A process and composition is described for the inclusion of polyether polyols in concentrations greater than 10% loading on the B-side formulation with a catalyst package less than 1% loading on the B-side formulation. In one specific example, the use of glycerin as a fluorine ion scavenger is utilized to improve performance of the polyurethane systems through a twelve-month shelf life.

The disclosure provides methods for preparing a plural component foam where the materials supplies are provided from unpressurized storage containers. In use, a continuous stream of high velocity air moves through the static mixing nozzle, and the material streams may be intermittently moved into the gas stream of the nozzle and aerated and mixed with each other and moved with the air to form the plural component foam. The plural component foams are delivered from a static mixing nozzle at pressures of less than 300 psi. Spray guns configured for preparing the plural component foams are also disclosed. Polyurethane foams, polyurethane adhesives, and polyurea foams prepared by the methods are further provided.

Storage-stable two-component polyurethane or polyisocyanurate spray foam compositions are disclosed, said compositions comprising: (a) an A-side component comprising one or more polyisocyanate and one or more blowing agent; and (b) a B-side component comprising one or more polyol and one or more blowing agent comprising pressurized gaseous carbon dioxide and one or more liquid blowing agent; wherein both the A-side component and the B-side component, separately, generate less than 300 ppm of fluoride ion after one week of aging at 50 C.

For achieving a predetermined flame retardancy, a urethane resin composition comprises a polyisocyanate compound, a polyol compound, a catalyst, a foaming agent, ammonium polyphosphate, and phosphoric ester, and is free from red phosphorus.

The invention pertains generally to a process and a composition-of-matter for a shelf-stable open cell polyurethane HFO-blown two-component polyurethane foam composition having improved flame-retardant properties through the use of at least one organo-tin containing catalyst and at least one potassium containing catalyst; and at least one dimorpholino-based ether catalyst, a ratio of the at least one potassium-containing catalyst to the tin-containing catalyst being at least approximately 1.5:1.0, the at least one surfactant comprising a polydimethylsiloxane (PDMS) backbone and polyethylene oxide-co-propylene oxide (PEO-PPO) random copolymer grafts; and the added water comprises at least 8 weight percent of said B-side reactants, the polyurethane foam having a Class B rating with a flame spread between 25 and 75 inclusive and a smoke developed of under 450 using ASTM E 84 testing protocol.

The present invention is directed to polyol composition comprising a polyol mixture (PM) comprising a polyetherol (P1) based on a polyhydric alcohol and a polyetherol (P2) based on a diamine; and at least one hydrohaloolefin (HFO) as blowing agent, a process for preparing a polyurethane foam using said polyol composition and the polyurethane foam obtained or obtainable by said process.

A process for preparing polyether-siloxane block copolymers by hydrosilylation of alpha, omega-modified hydrosiloxanes with alpha,omega-modified di(meth)allyl polyethers in the presence of a hydrosilylation catalyst, wherein the reaction is performed in a solvent mixture comprising aromatic solvents and alkoxylated alcohol, is described.

Storage-stable two-component polyurethane or polyisocyanurate spray foam compositions are disclosed, said compositions comprising: (a) an A-side component comprising one or more polyisocyanate and one or more blowing agent; and (b) a B-side component comprising one or more polyol and one or more blowing agent comprising pressurized gaseous carbon dioxide and one or more liquid blowing agent; wherein both the A-side component and the B-side component, separately, generate less than 300 ppm of fluoride ion after one week of aging at 50 C.

A catalyst composition comprising at least one compound with a general formula I:

##STR00001## wherein A is NR.sup.3, R.sup.3 is C.sub.1-C.sub.8 linear or branched, x=0-6, n and m are each independently 1 to 6, R.sup.1 and R.sup.2 are each independently C.sub.2-C.sub.8 alkyl, and R.sup.4 and R.sup.5 are CH.sub.3 groups; or AO, x=0-6, n and m are each independently 1 to 6, R.sup.1 and R.sup.2 are each independently C.sub.2-C.sub.8 alkyl, and R.sup.4 and R.sup.5 are CH.sub.3 groups; or AO or NR.sup.3, R.sup.3 is C.sub.1-C.sub.8 linear or branched, and N(R.sup.1R.sup.4) and N(R.sup.2R.sup.5) each independently represent a C.sub.3-C.sub.7 ring amine moiety of the type:

##STR00002##

Disclosed herein are new types of foam insulation, and in particular, foam insulation for the exterior surfaces of residential, industrial, institutional or commercial buildings made using new silicone spray foam systems. These inventions relate to isocyanate-free foams used for thermal insulation, flame-retardancy and water resistance. The foams are prepared from silicone polymers with non-fluorinated blowing agents and can be used in the construction industry.