Low-density thermoplastic expandable microspheres are disclosed. Various low-density structures, in particular, sandwich panels, based on foam prepared from the low-density microspheres, are also disclosed. Process of preparing low-density polymeric microspheres, per se, and the corresponding low-density structures, based on the microsphere foam, are also disclosed.

A process for producing a polyurethane or polyisocyanurate construction board, the process comprising (i) providing an A-side reactant stream that includes an isocyanate-containing compound; (ii) providing a B-side reactant stream that includes a polyol and a physical blowing agent, where the physical blowing agent includes pentane, butane, and optionally a blowing agent additive that has a Hansen Solubility Parameter (δ.sub.t) that is greater than 17 MPa.sup.−0.5; and (iii) mixing the A-side reactant stream with the B-side reactant stream to produce a reaction mixture.

The joint use of polyol ethers and ethylene oxide-rich alkyl alkoxylates as additives in filler-containing aqueous polymer dispersions for production of porous polymer coatings, preferably for production of porous polyurethane coatings, is described.

Polyol premixes and thermally insulating rigid polyurethane foams, such as those that can be used as a thermal insulation medium in the construction of refrigerated storage devices, are disclosed. A polymer polyol having a OH number of greater than 260 mg KOH/g is utilized. The resulting polyurethane foams can exhibit improved thermal insulation properties without sacrificing other important physical and processing properties.

Isocyanate-reactive compositions, rigid polyurethane foam-forming compositions, rigid polyurethane foams, and methods for their production, and composite articles having a rigid polyurethane foam sandwiched between metal facer substrates. The rigid polyurethane foams are produced from an isocyanate-reactive composition comprising: (1) a polyol blend that includes an amine-initiated polyether polyol; (2) a hydrochlorofluoroolefin (“HCFO”); and (3) a catalyst that includes an arylalkyl tertiary amine, an aryl tertiary amine, or a mixture thereof. The foam can have excellent adhesion to metal substrates.

A wall panel includes a first and second planar skins and a core disposed therebetween. A first and second lateral edge extends between the skins. The second lateral edge comprises a female receiver. The first lateral edge comprises a male extension extending therefrom. The female receiver is formed in the core and has a depth equal to or greater than a length of the male extension. The male extension is formed from the core comprises a first parallel surface extending parallel to and offset from the first planar skin and a second parallel surface extending parallel to and offset from the second planar skin. A first tapered portion comprises a first tapered surface extending at an angle relative to a longitudinal axis from the first parallel surface to a rounded end, and a second tapered surface extending at the angle from the second parallel surface to the rounded end.

A wall panel includes a first and second planar skins and a core disposed therebetween. A first and second lateral edge extends between the skins. The second lateral edge comprises a female receiver. The first lateral edge comprises a male extension extending therefrom. The female receiver is formed in the core and has a depth equal to or greater than a length of the male extension. The male extension is formed from the core comprises a first parallel surface extending parallel to and offset from the first planar skin and a second parallel surface extending parallel to and offset from the second planar skin. A first tapered portion comprises a first tapered surface extending at an angle relative to a longitudinal axis from the first parallel surface to a rounded end, and a second tapered surface extending at the angle from the second parallel surface to the rounded end.

Disclosed are polyurethane-foam forming compositions, rigid polyurethane foams and methods for their production, as well as to composite articles comprising such foams sandwiched between facer substrates, including use of such composite elements for side-wall and/or roof insulating elements for refrigerated tractor trailers. The rigid polyurethane foams are produced from an isocyanate-reactive composition comprising: (1) a polyol blend; (2) a hydrochlorofluoroolefin; and (3) a tertiary amine catalyst composition.

The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to open-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a sterically hindered amine catalyst.

A rigid polymer foam having specific characteristics in terms of resin absorption, and a structural element made from such rigid polymer foam and adapted to be used as a core layer in a multilayer structural element.