A boron-containing proton-exchange solid support may include a proton-exchange solid support comprising an oxygen atom and a tetravalent boron-based acid group comprising a boron atom covalently bonded to the oxygen atom.

A proton exchange membrane includes a porous structural framework and a boron-based acid group bonded to the porous structural framework. The porous structural framework may be formed of an amorphous or crystalline inorganic material and/or a synthetic or natural polymer. The boron-based acid group may be a tetravalent boric acid derivative, such as a cyclic boric acid derivative, borospiranic acid, or a borospiranic acid derivative. The boron-based acid group may be the reaction product of boric acid or a boric acid derivative and a poly-hydroxy compound.

A method for cleaving a coordinate bond of a complex polymer that contains at least one polymer chain and a plurality of nitrogen- and/or phosphorus-containing functional groups which are bonded to the polymer chain and capable of forming coordinate bonds, wherein the coordinately-bondable nitrogen- and/or phosphorus-containing functional groups form a coordinate bond via a metal ion, characterized in that the method includes dissolving the complex polymer in a solvent containing a free ligand, to cleave the coordinate bond.

A proton exchange solid support includes a first solid support including a polymer, a second solid support, and a tetravalent boron-based acid group that links the first solid support to the second solid support.

Methods for recycling oligomeric units derived from a first polymer into a second polymer are provided herein. Methods of preparing oligomeric macromonomers from oligomeric units are further provided. Methods of polymerizing oligomeric macromonomers are further provided.

The present invention relates to a porous organic polymer-based hydrogen ion conductive material and a method for preparing the same. More specifically, the present invention relates to a method for preparing a porous organic polymer (POP)-based material with high proton conductivity that is applicable to a membrane electrode assembly (MEA) of a proton exchange membrane fuel cell (PEMFC). The porous organic polymer-based proton conductive material of the present invention can be prepared in an easy and simple manner by microwave treatment and acid treatment requiring short processing time and low processing cost. In addition, the porous organic polymer-based proton conductive material of the present invention can be developed into a highly proton conductive material having the potential to replace Nafion through a simple post-synthesis modification. Therefore, the porous organic polymer-based proton conductive material of the present invention is suitable for use in a proton exchange membrane fuel cell.

A decorative sheet includes a primary film layer; a transparent resin layer; and a surface protective layer, in this order; the surface protective layer is formed of a plurality of layers with a layer located on an outermost surface is a surface protective layer, and a layer underlying the surface protective layer is a second surface protective layer and includes one or more ionizing radiation-curable resins having an erosion rate E in a range of 0.10 μm/g or more and 0.45 μm/g or less, and one or more thermosetting resins having an erosion rate E in a range of 0.30 μm/g or more and 0.6 μm/g or less, the erosion rate E being measured by using polygonal alumina powder having an average particle size (D50) of 1.2 μm, and a mass ratio between the ionizing radiation-curable resin and the thermosetting resin (ionizing radiation-curable resin/thermosetting resin) is 95/5 to 40/60.

A proton exchange membrane includes a porous structural framework and a boron-based acid group bonded to the porous structural framework. The porous structural framework may be formed of an amorphous or crystalline inorganic material and/or a synthetic or natural polymer. The boron-based acid group may be a tetravalent boric acid derivative, such as a cyclic boric acid derivative, borospiranic acid, or a borospiranic acid derivative. The boron-based acid group may be the reaction product of boric acid or a boric acid derivative and a poly-hydroxy compound.

A decorative sheet includes a primary film layer; a transparent resin layer; and a surface protective layer, in this order; the surface protective layer is formed of a plurality of layers with a layer located on an outermost surface is a surface protective layer, and a layer underlying the surface protective layer is a second surface protective layer and includes one or more ionizing radiation-curable resins having an erosion rate E in a range of 0.10 μm/g or more and 0.45 μm/g or less, and one or more thermosetting resins having an erosion rate E in a range of 0.30 μm/g or more and 0.6 μm/g or less, the erosion rate E being measured by using polygonal alumina powder having an average particle size (D50) of 1.2 μm, and a mass ratio between the ionizing radiation-curable resin and the thermosetting resin (ionizing radiation-curable resin/thermosetting resin) is 95/5 to 40/60.

Provided is an ion-conducting layer including: an ion conductive matrix; and a 1D composite dispersed in the ion conductive matrix and oriented in a membrane thickness direction, in which the 1D composite includes a core of a non-conductive 1D nanostructure; an intermediate layer enclosing the core and having magnetic nanoparticles bonded to a surface thereof; and a surface layer conducting the same kind of ions as ions in the matrix.