Patent classifications
C08J2377/06
FIBER-REINFORCED THERMOPLASTIC RESIN MOLDED ARTICLE
A fiber reinforced thermoplastic resin molded article includes a thermoplastic resin [A] and carbon fibers [B], a content of the thermoplastic resin [A] being 50 to 95 parts by weight and a content of the carbon fibers [B] being 5 to 50 parts by weight per 100 parts by weight of a total of the thermoplastic resin [A] and the carbon fibers [B], the molded article having a bending elastic modulus of 30 GPa or more, an interfacial shear strength between the thermoplastic resin [A] and the carbon fibers [B] being 15 MPa or more, and a logarithmic decrement of the molded article calculated by Formula (1) of less than 3, wherein the carbon fibers [B] have a weight-average fiber length (L.sub.w) of 0.5 to 10.0 mm:
Logarithmic decrement δ=(1/n)×ln(α.sub.(1)/α.sub.(1+n)) (1).
POLYAMIDE-BASED FILM, METHOD OF PREPARING POLYAMIDE-BASED FILM, COVER WINDOW AND DISPLAY DEVICE COMPRISING THE SAME
The embodiments provide a polyamide-based film, which comprises a polyamide-based polymer and has a light resistance index of 0.660 GPa-1 or less as represented by the following Equation 1, whereby it has excellent mechanical properties, optical properties, and light resistance. [Equation 1] Light resistance index=ΔYI/Y. In Equation 1, Y is the modulus of the film, and ΔYI is the rate of change in yellow index (YI) of the film before and after a light resistance test in which UV rays are irradiated to the film at 60° C., the UV irradiation is stopped, and water is sprayed at 50° C.
REINFORCED RESIN COMPOSITION, MOLDED PRODUCT, AND METHOD OF IMPROVING TENSILE STRENGTH AT ELEVATED TEMPERATURES
The present disclosure is directed to provide a reinforced resin composition excellent in mechanical strength at elevated temperatures and a molded product including such a reinforced resin composition. A reinforced resin composition of the present disclosure includes (A) a polyamide; (B) a polyamide; (C) a polyphenylene ether; and (D) an inorganic filler, wherein a mass ratio of the component (C) with respect to 100 parts by mass of a sum of the component (A), the component (B), and the component (C) is from 20 to 50 parts by mass, ΔH.sub.TcMt is 10 J/g or more, and ΔH.sub.MpMt is 35 J/g or less.
Polymerization process
The present invention relates to a process comprising the step of melt-mixing a semi-aromatic polyamide (A) having a melting point on second heating of 295° C. or less comprising terephthalamide repeat units and a polyamide oligomer (B) comprising terephthalamide repeat units and having an amine end group concentration of less than 2000 me q/Kg and an inherent viscosity of at least 0.10, at a temperature which is greater than the melting point on first heating of both semi-aromatic polyamide (A) and polyamide oligomer (B) for a time period sufficient to produce semi-aromatic polyamide (C) having a melting point on second heating which is greater than or equal to 300° C.
USE OF A REINFORCED THERMOPLASTIC COMPOSITION
The field of molded articles and fiber-reinforced thermoplastic compositions for obtaining them. The use of the reinforced thermoplastic composition for obtaining a thin molded article with reduced warpage. The composition may include: from 30 to 70% by weight of an amorphous polyamide matrix by total weight of the composition; from 30 to 70% by weight of glass fibers with a circular cross-section by total weight of the composition; and optionally additives.
Polyether block amide-poly(meth)acrylate foams
A mixture contains at least one polyether block amide (PEBA) and at least one poly(meth)acrylate, selected from poly(meth)acrylimides, poly-alkyl(meth)acrylates, and mixtures thereof. The mass ratio of PEBA to poly(meth)acrylate is 95:5 to 60:40. The polyalkyl(meth)acrylate contains 80% by weight to 99% by weight of methyl methacrylate (MMA) units and 1% by weight to 20% by weight of C1-C10-alkyl acrylate units, based on the total weight of polyalkyl(meth)acrylate. The mixture can be processed to give foamed mouldings. The mouldings can he used in footwear soles, stud material, insulation or insulating material, damping components, lightweight components, or in a sandwich structure.
POLYAMIDE-BASED RESIN EXPANDED BEADS, MOLDED ARTICLE OF POLYAMIDE-BASED RESIN EXPANDED BEADS, AND METHOD FOR PRODUCING POLYAMIDE-BASED RESIN EXPANDED BEADS
Polyamide-based resin expanded beads contain a polyamide-based resin as a base material resin. The beads have a crystal structure, an intrinsic peak of the polyamide-based resin and a high-temperature peak having a peak top temperature on a higher temperature side than a peak top temperature of the intrinsic peak appear in a DSC curve obtained under a predetermined condition; an amount of heat of fusion of the high-temperature peak is within 5 J/g or more and 50 J/g or less; and a coefficient of variation of the amount of heat of fusion of the high-temperature peak is 20% or less. The beads are produced by in-mold molding. A method for producing the beads includes: impregnating a polyamide-based resin; and releasing expandable polyamide-based resin beads from a sealed container, a temperature in the sealed container is raised at a rate of 0.3° C. or higher and 1.5° C. or lower per 10 minutes.
Process for manufacturing composite articles
The present invention relates to the use of thermoplastic polymer compositions for impregnating reinforcing materials in the form of fabric or industrial fabrics for the manufacture of composite materials. The field of the invention is that of composite materials as well as molding/consolidation processes and obtained parts. The invention more particularly relates to a method of manufacturing a composite article by injection molding comprising at least the steps of introducing at least one reinforcement fabric into a preheated mold, partial closure of the mold, a temperature rise step of the mold, optionally a step of maintaining the temperature of the mold before injection of a thermoplastic polymer composition, a step of injecting a thermoplastic polymer composition into the mold, a step of mold closure to the final part thickness allowing the flow of the resin through the reinforcing fabric, a cooling step and a recovery step of the obtained composite article.
Material, method for producing the material, partially welded material, composite material, and method of producing molded product
To provide a novel material that maintains suppleness which is the advantage of a material using fibers and has a low thermal shrinkage ratio, and a method for producing the material, a partially welded material using the material, a composite material, and a method for producing a molded product. A material including: a first region, a fiber region, and a second region continuously in a thickness direction; the first region and the second region being each independently a resin layer including from 20 to 100 mass % of a thermoplastic resin component and from 80 to 0 mass % of reinforcing fibers; the fiber region including from 20 to 100 mass % of thermoplastic resin fibers and from 80 to 0 mass % of reinforcing fibers; the thermoplastic resin component included in the first region and the thermoplastic resin component included in the second region each independently having a crystallization energy during temperature increase of 2 J/g or greater, measured by differential scanning calorimetry; and the thermoplastic resin fibers included in the fiber region having a crystallization energy during temperature increase of less than 1 J/g, measured by differential scanning calorimetry; wherein the crystallization energy during temperature increase is a value measured by using a differential scanning calorimeter (DSC) in a nitrogen stream while heating is performed from 25° C. to a temperature that is 20° C. higher than a melting point of the thermoplastic resin component or the thermoplastic resin fibers at a temperature increase rate of 10° C./min.
FLEXIBLE POLYAMIDE FILM
A flexible polyamide film obtained by forming a polyamide including a unit formed from an aliphatic dicarboxylic acid (A1) having 18 or more carbon atoms and/or a unit formed from an aliphatic diamine (B1) having 18 or more carbon atoms, wherein the polyamide has a total content of 10 to 92% by mass of the unit formed from (A1) and the unit formed from (B1), and the film has a melting point of 240° C. or higher.