under a predetermined condition; an amount of heat of fusion of the high-temperature peak is within 5 J/g or more and 50 J/g or less; and a coefficient of variation of the amount of heat of fusion of the high-temperature peak is 20% or less. The beads are produced by in-mold molding. A method for producing the beads includes: impregnating a polyamide-based resin; and releasing expandable polyamide-based resin beads from a sealed container, a temperature in the sealed container is raised at a rate of 0.3° C. or higher and 1.5° C. or lower per 10 minutes.
Expandable, expanding-agent-containing granules based on high-temperature thermoplastics
Expandable, blowing agent-containing pellets based on high temperature thermoplastics having a glass transition temperature according to ISO 11357-2-1999 of at least 180° C., wherein the expandable, blowing agent-containing pellets comprise at least one nucleating agent and have a poured density according to DIN ISO 697:1982 in the range from 400 to 900 kg/m.sup.3 and a mass in the range from 1 to 5 mg/pellet, processes for production thereof and foam particles obtainable therefrom having a glass transition temperature according to ISO 11357-2-1999 of at least 180° C., wherein the expanded foam particles comprise at least one nucleating agent and have a poured density according to DIN ISO 697:1982 in the range from 10 to 200 kg/m.sup.3, and particle foams obtainable therefrom and the use thereof for producing components for aviation.
Expandable, expanding-agent-containing granules based on high-temperature thermoplastics
Expandable, blowing agent-containing pellets based on high temperature thermoplastics having a glass transition temperature according to ISO 11357-2-1999 of at least 180° C., wherein the expandable, blowing agent-containing pellets comprise at least one nucleating agent and have a poured density according to DIN ISO 697:1982 in the range from 400 to 900 kg/m.sup.3 and a mass in the range from 1 to 5 mg/pellet, processes for production thereof and foam particles obtainable therefrom having a glass transition temperature according to ISO 11357-2-1999 of at least 180° C., wherein the expanded foam particles comprise at least one nucleating agent and have a poured density according to DIN ISO 697:1982 in the range from 10 to 200 kg/m.sup.3, and particle foams obtainable therefrom and the use thereof for producing components for aviation.