Storage-stable two-component polyurethane or polyisocyanurate spray foam compositions are disclosed, said compositions comprising: (a) an A-side component comprising one or more polyisocyanate and one or more blowing agent; and (b) a B-side component comprising one or more polyol and one or more blowing agent comprising pressurized gaseous carbon dioxide and one or more liquid blowing agent; wherein both the A-side component and the B-side component, separately, generate less than 300 ppm of fluoride ion after one week of aging at 50? C.

Various uses of fluoroalkenes, including fluorobutenesin a variety of applications, including as blowing agents are disclosed.

The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst.

An in-situ foaming system for forming a flame-retardant polyurethane foam in situ comprising a first liquid containing a polyisocyanate (A), a second liquid containing a polyol (B), a trimerization catalyst (C), a foaming agent (D), a foam stabilizer (E), and additives (F) comprising red phosphorus and at least one member selected from the group consisting of phosphoric acid esters, phosphate-containing flame retardants, bromine-containing flame retardants, boron-containing flame retardants, antimony-containing flame retardants, and metal hydroxides.

Disclosed are bowing agent compositions, foamable compositions, foams, foaming methods and/or foamed articles comprising one or more C2 to C6 fluoroalkenes, more preferably one or more C3 to C5 fluoroalkenes, and even more preferably one or more compounds having Formula I as follows:

XCF.sub.zR.sub.3-z (I)

Where X is a C.sub.1, C.sub.2, C.sub.3, C.sub.4, or C.sub.5 unsaturated, substituted or unsubstituted radical, each R is independently Cl, F, Br, I or H, and z is 1 to 3, it generally being preferred that the fluoroalkene of the present invention was at least four (4) halogen substituents, at least three of which are F and even more preferably none of which are Br.

Disclosed herein are compositions comprising hydrofluoroolefin blowing agents and a polyol blend useful in forming foams. Also disclosed are methods for forming a foam comprising the aforementioned compositions.

In one embodiment, ground mineral wool is added to conventional polyurethane composition A or B to improve fire or flame resistant properties. In a second embodiment, a larger percentage of ground mineral wool is used in combination with a higher water concentration in order to substantially reduce the hydrocarbon content of the resulting foam. In a third embodiment, a foam composition is substantially re-formulated to reduce polyol concentration. Preliminary testing has suggested that it is possible to create an effective foam-like insulation without requiring the foam components to have a high polyol concentration.

The invention described herein generally pertains to a composition and a method for improving the shelf life of a gaseous hydrofluoroolefin propellant, the improvement comprising at least the increased aromatic polyester polyol(s) in combination with a tertiary amine catalyst comprising at least two cyclohexyl rings and an aliphatic metal salt catalyst, the amine catalyst having less than 10% nitrogen on a weight basis.

The disclosure provides methods for preparing a plural component material where part A and part B supplies are delivered from unpressurized storage containers. In use, a continuous stream of high velocity air moves through the static mixing nozzle, and the material streams may be intermittently moved into the nozzle and aerated with an air supply to cause the A and B materials to be mixed with each other and moved with the air to form the plural component materials. The plural component materials are delivered from a static mixing nozzle at pressures of less than 300 psi. Spray guns configured for preparing the plural component materials are also disclosed. Polyurethane foams, polyurethane adhesives, and polyurea coatings prepared by the methods are further provided.

Hybrid spray foams utilize a urethane reactant, a crosslinker, and an (optional) epoxy and/or acrylic resin along with a blowing agent and rheology modifier to produce a quick-setting foam that remains in place until the foam forms and cures. The urethane reactant may be formed as an adduct with or without the use of isocyanate chemistry. In some embodiments, the polyurethane oligomer is made by reacting cyclocarbonates and di- or polyamines, while in other embodiments the polyurethane backbone employs the use of commercially available capped or blocked urethane oligomers made by any method. The oligomers contain reactive groups, typically at the oligomer ends, that crosslink with crosslinkers or with acrylic or epoxy resins to form hybrid polyurethane foams. Foams may also contain a plasticizer, and/or a surfactant as well as other optional additives. Methods of making such foams are also provided.