The invention describes powders for use in the production of spatial structures, i.e. molded bodies, using layer build-up methods, as well as methods for their efficient production. The powders have the special feature that they have good flow behavior, for one thing, and at the same time, have such a composition that the molded body that can be produced with the powder, using rapid prototyping, has significantly improved mechanical and/or thermal properties. According to a particularly advantageous embodiment, the powder has a first component that is present in the form of essentially spherical powder particles, which is formed by a matrix material, and at least one further component in the form of stiffening and/or reinforcing fibers, which are preferably embedded in the matrix material.

The invention concerns a thermoplastic composition having high fluidity in the molten state, comprising at least: (a) one thermoplastic polymer matrix; (b) one oligomer selected from cyclic ester oligomers, ether oligomers and mixtures thereof, said oligomer having a degree of polymerization of between 2 and 25; and (c) one phenolic polymer; said compounds (b) and (c) being present in a weight ratio (c)/(b) varying from 0.25 to 6, and preferably from approximately 0.75 to 2.75.

The invention also concerns a process for producing a composite article from such a composition by impregnating a reinforcement such as a fabric or a preform, the composite article obtained according to this process, and the use of an oligomer (b) in combination with at least one phenolic polymer (c), as a plasticizing additive in a thermoplastic polymer matrix.

Halogenated cyclic diesters, halogenated polymers derived from the cyclic diesters, and methods for making the halogenated cyclic diesters and related halogenated polymers.

Embodiments of the present technology may include a method of making a thermoplastic composite strand. The method may include melting a reactive thermoplastic resin to form a molten reactive resin. The method may also include fully impregnating a plurality of continuous fibers with the molten reactive resin in an impregnation device. The method may further include polymerizing the molten reactive resin to form a thermoplastic resin matrix. In addition, the method may include cooling the thermoplastic resin matrix to form a thermoplastic composite strand.

Provided is a thermoplastic resin composition which contains three components, i.e., a polyethylene, a polyamide and a compatibilizer and is excellent in impact resistance while realizing a reduction in environmental load, and a modifier capable of imparting impact resistance to a polyethylene. The composition and the modifier each contain a polyethylene, a polyamide and a compatibilizer. The compatibilizer is a modified elastomer having a reactive group that reacts with the polyamide, and the polyethylene and the polyamide have a bio-based carbon content rate of 80% or more according to ISO 16620-2.

Disclosed herein is a method to recover constituent polymers in multilayer plastic films or mixed plastic wastes. The method comprises selectively dissolving a polymer in a solvent at a temperature, wherein the polymer is soluble, but other polymers in the multilayer plastic film or mixed plastic waste are not. The solubilized polymer is then separated from the multilayer plastic film or mixed plastic waste by mechanical filtration and precipitated by changing the temperature and/or adding a cosolvent. The process is repeated for each of the polymer component, resulting in a number of segregated streams that can then be recycled. Computational tools can be used to select solvent systems and temperatures that selectively dissolve different polymers from among all of the components.

The invention relates to a process for preparing a biaxially oriented film, comprising the following steps: a) Melting a composition comprising at least 50 wt % with respect to the total amount of the composition of a copolyamide comprising: i. At least 75 wt % monomeric units derived from caprolactam, and further monomeric units derived from diamines X and/or diacids Y and/or aminoacids Z in a summed amount of between 0.2 to 25 wt %; or ii. At least 75 wt % monomeric units derived from hexamethylene diamine and adipic acid, and further monomeric units derived from diamines X and/or diacids Y and/or aminoacids Z in a summed amount of between 0.2 to 25 wt %; into a polymer melt; b) Casting the polymer melt through a planar die to form a film of at least one layer and subsequently quenching the film to a temperature of below Tg of the copolyamide; c) Stretching the film obtained after quenching in a direction parallel to the machine (MD-stretching) with a factor of at least 2 at a temperature of at least Tg of the copolyamide; d) Stretching the film obtained after MD stretching in a direction transversal to the machine (TD-stretching) with a factor of at least 2 at a temperature of at least Tg+10° C. of the copolyamide; e) Cooling the obtained film after TD-stretching; f) Heat setting the film obtained after cooling, at a temperature of between Tm−70° C. and Tm of the copolyamide; in which Tg and Tm of the copolyamide are determined as described by ASTM D3418-03. The invention also relates to a biaxially oriented film and food packaging obtainable by this process.

The present invention provides a polyamide composite material, which includes the following components in parts by weight: 25-85 parts of a polyamide resin; 10-50 parts of a glass fiber; 5-25 parts of polytetrafluoroethylene; and 0.1-2 parts of at least one of a K/Na/Ca/Mg/Ba/Zn/Li/Al salt of montanic acid. The montanate can effectively inhibit free hydrogen fluoride in the polytetrafluoroethylene, thereby effectively inhibiting free silicon in the glass fiber and improving the electrical performance of the material.

A resin powder for solid freeform fabrication has a 50 percent cumulative volume particle diameter of from 5 to 100 μm and a ratio (Mv/Mn) of a volume average particle diameter (Mv) to the number average particle diameter (Mn) of 2.50 or less and satisfies at least one of the following conditions (1) to (3): (1): Tmf1>Tmf2 and (Tmf1−Tmf2)≥3 degrees C., both Tmf1 and Tmf2 are measured in differential scanning calorimetry measuring according to ISO 3146, (2): Cd1>Cd2 and (Cd1−Cd2)≥3 percent, both Cd1 and Cd2 are measured in differential scanning calorimetry measuring according to ISO 3146, and (3): C×1>C×2 and (C×1−C×2)≥3 percent.

The present invention relates to a polymer film comprising a base film comprising polyamide-based resin; and two or more kinds of copolymers comprising polyamide-based segments and polyether-based segments, and a method for preparing the polymer film.