Modified thermoplastic hydrocarbon thermoplastic resins are provided, as well as methods of their manufacture and uses thereof in rubber compositions. The modified thermoplastic resins are modified by decreasing the relative quantity of the dimer, trimer, tetramer, and pentamer oligomers as compared to the corresponding unmodified thermoplastic resin polymers, resulting in a product that exhibits a greater shift in the glass transition temperature of the elastomer(s) used in tire formulations. This translates to better viscoelastic predictors of tire tread performance, such as wet grip and rolling resistance. The modified thermoplastic resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the modified thermoplastic resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, snow performance, and wet braking performance.

Modified thermoplastic hydrocarbon thermoplastic resins are provided, as well as methods of their manufacture and uses thereof in rubber compositions. The modified thermoplastic resins are modified by decreasing the relative quantity of the dimer, trimer, tetramer, and pentamer oligomers as compared to the corresponding unmodified thermoplastic resin polymers, resulting in a product that exhibits a greater shift in the glass transition temperature of the elastomer(s) used in tire formulations. This translates to better viscoelastic predictors of tire tread performance, such as wet grip and rolling resistance. The modified thermoplastic resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the modified thermoplastic resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, snow performance, and wet braking performance.

A method for the controlled removal of water from devulcanized rubber, comprising steps of contacting the devulcanized rubber with a solvent, dissolving the water out of the devulcanized rubber and into solution without removing other components in the rubber such as polymer, separating the devulcanized rubber from the solvent, and drying the devulcanized rubber. By controlling the amount of water that is in the solvent-solution, and/or the amount of time the devulcanized rubber is in contact with the solvent solution the amount of water that is removed can be controlled. By controlling the amount of water that is removed the rheology/viscosity (e.g. G and G) of the devulcanized rubber can be controlled.

A method for the controlled removal of water from devulcanized rubber, comprising steps of contacting the devulcanized rubber with a solvent, dissolving the water out of the devulcanized rubber and into solution without removing other components in the rubber such as polymer, separating the devulcanized rubber from the solvent, and drying the devulcanized rubber. By controlling the amount of water that is in the solvent-solution, and/or the amount of time the devulcanized rubber is in contact with the solvent solution the amount of water that is removed can be controlled. By controlling the amount of water that is removed the rheology/viscosity (e.g. G and G) of the devulcanized rubber can be controlled.

A system and method for a first reactor to produce a transfer slurry having a first polyolefin polymerized in the first reactor, a heat-removal zone to remove heat from the transfer slurry, and a second reactor to receive the transfer slurry cooled by the heat-removal zone, the second reactor to produce a product slurry having a product polyolefin which includes the first polyolefin and a second polyolefin polymerized in the second reactor.

A system and method for a first reactor to produce a transfer slurry having a first polyolefin polymerized in the first reactor, a heat-removal zone to remove heat from the transfer slurry, and a second reactor to receive the transfer slurry cooled by the heat-removal zone, the second reactor to produce a product slurry having a product polyolefin which includes the first polyolefin and a second polyolefin polymerized in the second reactor.

The invention relates to a process for the polymerization of olefins comprising the comprising the steps of a. Polymerizing olefins in a reaction mixture comprising monomers, diluent, processing aids to prepare a product stream comprising polyolefins, monomers and diluent; b. Removing the polyolefins from the product stream to obtain a purge stream; c. Removing gaseous components from the purge stream to obtain a liquid fraction; d. Treating the liquid fraction with at least one ionic liquid to obtain a fraction containing unsaturated hydrocarbons; e. Recycling the fraction containing unsaturated hydrocarbons to the reaction mixture, optionally after purification of said fraction containing unsaturated hydrocarbons. The invention also relates to an olefin polymerization system comprising a polymerization reactor, a purge vessel, a vent gas recovery and an ionic liquid separator for separating liquid alkenes from liquid alkanes, wherein the liquid alkenes which are separated from the alkanes in the ionic liquid separator can be recycled to the polymerization reactor.

The invention relates to a process for the polymerization of olefins comprising the comprising the steps of a. Polymerizing olefins in a reaction mixture comprising monomers, diluent, processing aids to prepare a product stream comprising polyolefins, monomers and diluent; b. Removing the polyolefins from the product stream to obtain a purge stream; c. Removing gaseous components from the purge stream to obtain a liquid fraction; d. Treating the liquid fraction with at least one ionic liquid to obtain a fraction containing unsaturated hydrocarbons; e. Recycling the fraction containing unsaturated hydrocarbons to the reaction mixture, optionally after purification of said fraction containing unsaturated hydrocarbons. The invention also relates to an olefin polymerization system comprising a polymerization reactor, a purge vessel, a vent gas recovery and an ionic liquid separator for separating liquid alkenes from liquid alkanes, wherein the liquid alkenes which are separated from the alkanes in the ionic liquid separator can be recycled to the polymerization reactor.

The invention relates to a method by which means inorganic fibres (glass, carbon, aramide, etc.) are recovered from composite materials of fibre and resin, with the significant advantage of working at room temperature. The method comprises the steps of treatment with solvent and separation of the fibre from the residues of degraded resin.

The invention relates to a method by which means inorganic fibres (glass, carbon, aramide, etc.) are recovered from composite materials of fibre and resin, with the significant advantage of working at room temperature. The method comprises the steps of treatment with solvent and separation of the fibre from the residues of degraded resin.