Patent classifications
C08J2203/10
Boron nitride polymer composite foam derived from emulsions stabilized by boron nitride kinetic trapping
The present disclosure provides advantageous graphene/graphite stabilized composites (e.g., graphene/graphite stabilized emulsion-templated foam composites), and improved methods for fabricating such graphene/graphite stabilized composites. More particularly, the present disclosure provides improved methods for fabricating pristine, graphene/graphite/polymer composite foams derived from emulsions stabilized by graphene/graphite kinetic trapping. In exemplary embodiments, the present disclosure provides that, instead of viewing the insolubility of pristine graphene/graphite as an obstacle to be overcome, it is utilized as a means to create or fabricate water/oil emulsions, with graphene/graphite stabilizing the spheres formed. These emulsions are then the frameworks used to make foam composites that have shown bulk conductivities up to about 2 S/m, as well as compressive moduli up to about 100 MPa and breaking strengths of over 1200 psi, with densities as low as about 0.25 g/cm.sup.3.
URETHANE RESIN COMPOSITION AND BUILDING INSULATION METHOD
A urethane resin composition having properties suitable for forming a building insulation layer without adding a foam stabilizer in a urethane resin composition having at least quasi-incombustibility. A urethane resin composition for forming a foam that constitutes a insulation material for a building includes a foam having at least quasi-incombustibility in a heat-release test complying with ISO-5660, the urethane resin composition containing at least a polyisocyanate compound, an ester polyol compound, a trimerization catalyst, an additive, and a non-silicon surface adjuster, and by not containing a foam stabilizer, the additive including red phosphorus as an essential component and being combined with a phosphate-containing flame retardant and/or a chlorine-containing flame retardant.
FLAME RETARDANT MASTERBATCH COMPOSITION FOR FOAMS CONTAINING A PH MODERATOR
A masterbatch composition suitable for use as a flame retardant in extruded polymer foams, and process for manufacturing the same, and extruded foams containing same; the composition comprising: (a) 20 to 40 parts by weight base resin comprising styrene homopolymer or copolymer; (b) 1 to 16 parts by weight acid scavenger comprising an epoxy-based compound; (c) 2 to 6 parts by weight antioxidant comprising an alkyl or aryl phosphite; and (d) 45 to 60 parts by weight flame retardant comprising a non-hexabromocyclododecane (HBCD) brominated polymer or copolymer, wherein the amounts of (a), (b), (c), and (d) total 100 parts by weight; and (e) 0.6 to 10 parts by weight of pH moderator, based on 100 parts of (a) base resin plus (e) water soluble pH moderator.
POROUS MATERIALS FOR ENERGY MANAGEMENT
Method for preparing porous polyurethane materials with controlled pore size and shape using isocyanates, polyols, and additives, and the porous polyurethane materials prepared therefrom. Method for preparing porous polyimides using at least one polyamine and a dianhydride and the porous polyimides materials prepared therefrom. The porous materials are useful for energy management, such as thermal, impact and vibration energy, and can exhibit improved fire-resistant performance.
AZEOTROPE OR AZEOTROPE-LIKE COMPOSITIONS OF Z-1-CHLORO-2,3,3,3-TETRAFLUOROPROPENE (HCFO-1224yd(Z))
Heterogeneous azeotrope or azeotrope-like compositions comprising Z-1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224yd(Z)) and water which may include from about 47.0 wt. % to about 99.7 wt. % Z-1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224yd(Z)) and from about 0.3 wt. % to about 53.0 wt. % water and having a boiling point between about 13.0° C. and about 14.0° C. at a pressure of between about 14.0 psia and about 15.0 psia. The azeotrope or azeotrope-like compositions may be used to as blowing agents in the formation of foams.
Polyurethane foams based on polyethercarbonate polyols
The present invention relates to a method for producing polyurethane foams by reacting an isocyanate component with an isocyanate-reactive component comprising at least one polyethercarbonate polyol, the reaction taking place in the presence of a component K selected from one or more compounds from the group consisting of K1 esters of mono- or polybasic carboxylic acids whose (first) dissociation has a pKa of 0.5 to 4.0, K2 mono-, di- and polysulfonates of mono- and polyfunctional alcohols, and K3 one or more compounds from the group consisting of K 3.1 esters of phosphoric acid, phosphonic acid, phosphorous acid, phosphinic acid, phosphonous acid and phosphinous acid, these esters each containing no P—OH group, K3.2 oligomeric alkyl phosphates of the general formula (II), where a is an integer from 1 to 10, b is an integer from 1 to 10, R1, R2, R3 and R4 are alkyl groups having at least one carbon, and R1, R2, R3 and R4 are alike or, independently of one another, different, and R5 is a linear alkylene group having at least two carbons or is a branched alkylene group having at least three carbons, and K3.3 comprises oligomeric alkyl phosphates of the general formula (III), where a is an integer from 1 to 10, b is an integer from 1 to 10, R1, R4 and R5 are linear alkylene groups having at least two carbons or are branched alkylene groups having at least three carbons, and R1, R4 and R5 are alike or, independently of one another, different, and R2 and R3 are alkyl groups having at least one carbon, and R2 and R3 are alike or, independently of one another, different. The invention also relates to polyurethane foams produced by the method of the invention and to the use thereof.
Viscoelastic Elastomeric Polyurethane Foams, Process for Preparing Them and Use Thereof
Disclosed herein are viscoelastic elastomeric polyurethane foams, a process for preparing them and a method of using them in making shaped articles. Further disclosed herein are of viscoelastic elastomeric polyurethane foams having improved, unique impact absorption performance.
Green fabrication of polytetrafluoroethylene and expanded polytetrafluoroethylene and uses thereof
Green, fast and easy evaporating organic solvent for use as a lubricant in the processing of polytetrafluoroethylene (PTFE) and expanded polytetrafluoroethylene (ePTFE) products and processes of using the solvents to fabricate the products are disclosed herein. The products can be used in the field of bio- and medical applications, such as for use in vascular grafts, cardiovascular and soft tissue patches, facial implants, surgical sutures, and endovascular prosthesis, and for any products known in the aerospace, electronics, fabrics, filtration, industrial and sealant arts.
METHOD FOR PRODUCING A MIXTURE COMPRISING AT LEAST ONE COMPOUND HAVING AT LEAST TWO HYDROXY AND/OR AMINO GROUPS AND USE THEREOF FOR PRODUCING A POLYMER
The present invention relates to a method for producing a mixture comprising at least one compound having at least two hydroxy and/or amino groups made of a biomass material. The invention also relates to such a mixture and to the use thereof for producing a polymer such as for example a polyurethane foam.
POLYURETHANE FOAMS WITH IMPROVED ACOUSTIC PROPERTIES
The invention relates in a first aspect to a process for producing a polyurethane foam, comprising the reaction of (a) an isocyanate composition comprising at least one polyisocyanate based on diphenylmethane diisocyanate; (b) a polyol mixture, wherein the polyol mixture comprises (b1) 50% to 85% by weight of at least one polyether polyol having a hydroxyl value in the range from 10 to 60 mg KOH/g, an OH functionality of more than 2, and an ethylene oxide proportion in the range from 50% to 100% by weight based on the alkylene oxide content of the at least one polyether polyol, and (b2) 15% to 50% by weight of at least one polyether polyol having a hydroxyl value in the range from 10 to 100 mg KOH/g, an OH functionality of more than 2, an ethylene oxide proportion in the range from 2% to 30% by weight based on the alkylene oxide content of the at least one polyether polyol, and a proportion of primary OH groups of 40 to 100% based on the total number of OH groups in the at least one polyether polyol, in each case based on the total amount by weight of constituents (b1) and (b2), which adds up to 100% by weight, and (b3) 0 to 20 further parts by weight of an optionally derivatized filler, based on 100 parts by weight of components (b1) and (b2), optionally present as a constituent of a graft polyol based on one or more of components (b1) and (b2); (c) a blowing agent composition comprising water; wherein the reaction employs the blowing agent composition (c) in a weight-based ratio of the weight of blowing agent composition (c) to the total weight of all isocyanate-reactive compounds used in the reaction in the range from 1:14 to 1:6; wherein a polyurethane foam having a foam density, determined according to DIN EN ISO 845 (October 2009), of not more than 25 kg/m.sup.3 and a compression hardness, determined at 40% compression in the first compression in accordance with DIN EN ISO 3386-1 (October 2015), in the range from 10 to 80 kPa is obtained.
In a second aspect, the invention relates to a polyurethane foam obtained or obtainable by the process of the first aspect.
A third aspect of the invention relates to the use of a polyurethane foam according to the second aspect as a sound absorption material.
According to a fourth aspect, the invention relates to a sound absorption material comprising a polyurethane foam according to the second aspect, preferably consisting of a polyurethane foam according to the second aspect.
A fifth aspect of the invention relates to the use of a polyol mixture (b) comprising (b1), (b2), and (b3) as defined in the first aspect, for producing a polyurethane foam.