Poly(tetramethyl-p-silphenylenesiloxane) (PTMPS) membranes and porous articles made therefrom that have a matrix tensile strength in at least one direction from about 1 MPa to about 50 MPa, a matrix modulus greater than about 100 MPa in at least one direction, a porosity greater than about 30%, and a microstructure of nodes interconnected by fibrils are provided. The PTMPS polymer forming the PTMPS membranes and porous articles has a crystallinity of at least about 70%, a polydispersity from 1 to 5, and a weight average molecular weight from about 350 kDa to about 5 MDa. The PTMPS membranes may be asymmetric, meaning that the observed pore structure on one side of the PTMPS membrane is different than the pore structure on the opposing side of the PTMPS membrane. Methods of forming porous PTMPS articles are provided. Dense PTMPS articles and methods of making the same are also provided.

An expandable structural adhesive film for bonding metal parts. The adhesive film comprises at least one first epoxy compound; at least one epoxy curing agent; at least one blowing agent; at least one film-forming agent; and at least one impact modifier. The structural adhesive film exhibits an elongation at break of at least 300% according to tensile test DIN EN ISO 527 and a free expansion rate according to EN 2667-3 of at least 45%.

In various embodiments a urethane/MOLECULAR REBAR formulation comprising a specific composition is disclosed. The composition comprises a urethane polymer or prepolymer/discrete carbon nanotube formulation. Utility of the urethane/MOLECULAR REBAR composition includes improved foams and adhesives.

A tetrafluoroethylene (TFE) copolymer film having a first endotherm between about 50 C. and about 300 C., a second endotherm between about 320 C. and about 350 C., and a third endotherm between about 350 C. and about 400 C. is provided. In exemplary embodiments, the third endotherm is approximately 380 C. In some embodiments, the second endotherm is between about 320 C. and about 330 C. or between about 330 C. and about 350 C. TFE copolymer films have a methane permeability less than about 20 g*micron/cm.sup.2/min. In addition, the dense articles have a void volume of less than about 20%. Methods for dense articles from core shell tetrafluoroethylene copolymers are also provided. The dense articles exhibit improved physical and mechanical properties such as adhesion and barrier properties.

Method for coagulating an aqueous polymer dispersion, where the aqueous polymer dispersion comprises at least one polymer in dispersion in aqueous phase, and also comprises thermally expandable, thermoplastic microspheres, the polymer dispersion is coagulated by energy input, and the coagulated composition is delivered via an outlet aperture, preferably in the form of a nozzle.

A true tetrafluoroethylene (TFE) copolymer of the fine powder type is provided, wherein the copolymer contains polymerized comonomer units of at least one comonomer other than TFE in concentrations of at least or exceeding 1.0 weight percent, and which can exceed 5.0 weight percent, wherein the copolymer is expandable, that is, the copolymer may be expanded to produce strong, useful, expanded TFE copolymeric articles having a microstructure of nodes interconnected by fibrils. Articles made from the expandable copolymer may include tapes, membranes, films, fibers, and are suitable in a variety of end applications, including medical devices.

A process for producing a molded article involves providing a thin-walled, gas-permeable shell; filling the shell with a foamed pelletized material composed of a polymer; and welding the foamed pelletized material to obtain the molded article. Molded articles are obtainable or obtained by such a process, and can be used as a footwear sole, part of a footwear sole, a mattress, a seat cushion, an underlay, a grip, a protective film, a component in automobile interiors and exteriors, a gymnastics mat, a body protector, a trim element in automobile construction, a sound insulator, a vibration damper, a cushion, a bicycle saddle, a toy, a tire or part of a tire, a covering for a track and field surface, a covering for a sports hall or a pathway, a damping layer or a damping core in a sandwich element, or a packaging.

An article is described comprising a foam substrate comprising: a thermoplastic composition comprising polyurethane, a copolymer of ethylene and a polar comonomer, or a combination thereof; and expanded microspheres; and wherein the article is a medical tape, bandage or wrap. Also describes are methods of use, methods of making a foam article, foam substrates comprising a pressure sensitive adhesive layer disposed on a outermost major surface of the foam substrate, and foam compositions.

An object to be achieved by the present invention is to provide an industrially useful adhesive sheet that can be used to bond various adherends and has excellent peel adhesion, excellent push strength, and excellent holding power under static load. The object of the present invention can be achieved by an adhesive sheet having, on one side or both side of a substrate, an adhesive layer (A) having a tensile strength of 6 N/cm.sup.2 or more as determined from a stress-strain curve (a so-called S-S curve) at a strain of 100%.

A closed-cell foam water-stop sheet with an adhesion layer, wherein the closed-cell foam water-stop sheet comprises: the adhesion layer that comprises a rubber component (A) having a total content of 80% by mass or more of a butyl rubber (a1) and an ethylene-propylene-diene rubber (a2), and a petroleum resin-based tackifier (B), the adhesion layer having a thickness of 0.01 to 2.0 mm; and a closed-cell foam sheet having a closed cell ratio of 70% or more, the closed-cell foam sheet being integrally attached to the adhesion layer, and wherein a mass ratio of the ethylene-propylene-diene rubber (a2) to the butyl rubber (a1) [(a2)/(a1)] is 0/100 to 93/7, a content of the petroleum resin-based tackifier (B) is 0.5 to 20 parts by mass based on 100 parts by mass of the rubber component (A), and the closed-cell foam water-stop sheet with an adhesion layer has a 25% compression stress of 10 to 800 kPa.