An extruder is disclosed including: a barrel; and a screw provided with a helical groove; wherein the screw comprises a dewatering portion comprising a first portion, and a second portion at a location downstream from the first portion; wherein, at the dewatering portion, clearance between the groove and the barrel decreases as one proceeds downstream; and wherein clearance reduction ratio at the first portion is greater than clearance reduction ratio at the second portion.

A detachable glove comprising at least two layers that are separated by an adhesive layer, wherein the adhesive layer includes a wetting agent, a latex coagulating agent, a synthetic organic polymer and water. A chlorinated detachable bi-layered glove and a method of manufacturing thereof. A polymer coated, detachable, bi-layered glove and a method of manufacturing thereof. A method of peeling a detachable bi-layered glove wherein the method includes (i) pulling cuff area of the outer glove layer until its circumference is detached from the inner glove layer and (ii) peeling off the outer glove layer once the full circumference of the outer glove layer is detached from the inner glove layer to yield the inner glove layer for further usage.

The present invention relates to a method of preparing reduced graphene oxide, incorporation of the reduced graphene oxide into polyisoprene latex to provide a polyisoprene latex graphene composite and elastomeric articles prepared using the polyisoprene latex-graphene composite. In particular, the reduction of graphene oxide is accomplished without the use of strong reducing agents and organic solvents and incorporation of the reduced graphene oxide into polyisoprene latex is accomplished using room temperature latex mixing method or hot maturation. The resultant composite exhibits good colloid stability, and polyisoprene latex films produced the composite exhibit good mechanical properties with improved ageing resistance.

An elastomeric article having a rubber component comprising polyisoprene and an aldehyde aniline condensate, the elastomeric article having less than 1 ppm diisopropyl xanthogen polysulfide residue.

A shoe cover is a natural latex article with reduced amount of sulfur cross linking agent and accelerators including zinc dithiocarbamate that break catalytically soluble sulfur S.sub.8 sulfur rings forming sulfur linear chains. Surfactants present in the pre-vulcanization composition wets natural polyisoprene particles and permeates small sized sulfur into the interior of these particles thereby pre-vulcanizing the particles. The latex emulsion also has post-vulcanization composition with accelerators that crosslink between particles during the post vulcanization cure cycle. The dipped natural polyisoprene article is substantially uniformly cured both in the inter-particle and intra-particle regions and reliably exhibits high cross link density, uniform distribution of double bonds and zinc segregation at the boundaries or original particles. The natural rubber films exhibit high tensile strength, tensile modulus, tear strength, elongation with low modulus of the shoe cover. The bottom surface of the shoe cover is etched to produce a slip resistant surface.

Methods of vulcanization using a high content sulfur polymer, instead of elemental sulfur, have been developed. These high sulfur content polymers are referred to as Chalcogenide Hybrid Inorganic/Organic Polymers (CHIP) materials and have good polymer compatibility in that they are soluble in a number of polymers. Furthermore, CHIP materials may have weaker bonds than the S—S bonds of elemental sulfur and thus provide for a higher crosslinking efficiency vulcanization.

A resin composition containing heat-expandable microspheres including a thermoplastic resin shell and a thermally vaporizable blowing agent encapsulated therein and at least one base resin selected from rubbers, olefin resins and thermoplastic elastomers. The thermoplastic resin is a polymer of a polymerizable component containing N-substituted maleimide and a nitrile monomer containing methacrylonitrile. Also disclosed are molded articles manufactured by molding the resin composition.

The present invention relates to a method of preparing reduced graphene oxide, incorporation of the reduced graphene oxide into polyisoprene latex to provide a polyisoprene latex graphene composite and elastomeric articles prepared using the polyisoprene latex-graphene composite. In particular, the reduction of graphene oxide is accomplished without the use of strong reducing agents and organic solvents and incorporation of the reduced graphene oxide into polyisoprene latex is accomplished using room temperature latex mixing method or hot maturation. The resultant composite exhibits good colloid stability and polyisoprene latex films produced from the composite exhibit good mechanical properties with improved ageing resistance.

Provided are a polymer material that contributes to environmental protection, has biodegradability, has excellent well-balanced mechanical properties, self-adhesion, and the like, is flexible, and has a reduced variation in the properties. The present invention provides a biodegradable rubber composition comprising natural rubber and an inorganic substance powder in a mass ratio of 45:55 to 10:90, and modified cellulose in an amount of 0.5 part by mass to 10.0 parts by mass relative to 100 parts by mass of the natural rubber.

A method for producing a rubber wet master batch is disclosed including: producing a carbon black-containing rubber latex solution by mixing carbon black, a dispersion solvent and a rubber latex solution; producing a carbon black-containing rubber coagulum by coagulating the thus-obtained carbon black-containing rubber latex solution; and producing a rubber wet master batch by dehydrating and drying the thus-obtained carbon black-containing rubber coagulum. With respect to this method for producing a rubber wet master batch, the carbon black satisfies conditions such that: the DBP oil absorption is 105-230 mL/100 g; STSA is 90-205 m.sup.2/g; and the value obtained by subtracting the value of STSA from the value of DBP oil absorption is 15 or more. This method for producing a rubber wet master batch enables the achievement of a vulcanized rubber that has wear resistance and low heat generation properties.