Methods of depolymerizing polyolefin-based material into useful petrochemical products using metal oxides and heat are described. The metal oxides improve the depolymerization reaction by decreasing the onset temperature for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.

A coated substrate that comprises a polyolefin substrate having a functional polymer layer disposed thereon. The polyolefin substrate has a flow through pore structure with a pore size ranging from about 5 microns to about 250 microns. The functional polymer layer has a thickness ranging from about 1 micron to about 20 microns and a layer pore structure having a pore size ranging from about 1 nm to about 100 nm.

A multilayer film having enhanced toughness and optical properties is provided. The multilayer film includes a base layer, an outer layer, and a tie layer between the base layer and the outer layer. The multilayer film can also include additional layers. Methods for making such multilayer films are also provided. Multilayer films according to the present invention are particularly useful packaging applications where rupture resistance and high clarity are desirable.

An improved method forms and employs a wax to modify asphalt. The method includes: (a) selecting a solid polymeric material, (b) heating the solid polymeric material in an extruder to produce a molten polymeric material, (c) filtering the molten polymeric material, (d) placing the molten polymeric material through a chemical depolymerization process in a reactor to produce a depolymerized polymeric material, and (e) adding the depolymerized material to a pre-wax mixture to produce a polymer-modified asphalt. The addition of wax reduced the mixing time necessary to achieve improved polymer dispersion compared to the control formulation modified bitumen and reduced the viscosity of the neat bitumen. Pre-polymer addition of wax is detrimental to most properties of the resulting modified asphalt. Post-polymer addition improved viscosity reduction, higher softening point and improved dimensional stability.

Foam pellets comprising a thermoplastic vulcanizate (TPV) and thermo-expandable microspheres, the foam pellet having a specific gravity of 0.2 to 1.0 and the TPV being composed of an at least partially vulcanized rubber component and a thermoplastic component. The foam pellets may be subsequently processed to form various foam articles without the need to include a foaming agent during processing.

A method for preparing a polymer mould-free stereostructure foamed product from supercritical fluid, containing a supercritical fluid delivery system, a stereoscopic foaming system and a preheating system, and has the following steps: performing pressure molding on a polymer material to obtain a foaming preform, then preheating the foaming preform in the preheating system, delivering the foaming preform to the stereoscopic foaming system after a temperature rises to a preheating temperature, introducing the supercritical fluid, and decompressing after the supercritical fluid is swelled and diffused to the polymer. The polymer is swelled using high-temperature medium-pressure supercritical fluid by utilizing a one-step method in a stereoscopic foaming tank and then subjected to free mould-free stereoscopic pressure-relief form molding, so as to obtain a polymer microcellular foamed product with controllable product shape, size precision, pore fineness and product density.

A non-linear surfactant, and particularly a non-linear surfactant comprising bi-functionalized molecules or particles having both hydrophobic and hydrophilic groups. The non-linear surfactant includes a nanoparticle template of a rigid molecular structure, wherein the nanoparticle comprises a molecule or a particle that is bi-functionalized with both hydrophilic and hydrophobic groups to obtain an amphiphilic nanoparticle. The template nanoparticle can be used as a surfactant, wetting agent, emulsifier, detergent or other surface active agents or for the preparation of nanoemulsions or dispersions. The non-linear surfactant can provide smaller particle sizes for emulsion suspensions and foams.

Provided is a resin composition for molding materials, comprising a plant fiber (A), a thermoplastic resin (B), and a compound (C) having a reactivity with a carboxy group.

Some embodiments of the present disclosure relate to an article comprising a reinforced glass mat. In some embodiments, the reinforced glass mat includes a glass mat and a reinforcement material. In some embodiments, the glass mat includes a web of glass fibers. In some embodiments, the reinforcement material is embedded into the web of glass fibers of the glass mat. In some embodiments, the reinforced glass mat includes a sufficient amount of the reinforcement material, so as to result in a nail shank shear resistance of 13 lbs to 17 lbs, when the article is tested according to ASTM 1761 at 140° F. Methods of making the article, specific embodiments of the reinforcement material in the form of a polymeric binder, and methods of forming a roofing shingle from the article are also disclosed.

Disclosed herein is a catalyst which comprises a silica core having an outer surface and a mesoporous silica shell having an outer surface and an inner surface with the inner surface being inside the outer surface of said mesoporous silica shell proximate to and surrounding the outer surface of said silica core. Wherein the outer surface of the mesoporous silica shell has openings leading to pores within the mesoporous silica shell which extend toward the outer surface of said silica core. The catalyst also includes catalytically active metal nanoparticles positioned within the pores proximate to said core, wherein the catalytic metal nanoparticles comprise about 0.0001 wt % to about 1.0 wt % of the catalyst. Also disclosed are methods of making the catalyst and using it to carry out a process for catalytically hydrogenolysizing a polyolefinic polymer.