The invention relates to an elastomeric film-forming composition comprising (a) a copolymer formed from monomers consisting of chlorobutadiene and an ethylenically unsaturated carboxylic acid or ester, and (b) one or more cross-linking agents. The invention also relates to dipped articles, gloves, methods of manufacture and uses involving the composition.

A latex for dip forming and a sulfur-based crosslinking agent, and has a pH of 9.5-11, the latex containing a copolymer having 40-80% by weight of conjugated diene monomer units (A) that contain a butadiene unit and an isoprene unit, 10-45% by weight of ethylenically unsaturated nitrile monomer units (B), and 2-15% by weight of ethylenically unsaturated acid monomer units (C), the ratio between the butadiene unit content and the isoprene unit content being 40:60 to 95:5 expressed in terms of weight.

The invention relates to a method for the manufacture of a prophylactic article, especially of a glove, from a (carboxylated) diene rubber, according to which a layer of a (carboxylated) diene latex is applied on a former and the (carboxylated) diene latex is cross-linked with a cross-linking agent, which is immobilized on inorganic and/or organic particles with formation of modified particles, and the modified particles are added to the (carboxylated) diene latex.

According to a method for the manufacture of a prophylactic article, especially of a glove, from a (carboxylated) diene rubber, at least one layer of a (carboxylated) diene latex is applied on a former and the (carboxylated) diene latex is cross-linked with a cross-linking agent, wherein a mercapto-functional siloxane polymer is used as cross-linking agent.

A binary process for manufacturing dipped latex product. The binary process disclosed herein eliminates the influence of any level of pre-vulcanization on the outcome of the dipping process whether using natural or synthetic latex. The binary process includes preparing a first latex mixture Formulation A including latex, one or more accelerators, and one or more surfactants, but without curing agents; and preparing a second latex mixture Formulation B including latex, one or more curing agents, and one or more surfactants, but without curing accelerators. The process further includes dipping one or more formers into the Formulations A and B separately in order to form a plurality of coatings/layers of the Formulations A and B, and later on curing the plurality of coatings/layers on the formers to form the dipped latex products, which can be a condom, glove, balloon, catheter, finger cot, surgical tubing, baby bottle nipple or dental dam.

A polymer latex, including a polymerization step of polymerizing a monomer in organic solvent to thereby obtain polymer solution of synthetic polyisoprene and/or styrene-isoprene-styrene block copolymer, antioxidant addition step of adding antioxidant to the polymer solution of synthetic polyisoprene and/or styrene-isoprene-styrene block copolymer at proportion of 0.01-1.00 parts by weight per 100 parts by weight of the synthetic polyisoprene and/or styrene-isoprene-styrene block copolymer, and emulsification step of emulsifying the polymer solution which the antioxidant is added, in water in the presence of a surfactant, to thereby obtain polymer latex, wherein the emulsification performs in the emulsification step so the ratio D75/D25 of the volume particle size D75 at a cumulative frequency of 75% to the volume particle size D25 at a cumulative frequency of 25% of a particle of the synthetic polyisoprene and/or styrene-isoprene-styrene block copolymer included in the polymer latex is 1.90 or more and 2.30 or less.

A method for producing a polymer latex, includes: a stirring step of adding water to a polymer solution obtained by dissolution of a synthetic rubber in an organic solvent, to allow water to be stirred in the polymer solution, thereby providing a water-stirred polymer solution (A); an aqueous phase removal step of removing an aqueous phase from the water-stirred polymer solution (A), thereby providing an aqueous phase-removed polymer solution (B); an emulsification step of mixing the aqueous phase-removed polymer solution (B) with an aqueous solution including a surfactant, for emulsification in water, thereby obtaining an emulsified liquid (C); a solvent removal step of removing an organic solvent in the emulsified liquid (C); and a concentration step of concentrating the emulsified liquid from which the organic solvent is removed (D).

Methods to make a silica elastomer composite with a destabilized dispersion of silica are described, along with silica elastomer composites made from the methods. The advantages achieved with the methods are further described.

A synthetic polyisoprene latex containing synthetic polyisoprene, wherein the synthetic polyisoprene constituting the synthetic polyisoprene latex includes a low-molecular weight synthetic isoprene chain having a molecular weight of less than 1,000,000 at a content rate of 10 to 70% by weight and a high-molecular weight synthetic isoprene chain having a molecular weight of 1,000,000 or more at a content rate of 30 to 90% by weight. Also, a method for producing the synthetic polyisoprene latex, wherein the synthetic polyisoprene containing the low-molecular weight synthetic isoprene chain and the high-molecular weight synthetic isoprene chain is obtained by polymerizing a monomer containing isoprene in an organic solvent by use of an organic alkali metal catalyst.

Functionalized substrates with properties that can control cell-substrate interactions, induce cellular processes and decisions by means of passive and active control to enhance cell proliferation, cell migration and wound healing are provided. By including a sensing electrode on the substrate, it is possible to measure the metabolites of cells or follow the migration of additives like drug molecules in real-time. The present technology provides a new cell culture and imaging platform composed of a transparent and chemically and topographically customized latex film with electrodes that enable real-time measurement of e.g. pH and ion concentration in the cell medium as well as the metabolic states of the cells.