Provided is a method for manufacturing an LCP film for a circuit substrate capable of achieving an LCP film for a circuit substrate having a low coefficient of linear thermal expansion and excellent dimensional stability, without excessively impairing excellent basic performance possessed by the liquid crystal polyester, such as mechanical characteristics, electrical characteristics, and heat resistance. The method for manufacturing an LCP film for a circuit substrate at least comprising: a composition provision step of providing an LCP resin composition at least containing 100 parts by mass of a liquid crystal polyester and 1 to 20 parts by mass of a polyarylate; a film forming step of T-die melt-extruding the LCP resin composition to form a T-die melt-extruded LCP film having a coefficient of linear thermal expansion (α2) in a TD direction of 50 ppm/K or more; and a pressurizing and heating step of subjecting the T-die melt-extruded LCP film to pressure and heat treatment to obtain an LCP film for a circuit substrate having a coefficient of linear thermal expansion (α2) in the TD direction of 16.8±12 ppm/K.

The present invention is directed to biodegradable sheets and straws formed from a composition comprising a first biodegradable polymer selected from the group consisting of PBAT, PBS, PLA and combinations thereof; and a second biodegradable polymer selected from the group consisting of PBS, PLA, PCL, PBSA, PBAT and combinations thereof, wherein the first biodegradable polymer is different from the second biodegradable polymer and wherein the straws or sheets have a thickness of 100-250 microns.

A biobased additive is provided that is both a nucleating and a reinforcing agent when added to thermoplastic polyester (e.g., biopolyesters). A composite material, which is an additive-reinforced biopolyester, was prepared and improved thermo-mechanical properties were quantified. This composite material is a new class of biobased material that offers a sustainable, environmentally-friendly solution for packaging and other applications.

An amorphous polyester or copolyester composition comprises the reaction product of a crystalline or semicrystalline polyester or copolyester, optionally derived from a recycled waste stream, at least one diol or aromatic diacid or an ester of a diacid or a hydroxycarboxylic acid or a lactone or a dianhydride, and a catalyst, wherein the amorphous composition has a weight average molecular weight of at least 10,000 g/mol (polystyrene equivalent molecular weight) as measured by gel permeation chromatography.

A method of depolymerizing a polymer by combining together the polymer with an enzyme (a hydrolytic enzyme capable of catalyzing cleavage of said (CO)—O bond of an ester or carbonate linkage of the polymer) and an aqueous liquid to provide a reaction mixture. The polymer comprises a (CO)—O bond of an ester or carbonate linkage. The reaction mixture defines a ratio eta (η) of liquid volume, in μL, to total solids, in mg, that is less than 2 μL/mg. Then, allowing an enzyme-catalyzed reaction of the enzyme with the polymer to take place thereby forming a reaction product.

The invention provides a biaxially oriented polyester film having excellent impact strength and heat resistance and a method for producing same. The method comprises (A) melt-extruding a composition comprising polyester resin for which Tc−(Tg+Tm)/2 is 25−30° C. to obtain unstretched polyester resin composition sheet, which (B) is heated at Tg+5 (° C.) to Tg+40 (° C.) of the polyester resin and stretched in the machine direction at 2×-6× to obtain uniaxially oriented polyester resin composition film, which (C) is heated at Tc−46 (° C.) to Tc+25 (° C.) of the polyester resin and stretched in the transverse direction at 4×−8× to obtain biaxially oriented polyester resin composition film, which (D) undergoes relaxation at 3%-20% in the transverse direction as heated at Tm−40 (° C.) to Tm−5 (° C.) of the polyester resin.

A method of immobilization of an insoluble dopant. In some embodiments, the insoluble dopant comprises a coordination polymer. In some embodiments, the insoluble dopant comprises a vapochromic coordination polymer. The method may comprise dissolving a polymer carrier in a solvent. The polymer carrier may comprise a thermoplastic such as, but not limited to, polylactic acid, polyethylene glycol or polycarbonate. The insoluble dopant (e.g. a coordination polymer such as a vapochromic coordination polymer) may then be mixed into the dissolved polymer. Phase separation of the mixture of the dopant and dissolved polymer may be induced to form a hydrogel. The hydrogel may be employed as is (e.g. as a raw material for hydrogel 3D printing, as a sensing material, etc.) or may undergo further processing (e.g. solidification, grinding, extrusion, etc.) before being employed, for example, as a raw material for 3D printing, as a sensing material, etc.

The invention relates to a method for producing a polymer master batch and a polymer composition, wherein the method comprises providing at least one monomer capable of forming a poly(hydroxy carboxylic acid), providing a graphene nano-filler, mixing the monomer and the graphene nano-filler and letting the monomer polymerize in the presence of the graphene nano-filler. The polymer together with the graphene nano-filler is further blended with another polymer to form a polymer composite. The invention also relates to a polymer composition with graphene nano-filler and a composite material comprising a polymer composite with graphene nano-fillers.

A preparation method of a fluoropolymer processing aid. The preparation method comprises the following steps: simultaneously adding ε-caprolactone and a fluoropolymer elastomer into a reactor, and heating to completely dissolve the fluoropolymer elastomer; and then cooling, adding polyol, mixing thoroughly, and adding an organotin catalyst to carry out a polymerization reaction; and after the reaction is finished, carrying out cooling, pulverizing or spray granulation so as to obtain the fluoropolymer processing aid. The processing aid prepared by using the method can reduce the extrusion pressure of a polymer during extrusion, improve the processing efficiency, improve the phenomena of melt rupture and “sharkskin” during polymer extrusion, and effectively enhance the surface quality of a product. Compared with the prior art, the processing aid of the invention has the characteristics of uniform dispersed particle size during polymer processing, no coking at a die head during long-time polymer extrusion processing, etc.

A liquid crystal polymer composite film is formed from a resin composite including one or more liquid crystal polymers and one or more fillers. The liquid crystal polymer composite film has a thickness in the range of 10 μm-200 μm and a ratio of the in-plane dielectric permittivity in the machine direction to the transverse direction in the range of 1.0-1.4 over a frequency range of 1 Ghz to 10 Ghz. A metal-clad laminate includes the liquid crystal polymer composite film and a metal clad layer laminated to a major surface of the liquid crystal polymer composite film. The metal-clad laminate may be included as part of an antenna.