Provided herein is a powder composition comprising a silica-infused crystalline polyester particle for laser sintering comprising at least one crystalline polyester resin and silica nanoparticles present in the particle an amount ranging from about 10 wt % to about 60 wt % relative to the total weight of the particle. Further provided herein are methods of preparing silica-infused crystalline polyester particles.

This invention relates to thermoresponsive hydrogels. Particularly, the invention relates to a thermoresponsive hydrogel comprising copolymer polyethylene glycol (PEG)-polycaprolactone (PCL)-polyethylene glycol (PEG) and polypropylene fumerate (PPF). The thermoresponsive hydrogel may further comprise a poloxamer, particularly Pluronic F-127. The invention extends to a method of manufacturing thermoresponsive hydrogels, also extends to an ink for a three dimensional (3D) printer including the thermoresponsive hydrogels. The invention further extends to a thermoresponsive hydrogel for use in the treatment of a bone injury and/or a bone defect, and/or to a method of treating a bone injury and/or a bone defect. The thermoresponsive hydrogels may include dispersed therein an active pharmaceutical ingredient (API), preferably an API falling in the Biopharmaceutics Classification System (BCS) class II, further preferably a statin type drug, most preferably simvastatin.

The present invention provides porous polymer coatings having adhesive and air flow resistive properties. The porous polymer coating comprises a polymeric foam having a void fraction of greater than about 15% and an air permeability greater than 3 cubic feet per minute per square foot as measured based on ASTM D737-04.

A heat-shrinkable polyester film is made from a polyester resin composition which includes an amorphous polyalkylene benzenedicarboxylate resin and a polyester elastomer resin. The polyester elastomer resin includes hard segments and soft segments, and is prepared by copolycondensation of an aromatic dicarboxylic acid and a diol component. The diol component includes a C2-C4 alkylene glycol for the hard segments and a polyethylene glycol with an average molecular weight not greater than 400 for the soft segments. The soft segments of the polyester elastomer resin are in an amount ranging from 1 part by weight to 2 parts by weight based on 100 parts by weight of the polyester resin composition.

There is provided a composite material including scaly fillers made of an inorganic material and a binding resin that is a thermosetting resin which binds the fillers. The composite material 1 is a foaming material in which a plurality of voids is dispersed therein, and the fillers accumulate on inner walls of the voids so that flat surfaces of the fillers overlap.

An aqueous binder composition is provided for use in the formation of fiber insulation and non-woven mats that comprises a reaction product of one or more Liquid Polyol Monomers; itaconic acid, its salts or anhydride; and a C4 to C6 polyol selected from the group consisting of pentaerythritol, trimethylol propane, neopentyl glycol, and mixtures thereof. The molar ratio of the combined alcohols (Liquid Polyol Monomers and C4 to C6 polyols) to itaconic acid is at least 2:1, wherein the molar ratio of Liquid Polyol Monomers to C4 to C6 polyols is from about 1:1 to about 30:1.

Aluminum organic thickeners have been developed for use as thickening agents for thermoset sheet molding compounds and bulk molding compounds. The role of the thickening agent is to control the viscosity of the molding compounds throughout the production processes. The thickeners include an aluminum chelate complex, 10% to 50% by weight of a polyester or polyester acrylate carrier resin, and 10% to 50% by weight of a diluent such as a petroleum distillate. A molding compound includes an aluminum chelate complex thickening agent, a thermosetting resin, reinforcing fibers or microspheres, a crosslinking initiator, and an inhibitor. A method of making a molding compound, such as SMC or BMC with the improved thickener is also provided.

Various methods of reshaping and recycling thermoset polymers and composites containing thermoset polymers are provided. The methods involve the bond exchange reaction of exchangeable covalent bonds in the polymer matrix with a suitable small molecule solvent in the presence of a catalyst. In some aspects, the methods are applied to a carbon fiber reinforced polymer or a thermoset polymer where the thermoset polymer matrix includes a plurality of ester bonds. Using a small molecule alcohol, the methods provide for recycling one or both of the carbon fiber and the polymer, for welding two surfaces, or for repairing a damaged surface in the materials.

A glass filled SMC composition having an effective amount of graphene for providing improved Izod impact strength, flexural strength and tensile properties over and SMC composition without graphene as an additive.

A composition with improved adhesive and sealant properties comprising a pre-polymer comprising a polymeric unit of the general formula (1A1B-).sub.n, wherein A represents a substituted or un-substituted ester, B represents a substituted or un-substituted acid ester comprising at least two acid ester functionalities, and n represents an integer greater than 1, wherein the compositions has a grafted anhydride content of less than about 0.05 mol/mol of polyacid.