Patent classifications
C08J2377/02
Cellulose Microfiber-Reinforced Polyamide Resin Molded Article
Provided is a polyamide resin molded article having high mechanical properties and dimensional accuracy as well as low friction coefficient, low wear, and/or low abrasion property. The present invention provides a polyamide resin molded article composed of a polyamide resin composition including (A) a polyamide resin, (B) chemically modified cellulose microfibers having a weight average molecular weight (Mw) of 100,000 or more, a ratio (Mw/Mn) of the weight average molecular weight (Mw) and the number average molecular weight (Mn) of 6 or less, an alkali-soluble polysaccharides average content of 12 mass percent or less, and a degree of crystallization of 60% or more, and (C) a dispersant having a melting point of 80° C. or less and a number average molecular weight of 1000-50,000, wherein the melting point (Tm) and the crystallization temperature (Tc) of the polyamide resin molded article satisfy formula (1): Tm−Tc≥30° C. . . . (1).
FIBER-REINFORCED THERMOPLASTIC RESIN MOLDED ARTICLE
A fiber reinforced thermoplastic resin molded article includes a thermoplastic resin [A] and carbon fibers [B], a content of the thermoplastic resin [A] being 50 to 95 parts by weight and a content of the carbon fibers [B] being 5 to 50 parts by weight per 100 parts by weight of a total of the thermoplastic resin [A] and the carbon fibers [B], the molded article having a bending elastic modulus of 30 GPa or more, an interfacial shear strength between the thermoplastic resin [A] and the carbon fibers [B] being 15 MPa or more, and a logarithmic decrement of the molded article calculated by Formula (1) of less than 3, wherein the carbon fibers [B] have a weight-average fiber length (L.sub.w) of 0.5 to 10.0 mm:
Logarithmic decrement δ=(1/n)×ln(α.sub.(1)/α.sub.(1+n)) (1).
TRIBLOCK COPOLYMERS AND HYDROGELS THEREOF
The invention provides methods for the formation of thermo-reversible hydrogels from triblock copolymers of poly(ethylene glycol) and poly(α-benzyl carboxylate-ε-caprolactone) (PBCL-PEG-PBCL) prepared by bulk and solution polymerization. PBCL-PEG-PBCLs prepared at fixed PBCL to PEG ratios but different polymerization times were characterized for their average molecular weights, molar-mass disparity and intrinsic viscosity using .sup.1H NMR and gel permeation chromatography (GPC). The results indicated a copolymer of high molecular weight population with elevated intrinsic viscosity. The size and proportion of this population grew as a function of polymerization time. The formation of this high molecular weight PBCL-PEG-PBCL population can be attributed to non-linear architecture caused by partial cross-linking of the PBCL segment during the polymerization reaction. At least about 40% mole concentration of the high molecular weight PBCL-PEG-PBCL was required for thermo-reversible micellar aggregation in aqueous media and hydrogel formation.
THERMOSETTING RESIN COMPOSITION, THERMOSETTING RESIN CURED PRODUCT, PREPREG AND FIBER-REINFORCED COMPOSITE MATERIAL
A thermosetting resin composition contains at least: [A] a thermosetting resin; [B] a curing agent; and [C] polyamide particles satisfying following (c1) to (c6): (c1) a melting point of polyamide resin constituting the polyamide particles is 200 to 300° C.; (c2) a crystallization temperature of the polyamide resin constituting the polyamide particles is 150° C. to 250° C.; (c3) a number average particle size of the polyamide particles is 1 to 100 μm; (c4) a sphericity of the polyamide particles is 80 to 100; and (c5) the linseed oil absorption of the polyamide particles is 10 to 100 mL/100 g. A thermosetting resin composition of the present invention enables suitable production of a fiber-reinforced composite material having sufficient compressive strength after impact and wet heat compression performance.
METHOD FOR PRODUCING POLYAMIDE RESIN FILM
To provide a method for producing a polyamide resin film by using a polyamide resin obtained through polymerization of a regenerated monomer used as a recycled material. Provided is a method for producing a polyamide resin film, including: (1) a step of producing a monomer from a raw material (A) for depolymerization, (2) a step of producing a polyamide resin (B) through polymerization using a raw material containing the monomer. (3) a step of refining the polyamide resin (B), and (4) a step of producing an unstretched film using a starting material containing the refined polyamide resin (B), and stretching the unstretched film.
PLASTIC COMPOSITE RESIN COMPOSITION, A METHOD OF MANUFACTURING A PLASTIC MOLDED ARTICLE, AND A PLASTIC MOLDED ARTICLE FOR RADAR ABSORPTION MANUFACTURED USING THE METHOD
The present disclosure relates to a plastic composite resin composition, a method of manufacturing a plastic molded article using the same, and a plastic molded article for radar absorption manufactured using the method. More particularly, the present disclosure provides a method of improving a radar absorption rate by manufacturing a plastic molded article having pores formed therein using a plastic resin including polyamide, a filler including carbon nanotubes, and a foaming agent.
Composite laminate and method for producing same
Provided is a composite laminate having excellent releasability from a mold during a production process and having excellent surface appearance (surface smoothness). A composite laminate 1 including an A layer 2 and a B layer 3, the A layer 2 being provided on one or both sides of the B layer 3, the A layer 2 containing inorganic fibers (a1) with an average fiber length of 1 μm to 300 μm and a thermoplastic resin (a2), the B layer 3 containing reinforcing fibers (b1) with an average fiber length of 1 mm or more and a thermoplastic resin (b2).
Resin molded body production method
Provided is a resin molded body production method that enables production of a resin molded body in which mechanical strength is good, anisotropy of physical properties is low, and little warpage is developed. This production method is for a resin molded body containing a thermoplastic resin (A) and a cellulose nanofiber (B), the production method including: a step for preparing a main supply material (a1) containing the thermoplastic resin (A) and the cellulose nanofiber (B) and an auxiliary supply material (a2) that is a product of melting treatment of the main supply material (a1); a resin composition formation step for obtaining a resin composition (b) by melting and mixing of the main supply material (a1) and the auxiliary supply material (a2); and a step for obtaining the resin molded body by molding the resin composition (b).
PREPREG, MOLDED ARTICLE, AND INTEGRALLY MOLDED ARTICLE
A prepreg and an integrally molded article are described, the prepreg including a thermoplastic resin existing on one face of a layer in which reinforcing fibers are impregnated with a thermosetting resin, wherein the prepreg exhibits, in injection molding or press molding, thermal weldability with a member containing a thermoplastic resin, and wherein the thermosetting resin has a specific peak on a loss tangent (tan δ) curve obtained by dynamic mechanical analysis (DMA), so that the prepreg exhibits suitable flexibility and adhesiveness, excellent formability on a complicated mold face, and adhesion to a mold face, causes no positional shift, and can be efficiently reinforced and stiffened at an intended position.
HIGH CRYSTALLINITY POLYAMIDE FOAM PARTICLES AND FOAM MOLDINGS
Described herein are polyamide foam particles including a polymer mixture including: (A) from 25 to 95 wt.-% of at least one polyamide, which is different from a copolyamide (B); and (B) from 5 to 75 wt.-% of at least one copolyamide prepared by polymerizing the following components: (B1) from 15 to 84 wt.-% of at least one lactam; and (B2) from 16 to 85 wt.-% of monomer mixture (M) including; (M1) at least one C.sub.32-C.sub.40 dimer acid; and (M2) at least one C.sub.4-C.sub.12 diamine; where the sum of the components (B1) and (B2) are 100 wt.-%. Also described herein is a process for preparing such polyamide foam particles and polyamide particle foam moldings obtainable by steam-chest molding.