Patent classifications
C08J2333/02
SUPERABSORBENT POLYMER HAVING EXCELLENT ANTIMICROBIAL AND DEODORIZING PROPERTIES, AND METHOD FOR PREPARING SAME
Disclosed are an antibacterial superabsorbent resin having excellent antibacterial and deodorizing properties and a method of preparing the same, wherein a fine powder can be recycled in a manner in which the fine powder is added with an additive and an antibacterial material upon regranulation thereof, thus minimizing the deterioration of the properties of the resulting superabsorbent resin and imparting antibacterial and deodorizing properties, as a consequence of which an antibacterial superabsorbent resin having excellent antibacterial and deodorizing properties can be economically obtained and can be applied to hygiene products.
PREPARATION METHOD AND APPLICATION OF POROUS HYDROGEL ADSORBENT BASED ON RADIX ASTRAGALI RESIDUE
The present disclosure provides a preparation method of a porous hydrogel adsorbent based on Radix Astragali residues, including the following steps: subjecting residues of Chinese herbal medicine Radix Astragali as a precursor to bleaching with NaClO.sub.2, alkaline washing with KOH, and high power ultrasonic treatment, thereby obtaining a precursor solution of uniformly dispersed cellulose nanofibers (CNFs); adding the precursor solution of CNFs to a mixed solution of N,N′-methylene bisacrylamide (MBA), acrylic acid (AA) and ammonium persulfate (APS), shaking evenly, and initiating a polymerization reaction at a predetermined temperature to form a monolithic gel; and cleaning the monolithic gel, putting the cleaned monolithic gel into a dimethyl sulfoxide (DMSO) solution containing epichlorohydrin to allow reaction, and transferring the product of the reaction to an aqueous sodium hydroxide solution containing triethylene tetramine to allow reaction, thereby finally obtaining an amino-functionalized porous hydrogel adsorbent.
RECYCLING OF SUPERABSORBENT FIBERS WITH AN EXTENSIONAL FLOW DEVICE
Superabsorbent fiber (SAF) in a feed stream is converted into soluble polymers in an extensional flow device. The total energy used to degrade the SAF into soluble polymers is less than about 50 MJ/kg SAF.
RECYCLING OF SUPERABSORBENT FIBERS VIA UV IRRADIATION IN FLOW SYSTEM
Superabsorbent fibers (SAF) in a feed stream is converted with UV irradiation into soluble polymers in a flow system. The UV total energy used to convert SAF into soluble polymers is less than about 50 MJ/kg SAF.
RECYCLING OF SUPERABSORBENT FIBERS WITH AN EXTENSIONAL FLOW DEVICE
Superabsorbent fibers (SAF) in a feed stream is converted into soluble polymers in an extensional flow device. The total energy used to degrade the SAF into soluble polymers is less than about 50 MJ/kg SAF.
Recycling of Superabsorbent Polymer With a Hybrid Oxidative Degradation and High Shear Mixing
New process for recycling of poly(acrylic acid)-based superabsorbent polymer (SAP) using a synergistic combination of high shear mixing device and oxidative degradation of SAP to produce poly(acrylic acid) (PAA) useful to recycle pre- and post-consumer SAP.
METHOD FOR PRODUCING WATER-ABSORBING POLYMER PARTICLES BY SUSPENSION POLYMERIZATION
A process for producing water-absorbing polymer particles by suspension polymerization and thermal surface postcrosslinking, wherein the agglomerated base polymer obtained by suspension polymerization has a centrifuge retention capacity of at least 37 g/g and the thermal surface postcrosslinking is conducted at 100 to 190° C.
Temperature-responsive gel having LCST with no volume phase transition, and production method therefor
A temperature-responsive hydrogel which contains a carboxyl group-bearing polymer and a divalent-metal salt of an organic acid is provided. The carboxyl group-bearing polymer may be a homopolymer of a carboxyl group-bearing monomer or a copolymer of a plurality of monomers including the monomer. A method for producing the temperature-responsive hydrogel involves immersing a carboxyl group-bearing polymer in an aqueous solution of a divalent-metal salt of an organic acid. The concentration of the divalent-metal salt of an organic acid in the aqueous solution may be 50 mM to the saturation concentration. It is possible to provide a temperature-responsive gel having an LCST with no volume phase transition and a method for producing the temperature-responsive gel.
METHOD FOR PRODUCING WATER-ABSORBENT RESIN
[Object] To provide a method for stably producing a water-absorbent resin in powder form or particle form, which has excellent physical properties such as water absorption performance and the like, without any production trouble.
[Solution] A method for producing a water-absorbent resin includes mixing a monomer composition, which contains at least a monomer and a pyrolytic polymerization initiator, with an organic solvent, a temperature of the organic solvent is not lower than 70° C. at time of mixing, and when a mass per unit time of the monomer in the monomer composition to be mixed with the organic solvent is expressed as an amount per unit volume of the organic solvent, a lower limit is 0.01 g/ml/min, and an upper limit is 0.2 g/ml/min.
METHOD FOR PREPARING SUPERABSORBENT POLYMER TREATED WITH WATER DISPERSION SOLUTION CONTAINING MICROPARTICLES
Disclosed are a method of preparing a superabsorbent polymer, including adding a superabsorbent polymer with a water dispersion solution containing particles having i) a BET specific surface area of 300 to 1500 m.sup.2/g and ii) a porosity of 50% or more, and a superabsorbent polymer prepared by the method.