The invention provides a powder pre-preg comprising as sole resin a vinyl ester resin having a Tg in the range of −5 to +30° C. and a melt viscosity @100° C. in the range of 2 to 75 dPa.Math.s, which can be used in making a composite at a temperature as low as 80° C.

A multistage filament winding process for manufacturing a composite article using a dual chemistry formulation including the steps of (a) providing a dual chemistry formulation containing components to effectuate dual cure of the formulation; (b) winding fibers on a liner or on a mandrel; (c) impregnating the wound fibers of step (b) with the dual chemistry formulation; (d) activating a first reaction (A) by UV or thermal-free radical initiation sufficient to form first macroscopic gels and to allow the first macroscopic gels to phase separate from the remaining substantially unreacted components in the formulation; (e) optionally, activating a second reaction by heating through IR lamps or other heating apparatus and controlling the second reaction sufficient to form second macroscopic gels subsequent to the formation of the first macroscopic gels which have gelled and phase separated in the formulation; (f) repeating steps (a)-(d) until a composite article having a predetermined thickness is formed; and (g) heating the formed composite article of step (f) sufficient to form a final composite article product having a predetermined glass transition temperature; a cured thermoset article prepared by the above process; and a process for manufacturing spoolable pipe.

A matrix resin composition for fiber reinforced composite materials is described. The resin is thermosetting and achieves a glass transition temperature of at least 177° C. (Tg), obtained by curing under anaerobic conditions at room temperature. The matrix resin will streamline composite fabrication processes by eliminating the need for heating during the cure process. The implications of this development are significant in terms of the ease of use and elimination of procedural steps. While the resin system was developed specifically for vacuum bagging, it is expected to be viable for other composite fabrication methods including resin transfer molding (RTM) and vacuum-assisted resin transfer molding (VARTM). The resin system is viable for use with carbon fiber reinforcements to fabricate laminates at least 0.20 inches thick. The resulting laminates have low porosity and mechanical properties equivalent to those prepared with common epoxy matrix resins.

A structure for protecting a substrate. The structure comprises an inner tie coat layer which can bond to the substrate, a geopolymer foam layer, and an outer protective layer. The geopolymer foam layer is the reaction product of a mixture comprising an aluminosilicate source, an alkali activator, reinforcing fibres, and a plurality of microparticles.

A laminated body in which a thermoplastic resin layer, a thermosetting resin layer, and a protective film are layered one on another in this order, in which the thermosetting resin layer contains a thermosetting resin composition containing two or more kinds of organometallic complex, a surface of the protective film at an opposite side of the thermosetting resin layer has a surface roughness Ra of 30 nm or less, and an amount of nitrogen atoms present at the surface of the protective film at the side of the thermosetting resin layer is less than 1 atm %.

Multicomposite material (R1, R2) including at least one monofilament (10) made of glass-resin composite including glass filaments (101) embedded in a thermoset polyester resin (102), characterized in that said monofilament is coated with at least one layer (12) of benzoxazine; use of such a material as reinforcer in finished articles or semi-finished products made of rubber; finished articles or semi-finished products made of rubber, such as vehicle tyres, reinforced with such a material.

Multicomposite material (R1, R2) including at least one monofilament (10) made of glass-resin composite including glass filaments (101) embedded in a thermoset polyester resin (102), characterized in that said monofilament is coated with at least one layer (12) of benzoxazine; use of such a material as reinforcer in finished articles or semi-finished products made of rubber; finished articles or semi-finished products made of rubber, such as vehicle tyres, reinforced with such a material.

The radical curable resin composition contains as essential raw materials a vinyl ester resin (A), an unsaturated monomer (B) with a flash point of 100° C. or higher, a polyisocyanate (C), a polymerization initiator (D), a stabilizer (E), and a polymerization inhibitor (F), the stabilizer being a nitroxy radical, and the polymerization inhibitor being at least one or more compounds represented by General Formula (1) or (2). This radical curable resin composition is excellent in handleability, flexibility, and curability during molding and excellent in storage stability with little change over time in the curability during molding, and can thus be suitably used for molding materials and molded articles obtained therefrom. In General Formulae (1) and (2). R.sup.1 represents a hydrogen atom or a C.sub.1-4 alkyl group, and X.sup.1 and X.sup.2 each independently represent a hydrogen atom, a C.sub.1-4 alkyl group, a hydroxy group, or a methoxy group.

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A laminated body in which a thermoplastic resin layer, a thermosetting resin layer, and a protective film are layered one on another in this order, in which the thermosetting resin layer contains a thermosetting resin composition containing two or more kinds of organometallic complex, a surface of the protective film at an opposite side of the thermosetting resin layer has a surface roughness Ra of 30 nm or less, and an amount of nitrogen atoms present at the surface of the protective film at the side of the thermosetting resin layer is less than 1 atm %.

The invention provides a powder pre-preg comprising as sole resin a vinyl ester resin having a Tg in the range of −5 to +30° C. and a melt viscosity @100° C. in the range of 2 to 75 dPa.Math.s, which can be used in making a composite at a temperature as low as 80° C.