Described herein is a Low TVOC flame-retardant polyurethane spray foam system, including at least one isocyanate as isocyanate component, and at least one substance reactive toward isocyanate, chain extender and/or crosslinking agent, flame retardant, blowing agent, catalysts, and additives and/or auxiliaries, as resin components, where the flame retardant includes expandable graphite and melamine, the amount of expandable graphite is in the range of from 5 wt % to less than 30 wt %, and the amount of melamine is in the range of from greater than 5 wt % to 30 wt %, each based on the total weight of the resin components. Also described herein are a polyurethane spray foam produced therefrom, the preparation thereof, and a method of use thereof in the application of heat insulation, sound insulation, cavity filling and damping packing.

A polyurethane insulation foam composition is disclosed herein. The polyurethane insulation foam comprises: (i) an isocyanate compound; (ii) an isocyanate reactive compound; (iii) water; (iv) a tertiary amine compound; (v) a hydrophilic carboxylic acid compound; (vi) a halogenated olefin compound; and (vii) optionally, other additives.

The present disclosure relates to acid-blocked alkylaminopyridine catalysts for use in a polyurethane formulation. The polyurethane formulation may include the acid-blocked alkylaminopyridine catalyst, a compound containing an isocyanate functional group, an active hydrogen-containing compound and a halogenated olefin compound.

Process for preparing rigid polyurethane or urethane-modified polyisocyanurate foams from polyisocyanates and polyfunctional isocyanate-reactive compounds in the presence of blowing agents wherein the polyfunctional isocyanate-reactive compounds comprise an unmodified or modified novolac polyol and a polyether polyol having a hydroxyl number of between 50 and 650 mg KOH/g obtained by reacting a polyfunctional initiator first with ethylene oxide and subsequently with propylene oxide wherein the propoxylation degree is between 0.33 and 2 mole propylene oxide per active hydrogen atom in the initiator and wherein the molar ratio of ethylene oxide to propylene oxide in said polyether polyol is at least 2.

A polyurethane insulation foam composition is disclosed herein. The polyurethane insulation foam comprises: (i) an isocyanate compound; (ii) an isocyanate reactive compound; (iii) water; (iv) a tertiary amine compound; (v) a hydrophilic carboxylic acid compound; (vi) a halogenated olefin compound; and (vii) optionally, other additives.

The invention pertains generally to a process and a composition-of-matter for a shelf-stable open cell polyurethane HFO-blown two-component polyurethane foam composition having improved flame-retardant properties through the use of at least one organo-tin containing catalyst and at least one potassium containing catalyst; and at least one dimorpholino-based ether catalyst, a ratio of the at least one potassium-containing catalyst to the tin-containing catalyst being at least approximately 1.5:1.0, the at least one surfactant comprising a polydimethylsiloxane (PDMS) backbone and polyethylene oxide-co-propylene oxide (PEO-PPO) random copolymer grafts; and the added water comprises at least 8 weight percent of said B-side reactants, the polyurethane foam having a Class B rating with a flame spread between 25 and 75 inclusive and a smoke developed of under 450 using ASTM E 84 testing protocol.

A sheet is provided, the sheet including at least two polymeric layers including a bottom layer and a top layer, wherein the at least two polymeric layers are sprayed, wherein the at least two polymeric layers are seamlessly fused across the entire area of the sheet, creating a seamless, one piece sheet, and wherein at least one polymeric layer of the sheet contains gas bubbles. An article including the sheet is also provided.

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

An aerosol can configuration includes an outer can, an inner container and a spray head with a discharge element. The spray head has an outlet valve connected to the interior of the outer can and an outlet valve connected to the interior of the inner container. The two outlet valves are opened jointly by pressing on the spray head, so that the contents of the outer can and the contents of the inner container jointly enter the discharge element. To form a foam, the outer can contains at least 30-70% by weight isocyanate, in particular diphenylmethane 4,4′-diisocyanate, 3-15% by weight polyol with an OH number of less than 300, and 5-30% by weight liquid gas at a critical temperature of ≥+70° C. At least 5-30% by weight polyol with an OH number of more than 300, and 1-10% by weight liquid gas with a critical temperature of ≥+70° C. are contained in the inner container.

Various uses of fluoroalkenes, including tetrafluoropropenes, particularly (HFO-1234) in a variety of applications, including as blowing agents are disclosed.