The present invention provides a hydrophobic thermoplastic starch and method for manufacturing the same, to be used as granules for making biodegradable composites. The hydrophobic thermoplastic Starch of the invention is in a granule type, has the melt flow index in the range of 0.2-6 g/10 min at 160° C. and has 60-80 wt % of starch and the water content less than 9%.

The present invention provides methods for preparing the nut waste sheet composites from a nut waste component and one or more binders.

The present invention provides methods for preparing the nut waste sheet composites from a nut waste component and one or more binders.

A method of producing a thermoplastic starch by an in-situ reactive extrusion plasticization process and a method for preparing a starch/polymer blend by an in-situ reactive extrusion plasticization and compatibilization process. In the method, a plasticizer reaction precursor (or a plasticizing compatibilizer reaction precursor) is mixed with starch to adhere to the surface of the starch or enter the starch to break the intermolecular and intramolecular hydrogen bonds of the starch. Then a mixture of the plasticizer reaction precursor (or the plasticizing compatibilizer reaction precursor) and starch is subjected to extrusion to produce the thermoplastic starch (or the starch/polymer blend), where the reaction precursor undergoes an in-situ reaction on the surfaces of the starch and in the starch to form a macro-molecular plasticizer (or a plasticizing compatibilizer) to plasticize starch or provide plasticizing and compatibilizing effect on the starch/polymer blend.

The instant invention relates to new film-forming compositions based on starchy material, comprising isosorbide. The instant invention also relates to products made from the film-forming compositions of the invention, in particular hard and soft capsules shells, and to methods for the manufacture of such products.

An example starch-based material for forming a biodegradable component includes a mixture of a starch and an expansion additive. The starch has an amylose content of less than about 70% by weight. The expansion additive enhances the expansion and physical properties of the starch. A method of preparing a starch-based material is also disclosed and an alternate starch-based material for forming a biodegradable component is also disclosed.

The present disclosure relates to a modified environment-friendly corn starch adhesive, comprising the following components in parts by weight: 30 parts of corn starch, 300-400 parts of water, 0.2-3 parts of oxidant, and 80-120 parts of polyvinyl alcohol, 1-5 parts of cross-linking agent, 3-5 parts of calcium chloride, 0.1-3 parts of urea, 0.2-0.5 parts of defoamer, and an appropriate amount of sodium hydroxide (to adjust pH), the cross-linking agent is a modified boric acid cross-linking agent prepared by reacting boric acid with epichlorohydrin, water and citric acid at 80-100° C. The surface of the modified boric acid cross-linking agent is bonded with a large number of epoxy groups and carboxyl groups, which can react with the carboxyl and aldehyde groups of the oxidized starch. These reactions can form synergistic effect with boric acid, which together improve the bonding efficiency and improve the adhesive strength of the colloid.

The invention relates to a method for producing a compound or a film containing thermoplastic starch, an alpha-hydroxycarboxylic acid ROHCOOH, in which R is CH.sub.2 or CH.sub.3CH.sub.2, in an amount of from 0.1 to 5, preferably 0.1 to 3, particularly preferably 0.1 to 1 wt. % in relation to the thermoplastic starch, and a thermoplastic polymer, in which method the compound or the film is exposed during or after its extrusion to an additional heating step to 100-140° C. A thermoplastic starch usable for the production of the compound, a compound produced by the method, and a transparent film produced from such a compound are also described.

A bio-based UV-curable 3D printed resin includes the following components by weight percentage: 19-78% of biodegradable starch resin polymer, 1-9% of radical initiator, 0.2-4% of adjuvant, 13-62% of reactive diluent and 2-8% hydroxyethyl starch. The preparation method thereof comprises the following steps of: mixing the above components by component proportion, ultrasonically washing the mixture for 10-20 min by an ultrasonic cleaner under a water temperature of 50° C., and then mixing the same in a homogenizer homogeneously to obtain the bio-based UV-curable 3D printed resin. The renewable resources are adopted and the environmental pollution and energy consumption are reduced, which is of bio-safety. Moreover, the hydroxyethyl starch has a high molecular compound generated by hydroxyethylation of glucose ring of amylose, resulting in various benefits. The 3D printed resin obtained has excellent performance and low skin irritation value.

A plastic pro-biodegradation additive includes a carrier polymer and a nanostarch compound. The nanostarch compound can include nanostarch with a particle size in a range of about 40 to about 500 nm. The nanostarch compound can include small-size and/or large-size regular starch. The carrier polymer can be a biodegradable polymer. The additive can include: a polysaccharide; an organic filler; one or more of a monosaccharide, a disaccharide and an oligosaccharide; a surfactant; and/or an inorganic filler. The carrier polymer can include a non-biodegradable polymer. Biodegradable plastic compositions and methods of preparing a biodegradable plastic material are also disclosed.